1 research outputs found
Alkoxy-Functionalized Hydroxamate/Zinc Metal–Organic Frameworks and the Effects of Substituents and Acid Addition on Their Structures
Single
crystals of alkoxy-functionalized hydroxamate/zinc metal–organic
frameworks (MOFs) were obtained by fixating the hydroxamate moiety
via intramolecular hydrogen bonding. The resulting MOF structures
depend on the steric demand of the alkoxy groups, whereby the incorporation
of bulky isopropyl groups affords porous hydroxamate/zinc MOFs. The
topological structures of the isopropyl-substituted MOFs could be
controlled by adding acid