On Extracting Mechanical Properties from Nanoindentation at Temperatures up to 1000∘^{\circ}C

Alloyed MCrAlY bond coats, where M is usually cobalt and/or nickel, are essential parts of modern turbine blades, imparting environmental resistance while mediating thermal expansivity differences. Nanoindentation allows the determination of their properties without the complexities of traditional mechanical tests, but was not previously possible near turbine operating temperatures. Here, we determine the hardness and modulus of CMSX-4 and an Amdry-386 bond coat by nanoindentation up to 1000$^{\circ}$C. Both materials exhibit a constant hardness until 400$^{\circ}$C followed by considerable softening, which in CMSX-4 is attributed to the multiple slip systems operating underneath a Berkovich indenter. The creep behaviour has been investigated via the nanoindentation hold segments. Above 700$^{\circ}$C, the observed creep exponents match the temperature-dependence of literature values in CMSX-4. In Amdry-386, nanoindentation produces creep exponents very close to literature data, implying high-temperature nanoindentation may be powerful in characterising these coatings and providing inputs for material, model and process optimisations

Oxygen vacancies in tungsten oxide and their influence on tungsten oxide silicon heterojunction solar cells

Tungsten oxide WOx can be incorporated into amorphous crystalline silicon heterojunction solar cells as hole contact and for interface modification between p type amorphous silicon and indium tin oxide. This paper aims at understanding the influence of tungsten oxides properties on silicon heterojunction solar cells. Using in system photoelectron spectroscopy on thermally evaporated WOx layers, it was verified that WOx with a stoichiometry close to WO3 features a work function close to 6 eV and is therefore suitable as hole contact on silicon. Additionally the oxygen vacancy concentration in WOx was measured using photoelectron spectroscopy. High oxygen vacancy concentrations in WOx lead to a low band bending in the WOx silicon junction. Furthermore solar cells were fabricated using the same WOx, and the band bending in these cells is correlated with their fill factors FF and open circuit voltages VOC VOC . Combining these results, the following picture arises positively charged oxygen vacancies raise the Fermi level in WOx and reduce the band bending at the WOx silicon junction. This, in turn, leads to reduced VOCVOC and FF. Thus, when incorporating WOx into silicon solar cells it is important to minimize the oxygen vacancy density in WOx. Therefore deposition methods, enabling adjustment of the WOx stoichiometry are preferabl

Sputtered Tungsten Oxide as Hole Contact for Silicon Heterojunction Solar Cells

Reactively sputtered tungsten oxide WOx was investigated as hole contact on n type crystalline silicon. Varying the oxygen gas flow during sputtering enables variation of the WOx conductivity from 0.01 to 1000 amp; 937; cm, while the band bending at the interface and the implied fill factor FF change by 70 meV and 1.5 . SputteredWOx shows higher resistivity and higher absorption in the visible range compared with indium tin oxide ITO . Therefore, stacks of WOx and ITO are used in solar cells. It was found that at least 20 nm thick WOx is needed to prevent detrimental effects of the ITO work function on the band bending at the junction, the implied FF, and the real FF of solar cells. WOx hole contacts of different thicknesses and conductivity were applied in solar cells and it was found that the highest FF is achieved using about 20 nm thick interlayers of WOx with the highest possible conductivity. It was found that sputtering enables a drastic improvement of WOx silicon solar cells compared with thermal evaporation, due to the precise control of the WOx conductivity. Unfortunately, the resistivity of the sputteredWOx is still limiting the FF of these device

Building Skills for and Implementing Course Based Undergraduate Research Experiences (CUREs) Across an Environmental Studies Curriculum

Course Based Undergraduate Research Experiences (CUREs) are an effective method of teaching students not only content, but also critical thinking, scientific practice, and other skills beneficial to their education and success. They lower the barrier to participation in undergraduate research, thereby increasing access to entry. Thus, CUREs are especially valuable to under-performing students as they are an effective means of bridging the achievement gap. Due to the value and effectiveness of CUREs in student development, Lynn University has implemented a means by which students are exposed to CUREs and skills necessary to complete a CURE throughout the Environmental Studies major curriculum. This presentation will give a description of the curriculum and how CUREs and CURE-required skills are taught throughout the curriculum culminating in a fully independent capstone research project

