Lamellae Stability in Confined Systems with Gravity

The microphase separation of a diblock copolymer melt confined by hard walls and in the presence of a gravitational field is simulated by means of a cell dynamical system model. It is found that the presence of hard walls normal to the gravitational field are key ingredients to the formation of well ordered lamellae in BCP melts. To this effect the currents in the directions normal and parallel to the field are calculated along the interface of a lamellar domain, showing that the formation of lamellae parallel to the hard boundaries and normal to the field correspond to the stable configuration. Also, it is found thet the field increases the interface width.Comment: 4 pages, 2 figures, submitted to Physical Review

Synthesis, Stability, and Crystal Structure of an Azulenium Cation Containing an Adamantyl Group

This is the pre-peer reviewed version of the following article: EUROPEAN JOURNAL OF ORGANIC CHEMISTRY. 2008(31):5301-5307 (2008), which has been published in final form at doi:10.1002/ejoc.200800700.ArticleEUROPEAN JOURNAL OF ORGANIC CHEMISTRY. 2008(31):5301-5307 (2008)journal articl

Backscatter from a Spherical Inclusion with Compliant Interphase Characteristics

In studies of scattering by an inclusion it is generally assumed that the inclusion is perfectly bonded to the surrounding matrix material. The actual bond between two materials is, however, generally effected by a thin layer, which may be called an interphase, rather than an interface. It is well known that the mechanical behavior of such an interphase may significantly influence the overall mechanical behavior of a solid containing inclusions.</p

A Novel Heterophilic Antibody Interaction Involves IgG4

IgG4 has been implicated in a diverse set of complex pathologies - e.g. autoimmune pancreatitis (AIP), idiopathic membranous nephropathy - and carries unique features including lack of activation of the classical complement pathway and a dynamic Fab-arm exchange. We recently showed that the rheumatoid factor (RF)-like activity of IgG4 is achieved through a hitherto unknown, Fc-Fc (and not Fab-Fc as is the case in classical RF; CRF) interaction; hence the name, novel RF (NRF). Here, we further explore the resemblance/difference between CRF and NRF. As heterophilic interactions of human IgM RF (CRF) are well known, we checked whether this is the case for IgG4. Human IgG4 showed variable reactivity to animal IgGs: reacting intensely with rabbit and mouse IgGs, but weakly with others. The binding to rabbit IgG was not through the Fab (as in CRF) but via the Fc piece, as was recently shown for human IgG (NRF). This binding correlates with the IgG4 concentration per se and could therefore be of diagnostic usage and incidentally explain some observed interferences in biological assays. In conclusion, here is defined a novel heterophilic antibody interaction and is established the universality of the unique Fc-Fc binding, both involving IgG4.ArticleSCANDINAVIAN JOURNAL OF IMMUNOLOGY. 71(2):109-114 (2010)journal articl

Surgery for acute type A aortic dissection in pregnant patients with Marfan syndrome

ArticleEuropean journal of cardio-thoracic surgery. 28(2): 280-283 (2005)journal articl

Phase Separation Kinetics in a Model with Order-Parameter Dependent Mobility

We present extensive results from 2-dimensional simulations of phase separation kinetics in a model with order-parameter dependent mobility. We find that the time-dependent structure factor exhibits dynamical scaling and the scaling function is numerically indistinguishable from that for the Cahn-Hilliard (CH) equation, even in the limit where surface diffusion is the mechanism for domain growth. This supports the view that the scaling form of the structure factor is "universal" and leads us to question the conventional wisdom that an accurate representation of the scaled structure factor for the CH equation can only be obtained from a theory which correctly models bulk diffusion.Comment: To appear in PRE, figures available on reques

Coarsening Dynamics of a One-Dimensional Driven Cahn-Hilliard System

We study the one-dimensional Cahn-Hilliard equation with an additional driving term representing, say, the effect of gravity. We find that the driving field $E$ has an asymmetric effect on the solution for a single stationary domain wall (or `kink'), the direction of the field determining whether the analytic solutions found by Leung [J.Stat.Phys.{\bf 61}, 345 (1990)] are unique. The dynamics of a kink-antikink pair (`bubble') is then studied. The behaviour of a bubble is dependent on the relative sizes of a characteristic length scale $E^{-1}$, where $E$ is the driving field, and the separation, $L$, of the interfaces. For $EL \gg 1$ the velocities of the interfaces are negligible, while in the opposite limit a travelling-wave solution is found with a velocity $v \propto E/L$. For this latter case ($EL \ll 1$) a set of reduced equations, describing the evolution of the domain lengths, is obtained for a system with a large number of interfaces, and implies a characteristic length scale growing as $(Et)^{1/2}$. Numerical results for the domain-size distribution and structure factor confirm this behavior, and show that the system exhibits dynamical scaling from very early times.Comment: 20 pages, revtex, 10 figures, submitted to Phys. Rev.

One-loop contributions of charginos and neutralinos to W-pair production in E+ E- collisions

We study the one-loop effects of charginos and neutralinos on the helicity amplitudes for \eeww in the minimal supersymmetric standard model. The calculation is tested by using two methods. First, the sum rule for the form factors between \eeww and the process where the external $W^\pm$ bosons are replaced by the corresponding Goldstone bosons $\omega^\pm$ is employed to test the analytic expression and the accuracy of the numerical program. Second, the decoupling property in the large mass limit is used to test the overall normalization of the amplitudes. These two tests are most effectively carried out when the amplitudes are expanded in terms of the modified minimal subtraction ($\bar{\rm MS}$) couplings of the standard model. The resulting perturbation expansion is valid at collider energies below and around the threshold of the light supersymmetric particles. We find that the corrections to the cross section of the longitudinally polarized $W$-pair production can be as large as -1.4% at the threshold of the light chargino-pair production for large scattering angles. We also study the effects of the CP-violating phase in the chargino and neutralino sectors on the helicity amplitudes. We find that the resulting CP-violating asymmetries can be at most 0.1%.Comment: 30 pages, 25 figures, Final verision, To appear in Physical Review D, Several sentences are improve