7,610 research outputs found
Chiral quaternary carbon compounds. II. An asymmetric synthesis of (R) or (S)-4,4-dialkyl-2-cyclopentenones
Current sheet formation and nonideal behavior at three-dimensional magnetic null points
The nature of the evolution of the magnetic field, and of current sheet
formation, at three-dimensional (3D) magnetic null points is investigated. A
kinematic example is presented which demonstrates that for certain evolutions
of a 3D null (specifically those for which the ratios of the null point
eigenvalues are time-dependent) there is no possible choice of boundary
conditions which renders the evolution of the field at the null ideal.
Resistive MHD simulations are described which demonstrate that such evolutions
are generic. A 3D null is subjected to boundary driving by shearing motions,
and it is shown that a current sheet localised at the null is formed. The
qualitative and quantitative properties of the current sheet are discussed.
Accompanying the sheet development is the growth of a localised parallel
electric field, one of the signatures of magnetic reconnection. Finally, the
relevance of the results to a recent theory of turbulent reconnection is
discussed.Comment: to appear in Phys. Plasmas. A version with higher quality figures can
be found at http://www.maths.dundee.ac.uk/~dpontin/ In this replacement
version, typos have been corrected, and in addition references and some
further discussion adde
An efficient asymmetric synthesis of (+)-mesembrine and related chiral 4,4-disubstituted cyclohexenones
Quasi-Dynamic Frame Coordination For Ultra- Reliability and Low-Latency in 5G TDD Systems
The fifth generation (5G) mobile technology features the ultra-reliable and
low-latency communications (URLLC) as a major service class. URLLC applications
demand a tight radio latency with extreme link reliability. In 5G dynamic time
division duplexing (TDD) systems, URLLC requirements become further challenging
to achieve due to the severe and fast-varying cross link interference (CLI) and
the switching time of the radio frame configurations (RFCs). In this work, we
propose a quasi-dynamic inter-cell frame coordination algorithm using hybrid
frame design and a cyclic-offset-based RFC code-book. The proposed solution
adaptively updates the RFCs in time such that both the average CLI and the
user-centric radio latency are minimized. Compared to state-of-the-art dynamic
TDD studies, the proposed scheme shows a significant improvement in the URLLC
outage latency, i.e., 92% reduction gain, while boosting the cell-edge capacity
by 189% and with a greatly reduced coordination overhead space, limited to
B-bit
Two-photon Double Ionization of H in Intense Femtosecond Laser Pulses
Triple-differential cross sections for two-photon double ionization of
molecular hydrogen are presented for a central photon energy of 30 eV. The
calculations are based on a fully {\it ab initio}, nonperturbative, approach to
the time-dependent Schroedinger equation in prolate spheroidal coordinates,
discretized by a finite-element discrete-variable-representation. The wave
function is propagated in time for a few femtoseconds using the short,
iterative Lanczos method to study the correlated response of the two
photoelectrons to short, intense laser radiation. The current results often lie
in between those of Colgan {\it et al} [J. Phys. B {\bf 41} (2008) 121002] and
Morales {\it et al} [J. Phys. B {\bf 41} (2009) 134013]. However, we argue that
these individual predictions should not be compared directly to each other, but
preferably to experimental data generated under well-defined conditions.Comment: 4 pages, 4 figure
A cross-cultural study of cereal foods' quality perception
Cereal foods' production and use show substantial heterogeneity across Europe. For a category central in most EU diets, cereal foods' quality perception is, nevertheless, surprisingly understudied. With this in mind, 357 Danish, Lithuanian and Portuguese citizens were inquired about the importance of several cues and dimensions in their evaluation of the perceived quality of bread, cookies, breakfast cereals, pasta and vodka. Portuguese and Lithuanians consistently gave a significantly higher average importance to all the cues and quality dimensions considered, for all products, than their Danish counterparts. Nevertheless, respondents in all three samples found expected quality dimensions to be much more important than both extrinsic and intrinsic cues across almost all product categories. Dimensions and cues like taste and country - of- origin were the most relevant to Lithuanians, while taste , label information and price were the most important for Danes. The cues and dimensions Portuguese found relevant were fairly different and more category- dependent. Cues like store type for bread, brand for breakfast cereals, pasta and vodka, country - of- origin for vodka , and price for cookies, pasta and vodka were more often assessed by the Portuguese as relevant for decision- making at the point - of- purchase. This highlights the need for further cross - cultural research on food quality perception.Cereal Foods, Consumer Quality Perception, Total Food Quality Model, Cross - cultural Study, Consumer/Household Economics, Food Consumption/Nutrition/Food Safety,
On the fundamental theorem of asset pricing: random constraints and bang-bang no-arbitrage criteria
The paper generalizes and refines the Fundamental Theorem of Asset Pricing of Dalang, Morton and Willinger in the following two respects: (a) the result is extended to a model with portfolio constraints; (b) versions of the no-arbitrage criterion based on the bang-bang principle in control theory are developed.no arbitrage criteria, portfolio constraints, supermartingale measures, bang-bang control
An asymmetric synthesis of chiral 4,4-disubstituted cyclohexenones in high enantiomeric purity
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