Building Skills for and Implementing Course Based Undergraduate Research Experiences (CUREs) Across an Environmental Studies Curriculum

Course Based Undergraduate Research Experiences (CUREs) are an effective method of teaching students not only content, but also critical thinking, scientific practice, and other skills beneficial to their education and success. They lower the barrier to participation in undergraduate research, thereby increasing access to entry. Thus, CUREs are especially valuable to under-performing students as they are an effective means of bridging the achievement gap. Due to the value and effectiveness of CUREs in student development, Lynn University has implemented a means by which students are exposed to CUREs and skills necessary to complete a CURE throughout the Environmental Studies major curriculum. This presentation will give a description of the curriculum and how CUREs and CURE-required skills are taught throughout the curriculum culminating in a fully independent capstone research project

Direct determination of the band offset in atomic layer deposited ZnO hydrogenated amorphous silicon heterojunctions from X ray photoelectroscopy valence band spectra

The chemical composition and band alignment at the heterointerface between ALD grown zinc oxide ZnO and hydrogenated amorphous silicon a Si H is investigated using monochromatized X ray photoelectron spectroscopy. A new approach for obtaining the valence band offset DeltaEV is developed, which consists in fitting the valence band VB spectrum obtained for a Si H with a thin ZnO overlayer as the sum of experimentally obtained VB spectra of a bulk a Si H film and a thick ZnO film. This approach allows obtaining DeltaEV 2.71 0.15 eV with a minimum of assumptions, and also yields information on the change in band bending of both substrate and ZnO film. The band offset results are compared to values obtained using the usual approach of comparing valence band edge to core level energy differences, DeltaEB,CL DeltaEB,VB. Furthermore, a theoretical value for the VB offset is calculated from the concept of charge neutrality level line up, using literature data for the CNLs and the experimentally determined ZnO a Si H interface dipole. The thus obtained value of DeltaEVCNL 2.65 0.3 eV agrees well with the experimental DeltaE

Life in the Polar Winter - Strategies of Survival

The perception of the polar winter as a period in which organisms have to struggle for survival is common among people living almost exclusively outside the polar regions, even if sometimes in areas with winter resembling the polar winter. ... For arctic organisms, endemic to and wintering in the far North, the polar winter possibly has a different significance. For these organisms it is often a period of rest, during which they conserve energy and prepare for reproduction in the coming feeding season. Until the last decades of this century, we knew little about the significance of the polar winter for organisms that live there year-round. For migratory species it is obviously a rather intolerable season, but how resident species survive and live through the winter was unknown. ... The series of eight papers presented here ... stem from a multidisciplinary symposium organized by the Arctic Centre of the University of Groningen on the occasion of the 375th anniversary of this university of 1989. ... The guiding question of this symposium was: How do humans and their living resources survive the polar winter? As the resources are both terrestrial and marine, both are discussed when presenting organisms from different trophic levels. ... This series of papers concludes with a study of the successes and misfortunes of western Europeans wintering in the High Arctic in the 16th and 17th centuries and an article about Russian trappers during the 18th and 19th centuries wintering in Spitsburgen. ..

Brief Cognitive Screening Tools for Primary Care Practice

Early detection and diagnosis of Alzheimer’s disease and other cognitive impairment presents as a critical issue facing primary and specialty care providers in Washington State. In order to address the gaps and challenges faced by providers, the Dementia Action Collaborative offers the current paper to provide information and guidance around early detection and diagnosis of memory loss and dementia, including Alzheimer’s disease. At the conclusion of this paper, providers should be able to identify indications and opportunities for detection, appropriate tools, and care pathways for individuals and families affected by cognitive impairment and dementia