19 research outputs found
Radiative charge transfer lifetime of the excited state of (NaCa)
New experiments were proposed recently to investigate the regime of cold
atomic and molecular ion-atom collision processes in a special hybrid
neutral-atom--ion trap under high vacuum conditions. The collisional cooling of
laser pre-cooled Ca ions by ultracold Na atoms is being studied. Modeling
this process requires knowledge of the radiative lifetime of the excited
singlet A state of the (NaCa) molecular system. We calculate
the rate coefficient for radiative charge transfer using a semiclassical
approach. The dipole radial matrix elements between the ground and the excited
states, and the potential curves were calculated using Complete Active Space
Self-Consistent field and M\"oller-Plesset second order perturbation theory
(CASSCF/MP2) with an extended Gaussian basis, 6-311+G(3df). The semiclassical
charge transfer rate coefficient was averaged over a thermal Maxwellian
distribution. In addition we also present elastic collision cross sections and
the spin-exchange cross section. The rate coefficient for charge transfer was
found to be cm/sec, while those for the elastic and
spin-exchange cross sections were found to be several orders of magnitude
higher ( cm/sec and cm/sec,
respectively). This confirms our assumption that the milli-Kelvin regime of
collisional cooling of calcium ions by sodium atoms is favorable with the
respect to low loss of calcium ions due to the charge transfer.Comment: 4 pages, 5 figures; v.2 - conceptual change
Metastable neon collisions: anisotropy and scattering length
In this paper we investigate the effective scattering length of
spin-polarized Ne*. Due to its anisotropic electrostatic interaction, its
scattering length is determined by five interaction potentials instead of one,
even in the spin-polarized case, a unique property among the Bose condensed
species and candidates. Because the interaction potentials of Ne* are not known
accurately enough to predict the value of the scattering length, we investigate
the behavior of as a function of the five phase integrals corresponding to
the five interaction potentials. We find that the scattering length has five
resonances instead of only one and cannot be described by a simple gas-kinetic
approach or the DIS approximation. However, the probability for finding a
positive or large value of the scattering length is not enhanced compared to
the single potential case. The complex behavior of is studied by comparing
a quantum mechanical five-channel numerical calculation to simpler two-channel
models. We find that the induced dipole-dipole interaction is responsible for
coupling between the different |\Omega> states, resulting in an inhomogeneous
shift of the resonance positions and widths in the quantum mechanical
calculation as compared to the DIS approach. The dependence of the resonance
positions and widths on the input potentials turns out to be rather
straightforward. The existence of two bosonic isotopes of Ne* enables us to
choose the isotope with the most favorable scattering length for efficient
evaporative cooling towards the Bose-Einstein Condensation transition, greatly
enhancing the feasibility to reach this transition.Comment: 13pages, 8 eps figures, analytical model in section V has been
remove
Collective dynamics of internal states in a Bose gas
Theory for the Rabi and internal Josephson effects in an interacting Bose gas
in the cold collision regime is presented. By using microscopic transport
equation for the density matrix the problem is mapped onto a problem of
precession of two coupled classical spins. In the absence of an external
excitation field our results agree with the theory for the density induced
frequency shifts in atomic clocks. In the presence of the external field, the
internal Josephson effect takes place in a condensed Bose gas as well as in a
non-condensed gas. The crossover from Rabi oscillations to the Josephson
oscillations as a function of interaction strength is studied in detail.Comment: 18 pages, 2 figure
Trap losses induced by near-resonant Rydberg dressing of cold atomic gases
The near-resonant dressing of cold strontium gases and Bose-Einstein condensates contained in an optical dipole trap (ODT) with the 5s30s3S1 Rydberg state is investigated as a function of the effective two-photon Rabi frequency, detuning, and dressing time. The measurements demonstrate that a rapid decrease in the ground-state atom population in the ODT occurs even for weak dressing and when well detuned from resonance. This decrease is attributed to Rydberg atom excitation, which can lead to direct escape from the trap and to population of very long-lived 5s5p3P0,2 metastable states. The effects of interactions between Rydberg atoms, including those populated by blackbody radiation, are analyzed. The work has important implications when considering the use of Rydberg dressing to control the interactions between dressed ground-state atoms