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Department of Energy EngineeringTransition metal dichalcogenides (TMDs) have received significant attention because of their potentials for replacing or modifying the existing charge transporting materials in organic solar cells (OSCs) with their unique crystalline structure and desirable electrical properties. Poly(3,4-ethylene dioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) has been considered as the representative hole transporting material owing to its notable optical transmittance, electrical conductivity, and solution-processability. In this study, we provide a facile method to introduce liquid-phase exfoliated TMD, tungsten diselenide (WSe2), as the device performance enhancer in OSCs. Implementation of WSe2 into PEDOT:PSS without significant change to the surface morphology mediates effective charge transport in the completed device. The phase separation of PEDOT and PSS induced by the WSe2 provides a conductivity enhancement in the modified hole transport layer (HTL), which contributes to the increase of hole mobility and decrease of charge recombination loss in the OSCs, resulting in the improvement of power conversion efficiency from 7.3% to 8.5% for pristine and modified HTL devices, respectively. These results provide a simple strategy for the enhancement of device performance in OSCs, demonstrating their promising potential in the application of TMDs for next-generation energy harvesting devices.ope

Forecasting Warping Deformation Using Multivariate Thermal Time Series and K-Nearest Neighbors in Fused Deposition Modeling

Over the past decades, additive manufacturing has rapidly advanced due to its advantages in enabling diverse material usage and complex design production. Nevertheless, the technology has limitations in terms of quality, as printed products are sometimes different from their desired designs or are inconsistent due to defects. Warping deformation, a defect involving layer shrinkage induced by the thermal residual stress generated during manufacturing processes, is a major factor in lowering the quality and raising the cost of printed products. This study utilized a variety of thermal time series data and the K-nearest neighbors (KNN) algorithm with dynamic time warping (DTW) to detect and predict the warping deformation in the printed parts using fused deposition modeling (FDM) printers. Multivariate thermal time series data extracted from thermocouples were trained using DTW-based KNN to classify warping deformation. The results showed that the proposed approach can predict warping deformation with an accuracy of over 80% by only using thermal time series data corresponding to 20% of the whole printing process. Additionally, the classification accuracy exhibited the promising potential of the proposed approach in warping prediction and in actual manufacturing processes, so the additional time and cost resulting from defective processes can be reduced

Longitudinal trajectory of acidosis and mortality in acute kidney injury requiring continuous renal replacement therapy

Abstract Background Acidosis frequently occurs in severe acute kidney injury (AKI), and continuous renal replacement therapy (CRRT) can control this pathologic condition. Nevertheless, acidosis may be aggravated; thus, monitoring is essential after starting CRRT. Herein, we addressed the longitudinal trajectory of acidosis on CRRT and its relationship with worse outcomes. Methods The latent growth mixture model was applied to classify the trajectories of pH during the first 24 hours and those of C-reactive protein (CRP) after 24 hours on CRRT due to AKI (n = 1815). Cox proportional hazard models were used to calculate hazard ratios of all-cause mortality after adjusting multiple variables or matching their propensity scores. Results The patients could be classified into 5 clusters, including the normally maintained groups (1st cluster, pH = 7.4; and 2nd cluster, pH = 7.3), recovering group (3rd cluster with pH values from 7.2 to 7.3), aggravating group (4th cluster with pH values from 7.3 to 7.2), and ill-being group (5th cluster, pH < 7.2). The pH clusters had different trends of C-reactive protein (CRP) after 24 hours; the 1st and 2nd pH clusters had lower levels, but the 3rd to 5th pH clusters had an increasing trend of CRP. The 1st pH cluster had the best survival rates, and the 3rd to 5th pH clusters had the worst survival rates. This survival difference was significant despite adjusting for other variables or matching propensity scores. Conclusions Initial trajectories of acidosis determine subsequent worse outcomes, such as mortality and inflammation, in patients undergoing CRRT due to AKI

Risk of ventricular tachycardia and its outcomes in patients undergoing continuous renal replacement therapy due to acute kidney injury

Background Despite efforts to treat critically ill patients who require continuous renal replacement therapy (CRRT) due to acute kidney injury (AKI), their mortality risk remains high. This condition may be attributable to complications of CRRT, such as arrhythmias. Here, we addressed the occurrence of ventricular tachycardia (VT) during CRRT and its relationship with patient outcomes. Methods This study retrospectively enrolled 2,397 patients who started CRRT due to AKI from 2010 to 2020 at Seoul National University Hospital in Korea. The occurrence of VT was evaluated from the initiation of CRRT until weaning from CRRT. The odds ratios (ORs) of mortality outcomes were measured using logistic regression models after adjustment for multiple variables. Results VT occurred in 150 patients (6.3%) after starting CRRT. Among them, 95 cases were defined as sustained VT (i.e., lasting ≥30 seconds), and the other 55 cases were defined as non-sustained VT (i.e., lasting <30 seconds). The occurrence of sustained VT was associated with a higher mortality rate than a nonoccurrence (OR, 2.04 and 95% confidence interval [CI], 1.23–3.39 for the 30-day mortality; OR, 4.06 and 95% CI, 2.04–8.08 for the 90-day mortality). The mortality risk did not differ between patients with non-sustained VT and nonoccurrence. A history of myocardial infarction, vasopressor use, and certain trends of blood laboratory findings (such as acidosis and hyperkalemia) were associated with the subsequent risk of sustained VT. Conclusion Sustained VT occurrence after starting CRRT is associated with increased patient mortality. The monitoring of electrolytes and acid-base status during CRRT is essential because of its relationship with the risk of VT

Study on Highly Efficient Organic and Perovskite Solar Cells with Operational Stability

Department of Materials Science and Engineeringclos