Constraints on the High-Density Nuclear Equation of State from Neutron Star Observables

Depending on the density reached in the cores of neutron stars, such objects may contain stable phases of novel matter found nowhere else in the Universe. This article gives a brief overview of these phases of matter and discusses astrophysical constraints on the high-density equation of state associated with ultra-dense nuclear matter.Comment: 16 pages, 11 figures, Contribution to Proceedings of the 3rd International Workshop on Astronomy and Relativistic Astrophysics (IWARA), 3-6 October 2007, Joao Pessoa, Brazi

Comparison of Aromatic Dithiophoshinic and Phosphinic Acid Derivatives for Minor Actinide Extraction

A new extractant for the separation of actinide(III) and lanthanide(III), bis(otrifluoromethylphenyl) phosphinic acid (O-PA) was synthesized. The synthetic route employed mirrors one that was employed to produce the sulfur containing analog bis(otrifluoromethylphenyl) dithiophosphinic acid (S-PA). Multinuclear NMR spectroscopy was used for elementary characterization of the new O-PA derivative. This new O-PA extractant was used to perform Am(III)/Eu(III) separations and the results were directly compared to those obtained in identical separation experiments using S-PA, an extractant that is known to exhibit separation factors of ~100,000 at low pH. The separations data are presented and discussed in terms comparing the nature of the oxygen atom as a donor to that of the sulfur atom in extractants that are otherwise identical

Correlations of Polyimides and Blended Polyimides for High Temperature Gas Separations

High performance polymers are of interest for high temperature gas separations, especially for the sequestration of carbon dioxide. A new family of high performance imide polymers has been identified as a successful membrane capture material. VTEC polyimides possess desired thermal properties (up to 500 °C) along with being robust and flexible even after multiple thermal cycles (up to 400 °C). Polyimides (PI) are excellent materials for high selectivity for smaller kinetic diameter gases such as H2 and CO2; however, they have low fluxes. We blended small amounts of different polymers with VTEC polyimide, which changes the fluxes. Another critical problem when working with glassy polymers is their moisture content. It has been found that water entrapped within the polymer matrix (left over from the solvent, or physisorbed) can also cause the polymer to change dramatically. Additionally presence of molecular water in the polymer’s void volume has been validated through Positron Annihilation Lifetime (PAL) spectroscopy. In this presentation, polymer characterization and gas-separation testing results will be discussed

Comparison of Aromatic Dithiophosphinic and Phosphinic Acid Derivatives for Minor Actinide Extraction 2008 MRS Spring Meeting Comparison of Aromatic Dithiophosphinic and Phosphinic Acid Derivatives for Minor Actinide Extraction

ABSTRACT A new extractant for the separation of actinide(III) and lanthanide(III), bis(otrifluoromethylphenyl)phosphinic acid (O-PA) was synthesized. The synthetic route employed mirrors one that was employed to produce the sulfur containing analog bis(otrifluoromethylphenyl)dithiophosphinic acid (S-PA). Multinuclear NMR spectroscopy was used for elementary characterization of the new O-PA derivative. This new O-PA extractant was used to perform Am(III)/Eu(III) separations and the results were directly compared to those obtained in identical separation experiments using S-PA, an extractant that is known to exhibit separation factors of ~100,000 at low pH. The separations data are presented and discussed in terms comparing the nature of the oxygen atom as a donor to that of the sulfur atom in extractants that are otherwise identical

Comparison of Dithiophosphinic and Phosphinic Acid Derivatives for Minor Actinide Extraction

A new extractant for the separation of actinide(III) and lanthanide(III), bis(otrifluoromethylphenyl) phosphinic acid (O-PA) was synthesized. The synthetic route employed mirrors one that was employed to produce the sulfur containing analog bis(otrifluoromethylphenyl) dithiophosphinic acid (S-PA). Multinuclear NMR spectroscopy was used for elementary characterization of the new O-PA derivative. This new O-PA extractant was used to perform Am(III)/Eu(III) separations and the results were directly compared to those obtained in identical separation experiments using S-PA, an extractant that is known to exhibit separation factors of ~100,000 at low pH. The separations data are presented and discussed in terms comparing the nature of the oxygen atom as a donor to that of the sulfur atom in extractants that are otherwise identical

A Level of Care Instrument for Children\u27s Systems of Care: Construction, Reliability and Validity

The Child and Adolescent Level of Care System/Child and Adolescent Service Intensity Instrument (CALOCUS/ CASH) is designed to help determine the intensity of services needed for a child served in a mental health system of care. The instrument contains eight dimensions that are rated following a comprehensive clinical evaluation. The dimensions are risk of harm, functionality, co-morbidity (psychiatric, substance abuse, development disability and medical), environmental stressors, environmental supports, the child\u27s resiliency, and the child and family\u27s willingness to engage in treatment. An algorithm connects the ratings to a level of care recommendation. The instrument specifies six levels of care defined flexibly enough to consider whatever services are available. The results of psychometric testing using raters with a broad range of clinical experience and training from four different systems of care around the country are presented. The testing demon-strates excellent reliability when rating vignettes. Using children and adolescents in live system of care clinical settings, the CALOCUS/CASH demonstrates reasonable validity when compared with the Child Global Assessment Scale, and the Child and Adolescent Functional Assessment Scale