51 research outputs found
Geometry of good sets in n-fold Cartesian product
We propose here a multidimensional generalisation of the notion of link
introduced in our previous papers and we discuss some consequences for
simplicial measures and sums of function algebras.Comment: 17 pages, no figures, no table
Probing the inter-layer exciton physics in a MoS/MoSe/MoS van der Waals heterostructure
Stacking atomic monolayers of semiconducting transition metal dichalcogenides
(TMDs) has emerged as an effective way to engineer their properties. In
principle, the staggered band alignment of TMD heterostructures should result
in the formation of inter-layer excitons with long lifetimes and robust valley
polarization. However, these features have been observed simultaneously only in
MoSe/WSe heterostructures. Here we report on the observation of long
lived inter-layer exciton emission in a MoS/MoSe/MoS trilayer van
der Waals heterostructure. The inter-layer nature of the observed transition is
confirmed by photoluminescence spectroscopy, as well as by analyzing the
temporal, excitation power and temperature dependence of the inter-layer
emission peak. The observed complex photoluminescence dynamics suggests the
presence of quasi-degenerate momentum-direct and momentum-indirect bandgaps. We
show that circularly polarized optical pumping results in long lived valley
polarization of inter-layer exciton. Intriguingly, the inter-layer exciton
photoluminescence has helicity opposite to the excitation. Our results show
that through a careful choice of the TMDs forming the van der Waals
heterostructure it is possible to control the circular polarization of the
inter-layer exciton emission.Comment: 19 pages, 3 figures. Just accepted for publication in Nano Letters
(http://pubs.acs.org/doi/10.1021/acs.nanolett.7b03184
Non equilibrium anisotropic excitons in atomically thin ReS
We present a systematic investigation of the electronic properties of bulk
and few layer ReS van der Waals crystals using low temperature optical
spectroscopy. Weak photoluminescence emission is observed from two
non-degenerate band edge excitonic transitions separated by 20 meV. The
comparable emission intensity of both excitonic transitions is incompatible
with a fully thermalized (Boltzmann) distribution of excitons, indicating the
hot nature of the emission. While DFT calculations predict bilayer ReS to
have a direct fundamental band gap, our optical data suggests that the
fundamental gap is indirect in all cases
Non equilibrium anisotropic excitons in atomically thin ReS2
We present a systematic investigation of the electronic properties of bulk and few layer ReS2 van der Waals crystals using low temperature optical spectroscopy. Weak photoluminescence emission is observed from two non-degenerate band edge excitonic transitions separated by similar to 20 meV. The comparable emission intensity of both excitonic transitions is incompatible with a fully thermalized (Boltzmann) distribution of excitons, indicating the hot nature of the emission. While DFT calculations predict bilayer ReS2 to have a direct fundamental band gap, our optical data suggests that the fundamental gap is indirect in all cases
Intervalley Scattering of Interlayer Excitons in a MoS/MoSe/MoS Heterostructure in High Magnetic Field
Degenerate extrema in the energy dispersion of charge carriers in solids,
also referred to as valleys, can be regarded as a binary quantum degree of
freedom, which can potentially be used to implement valleytronic concepts in
van der Waals heterostructures based on transition metal dichalcogenides. Using
magneto-photoluminescence spectroscopy, we achieve a deeper insight into the
valley polarization and depolarization mechanisms of interlayer excitons formed
across a MoS/MoSe/MoS heterostructure. We account for the
non-trivial behavior of the valley polarization as a function of the magnetic
field by considering the interplay between exchange interaction and phonon
mediated intervalley scattering in a system consisting of Zeeman-split energy
levels. Our results represent a crucial step towards the understanding of the
properties of interlayer excitons, with strong implications for the
implementation of atomically thin valleytronic devices.Comment: just accepted in Nano Letters, DOI: 10.1021/acs.nanolett.8b0148
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