618 research outputs found
Photoionization of tungsten ions: experiment and theory for W
Experimental and theoretical results are reported for single-photon single
ionization of the tungsten ion W. Absolute cross sections have been
measured employing the photon-ion merged-beams setup at the Advanced Light
Source in Berkeley. Detailed photon-energy scans were performed at 200~meV
bandwidth in the 40 -- 105~eV range. Theoretical results have been obtained
from a Dirac-Coulomb R-matrix approach employing basis sets of 730 levels for
the photoionization of W. Calculations were carried out for the
, =2, ground level and the
associated fine-structure levels with =3 and 4 for the W ions. In
addition, cross sections have been calculated for the metastable levels
. Very satisfying agreement of theory and experiment is
found for the photoionization cross section of W which is remarkable
given the complexity of the electronic structure of tungsten ions in low charge
states.Comment: 15 pages, 3 figures, to appear in the Journal of Physics B: Atomic,
Molecular and Optical Physic
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Polarization control at the microscopic and electronic structure observatory
The new Microscopic and Electronic Structure Observatory (MAESTRO) at the Advanced Light Source (ALS) in Berkeley provides X-rays of variable polarization, produced by an elliptically polarized undulator (EPU), for angle resolved photoemission (ARPES) and photoemission electron microscopy (PEEM) experiments. The interpretation of photoemission data, in particular of dichroism effects in ARPES, requires the precise knowledge of the exact polarization state. Numerical simulations show that the first harmonics of the EPU at MAESTRO provides soft X-rays of almost 100% on axis polarization. However, the higher harmonics as well as the downstream optical elements of the beamline, have a considerable impact on the polarization of the light delivered to the experimental end-station. Employing a simple reflective polarimeter, the polarization is characterized for variable EPU and beamline settings and the overall degree of polarization in the MAESTRO end-stations is estimated to be on the order of 83%
Single-photon single ionization of W ions: experiment and theory
Experimental and theoretical results are reported for photoionization of
Ta-like (W) tungsten ions. Absolute cross sections were measured in the
energy range 16 to 245 eV employing the photon-ion merged-beam setup at the
Advanced Light Source in Berkeley. Detailed photon-energy scans at 100 meV
bandwidth were performed in the 16 to 108 eV range. In addition, the cross
section was scanned at 50 meV resolution in regions where fine resonance
structures could be observed. Theoretical results were obtained from a
Dirac-Coulomb R-matrix approach. Photoionization cross section calculations
were performed for singly ionized atomic tungsten ions in their , =1/2, ground level and the associated
excited metastable levels with =3/2, 5/2, 7/2 and 9/2. Since the ion beams
used in the experiments must be expected to contain long-lived excited states
also from excited configurations, additional cross-section calculations were
performed for the second-lowest term, 5d^5 \; ^6{\rm S}_{J}, =5/2, and for
the F term, 5d^3 6s^2 \; ^4{\rm F}_{J}, with = 3/2, 5/2, 7/2 and 9/2.
Given the complexity of the electronic structure of W the calculations
reproduce the main features of the experimental cross section quite well.Comment: 23 pages, 7 figures, 1 table: Accepted for publication in J. Phys. B:
At. Mol. & Opt. Phy
Three Dimensional Mapping of Texture in Dental Enamel
We have used synchrotron x-ray diffraction to study the crystal orientation in human dental enamel as a function of position within intact tooth sections. Keeping tooth sections intact has allowed us to construct 2D and 3D spatial distribution maps of the magnitude and orientation of texture in dental enamel. We have found that the enamel crystallites are most highly aligned at the expected occlusal points for a maxillary first premolar, and that the texture direction varies spatially in a three dimensional curling arrangement. Our results provide a model for texture in enamel which can aid researchers in developing dental composite materials for fillings and crowns with optimal characteristics for longevity, and will guide clinicians to the best method for drilling into enamel, in order to minimize weakening of remaining tooth structure, during dental restoration procedure
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Absolute single photoionization cross-sections of Br3+: Experiment and theory
Absolute single photoionization cross section measurements for Br3+ ions are reported in the photon energy range 44.79-59.54 eV at a photon energy resolution of 21 ±3 meV. Measurements were performed at the Advanced Light Source at Lawrence Berkeley National Laboratory using the merged-beams technique. Numerous resonance features in the experimental spectrum are assigned and their energies and quantum defect values are tabulated. The cross-section measurements are also compared with Breit-Pauli R-matrix calculations with suitable agreement over the photon energy range investigated. Analysis of the measured spectrum including Rydberg resonance series identifications produced a new emperical determination of the ionizational potential of Br3+ of 46.977 ± 0.050 eV, which is 805 meV lower than the most recently published value of 47.782 eV. This disparity between our determination and the earlier published value is similar to an 843 meV shift in the accepted ionization potential published for iso-electronic Se2+ as part of this same research program
Advances in Atomic Data for Neutron-Capture Elements
Neutron(n)-capture elements (atomic number Z>30), which can be produced in
planetary nebula (PN) progenitor stars via s-process nucleosynthesis, have been
detected in nearly 100 PNe. This demonstrates that nebular spectroscopy is a
potentially powerful tool for studying the production and chemical evolution of
trans-iron elements. However, significant challenges must be addressed before
this goal can be achieved. One of the most substantial hurdles is the lack of
atomic data for n-capture elements, particularly that needed to solve for their
ionization equilibrium (and hence to convert ionic abundances to elemental
abundances). To address this need, we have computed photoionization cross
sections and radiative and dielectronic recombination rate coefficients for the
first six ions of Se and Kr. The calculations were benchmarked against
experimental photoionization cross section measurements. In addition, we
computed charge transfer (CT) rate coefficients for ions of six n-capture
elements. These efforts will enable the accurate determination of nebular Se
and Kr abundances, allowing robust investigations of s-process enrichments in
PNe.Comment: To be published in IAU Symp. 283: Planetary Nebulae, an Eye to the
Future; 2 page
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