Office paper recyclability: fibrous characteristics

Recyclability is the ability of a material to reacquire the same properties it had originally. The aim of this work was to verify the recyclability of three printing and writing papers, from the characteristics of their fibers after two recycles. Three ECF bleached kraft eucalyptus commercial bond papers from Argentina and Brazil were studied (A, B, C). The papers were repulped and refined using different levels and intensities of energy (1st recycle). Laboratory sheets were produced, and they were repulped and refined again (2nd recycle). The microscopic characteristics of repulped papers were obtained by automatic equipment based on image analysis. Differences found in the behavior of the different samples can be explained by fiber parameters. The fiber length was significantly different in the three papers (A > B > C) and globally decreased in the second recycle (about 6%). Sample A had the highest initial fiber length and length/width, but it largely decreased with refining conditions in the 1st recycle (length fall 12%, generating fines by cutting), whereas it fall 9% between the 1st and 2nd recycles, and nothing with refining conditions in the 2nd recycle. Sample B fall by 5% with refining conditions in the 1st recycle, and 9% between the 1st and the 2nd recycle, but suffered few alteration in the second recycle. Fiber length of sample C was unaffected by refining conditions and only decreased 9% between the 1st and 2nd recycles. In all cases, the generated fines increased lightly with refining in the first recycle, but were two-fold higher in the second recycle than in the first one. The fiber coarseness of the 3 samples was similar in the first recycle, but decreases significantly in the 2nd recycleFil: Benitez, Julieta Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Cs.exactas Químicas y Naturales. Instituto de Materiales de Misiones; ArgentinaFil: Koga, Mariza E. T.. Instituto de Pesquisas Tecnologicas de Sao Paulo; BrasilFil: Otero D'Almeida, Maria L.. Instituto de Pesquisas Tecnologicas de Sao Paulo; BrasilFil: Felissia, Fernando Esteban. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Cs.exactas Químicas y Naturales. Instituto de Materiales de Misiones; ArgentinaFil: Park, Song W.. Universidade de Sao Paulo; BrasilFil: Area, Maria Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Cs.exactas Químicas y Naturales. Instituto de Materiales de Misiones; Argentin

Office paper recyclability: first recycling

Paper recyclability implies in the paper capacity to be recycled maintaining its properties to the maximum. Four commercial papers from Argentina and Brazil were studied, including three eucalyptus kraft (A, B, C) and one sugar cane bagasse soda-AQ (D), all with different bleaching processes. Their physical and chemical properties and a first laboratory recycling were evaluated. A refining of the pulp with a PFI mill, applying two energy levels at two different intensities - measured by number of revolutions and load - was accomplished to reach the same °SR (between 30 and 40, approximately). The refining energy and the yield were registered in each case. The properties of laboratory handsheets, and the aging to 24, 48, 72 and 144 hours were evaluated. The statistical analysis of the results indicates that the properties of the initial eucalyptus papers were similar, whereas they were generally inferior in the case of the bagasse paper. The bagasse and eucalyptus papers presented similar initial whiteness, but the first one had a higher reversion than the others. Once repulped, the eucalyptus papers A, B and C required, respectively, 4, 7 and 10 times greater energy than D, to obtain the same °SR. In all cases, the required energy to achieve the same °SR is slightly greater with the smaller refining intensity. The physical properties of the handsheets from the first recycle of paper D were, in general, lower. Among eucalyptus papers, B showed a slightly higher resistance and C, a slightly lower one. The mechanical properties of pulp sheets A, and D to a lesser extension, were more affected by the refining intensity than the rest, indicating a higher sensitivity of the fibers. The whiteness of the sheets of pulp B is lower than the rest. Opacity and light scattering coefficient of the sheets of pulp C were much higher than those of the other pulps.Fil: Benitez, Julieta Beatriz. Universidad Nacional de Misiones; ArgentinaFil: Koga, Mariza E. T.. Instituto de Pesquisas Tecnológicas de São Paulo (ipt); BrasilFil: Otero D'Almeida, Maria L.. Instituto de Pesquisas Tecnológicas de São Paulo (ipt); BrasilFil: Felissia, Fernando Esteban. Universidad Nacional de Misiones; ArgentinaFil: Park, Song W.. Escola Politecnica, Universidad de Sao Paulo (usp); BrasilFil: Area, Maria Cristina. Universidad Nacional de Misiones; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentin