Cross Metathesis Assisted Solid-Phase Synthesis of Glycopeptoids

A solid-phase synthesis of glycopeptoids was explored through olefin cross metathesis (CM). Peptoids and sugar derivatives with appropriate olefin moieties were coupled in the presence of an olefin metathesis catalyst to afford glycopeptoids in good yields. This systematic solid-phase CM study can provide facile access to the molecular sources of glycopeptidomimetics and postchemical modifications on various molecular scaffolds

The Light and Period Variations of the Eclipsing Binary AA Ursae Majoris

We present new multiband CCD photometry for AA UMa made on 8 nights between January and March 2009; the $R$ light curves are the first ever compiled. Historical light curves, as well as ours, display partial eclipses and inverse O'Connell effects with Max I fainter than Max II. Among possible spot models, a cool spot on either of the component stars and its variability with time permit good light-curve representations for the system. A total of 194 eclipse timings over 81 yrs, including our five timings, were used for ephemeris computations. We found that the orbital period of the system has varied due to a periodic oscillation overlaid on an upward parabolic variation. The continuous period increase at a fractional rate of $+$1.3$\times$10$^{-10}$ is consistent with that calculated from the W-D code and can be interpreted as a thermal mass transfer from the less to the more massive secondary star at a rate of 6.6$\times$10$^{-8}$ M$_\odot$ yr$^{-1}$. The periodic component is in satisfactory accord with a light-time effect due to an unseen companion with a period of 28.2 yrs, a semi-amplitude of 0.007 d, and a minimum mass of $M_3 \sin i_3$=0.25 $M_\odot$ but this period variation could also arise from magnetic activity.Comment: 23 pages, including 5 figures and 8 tables, accepted for publication in PAS

Amplitude death in a ring of nonidentical nonlinear oscillators with unidirectional coupling

We study the collective behaviors in a ring of coupled nonidentical nonlinear oscillators with unidirectional coupling, of which natural frequencies are distributed in a random way. We find the amplitude death phenomena in the case of unidirectional couplings and discuss the differences between the cases of bidirectional and unidirectional couplings. There are three main differences; there exists neither partial amplitude death nor local clustering behavior but oblique line structure which represents directional signal flow on the spatio-temporal patterns in the unidirectional coupling case. The unidirectional coupling has the advantage of easily obtaining global amplitude death in a ring of coupled oscillators with randomly distributed natural frequency. Finally, we explain the results using the eigenvalue analysis of Jacobian matrix at the origin and also discuss the transition of dynamical behavior coming from connection structure as coupling strength increases.Comment: 14 pages, 11 figure

Conventional Vickers and true instrumented indentation hardness determined by instrumented indentation tests

We evaluate Vickers hardness and true instrumented indentation test (IIT) hardness of 24 metals over a wide range of mechanical properties using just IIT parameters by taking into account the real contact morphology beneath the Vickers indenter. Correlating the conventional Vickers hardness, indentation contact morphology, and IIT parameters for the 24 metals reveals relationships between contact depths and apparent material properties. We report the conventional Vickers and true IIT hardnesses measured only from IIT contact depths; these agree well with directly measured hardnesses within ±6% for Vickers hardness and ±10% for true IIT hardness