1 research outputs found
A convenient route to enantiomerically enriched furo-fused BINOL derivative
No full text940-943A simple
synthetic route has been developed to obtain a new axially chiral, C2-symmetric, modified BINOL with the
introduction of methyl substituted furan ring fused to the BINOL 1
framework. The successful placement of the furan moiety at C-7; C-8 and
C-7′; C-8′ positions of 1 resulted in the sterically demanding BINOL
derivative. The synthesis of
both enantiomers of methyl-substituted furo-fused BINOL has been carried out
with high enantioselectivitie
