"Non-invasive" portable laser ablation sampling of art and archaeological materials with subsequent Sr-Nd isotope analysis by TIMS using 10¹³ Ω amplifiers

A new integrated trace element and multi-isotope provenancing methodology is presented that uses a portable “non-invasive” pulsed laser ablation sampling technique. Samples are collected on location onto Teflon filters for return to a clean laboratory for low blank (pg) geochemical procedures. Ablation pits approximately 60 or 120 μm in width and depth remove mg amounts of material. Following dissolution, trace element ratios are determined by inductively coupled plasma mass spectrometry and combined Sr–Nd isotopes by thermal ionization mass spectrometry. Use of 1013 Ω resistors allows precise analysis of subnanogram amounts of Sr-Nd isotopes, which coupled with the trace element data, provides highly effective multi-variant discrimination for material provenance and authenticity verification. Monitoring of blank contributions is required

A holistic provenance and microwear study of pre-colonial jade objects from the Virgin Islands: unravelling mobility networks in the wider Caribbean

Pre-colonial Caribbean jade objects from the National Museum of Denmark Hatt Collection were subjected to a provenance and microwear analysis. Thirty-nine jade celts and bodily ornaments from the US Virgin Islands, i.e., St. Croix, St. Thomas, St. John, and five celts from the West Indies of unknown location, St. Vincent, Cuba and the Dominican Republic were analysed.A comprehensive in-depth examination of jade adornments from St. Croix, combining typo-technological and microwear analysis, is compared to other lithologies used for pre-colonial ornaments. A portable laser ablation system was used to sample jade celts and bodily ornaments on site in a quasi-non-destructive manner. Low-blank trace element and Sr-Nd isotope ratio data were evaluated with a multiclass regression provenance prediction model.This study demonstrates that the pan-Caribbean exchange of jade raw materials, pre-forms or finished objects during the Ceramic Age (400 BC to AD 1492) occurred on a more complex scale than previously thought involving jade sources in Guatemala, eastern Cuba and the northern Dominican Republic. In addition, the study of ornaments recovered from St. Croix reveals use of specific lithologies suggesting stronger ties to Indigenous communities on Puerto Rico than other Lesser Antillean Islands.Material Culture Studie