Resolving the extended stellar atmospheres of Asymptotic Giant Branch stars at (sub-)millimetre wavelengths

The initial conditions for the mass loss during the asymptotic giant branch (AGB) phase are set in their extended atmospheres, where, among others, convection and pulsation driven shocks determine the physical conditions. High resolution observations of AGB stars at (sub)millimetre wavelengths can now directly determine the morphology, activity, density, and temperature close to the stellar photosphere. We used the Atacama Large Millimeter/submillimeter Array (ALMA) high angular resolution observations to resolve the extended atmospheres of four of the nearest AGB stars: W Hya, Mira A, R Dor and R Leo. We interpreted the observations using a parameterised atmosphere model. We resolve all four AGB stars and determine the brightness temperature structure between $1$ and $2$ stellar radii. For W Hya and R Dor we confirm the existence of hotspots with brightness temperatures $>3000$ to $10000$~K. All four stars show deviations from spherical symmetry. We find variations on a timescale of days to weeks, and for R Leo we directly measure an outward motion of the millimetre wavelength surface with a velocity of at least $10.6\pm1.4$~km~s$^{-1}$. For all objects but W Hya we find that the temperature-radius and size-frequency relations require the existence of a (likely inhomogeneous) layer of enhanced opacity. The ALMA observations provide a unique probe of the structure of the extended AGB atmosphere. We find highly variable structures of hotspots and likely convective cells. In the future, these observations can be directly compared to multi-dimensional chromosphere and atmosphere models that determine the temperature, density, velocity, and ionisation structure between the stellar photosphere and the dust formation region. However, our results show that for the best interpretation, both very accurate flux calibration and near-simultaneous observations are essential.Comment: 18 pages, 13 figures, Accepted to A&A, final version after language editin

CO and HCN isotopologue ratios in the outflows of AGB stars

Isotopologue line intensity ratios of circumstellar molecules have been widely used to trace the photospheric elemental isotopic ratios of evolved stars. However, depending on the molecular species and the physical conditions of the environment, the circumstellar isotopologue ratio may deviate considerably from the stellar atmospheric value. In this paper, we aim to examine how the CO and HCN abundance ratios vary radially due to chemical reactions in the outflows of AGB stars and the effect of excitation and optical depth on the resulting line intensity ratios. We find that the circumstellar 12CO/13CO can deviate from its atmospheric value by up to 25-94% and 6-60% for C- and O-type CSEs, respectively. We show that variations of the intensity of the ISRF and the gas kinetic temperature can significantly influence the CO isotopologue ratio in the outer CSEs. On the contrary, the H12CN/H13CN ratio is stable for all tested mass-loss rates. The RT modeling shows that the integrated line intensity ratio of CO of different rotational transitions varies significantly for stars with intermediate mass-loss rates due to combined chemical and excitation effects. In contrast, the excitation conditions for the both HCN isotopologues are the same. We demonstrate the importance of using the isotopologue abundance profiles from chemical models as inputs to RT models in the interpretation of isotopologue observations. Previous studies of CO isotopologue ratios are based on multi-transition data for individual sources and it is difficult to estimate the errors in the reported values due to assumptions that are not entirely correct according to this study. If anything, previous studies may have overestimated the circumstellar 12CO/13CO abundance ratio. The use of the HCN as a tracer of C isotope ratios is affected by fewer complicating problems, provided one accounts corrections for high optical depths.Comment: 14 pages, 11 figure

ALMA observations of the vibrationally-excited rotational CO transition v=1,J=3−2v=1, J=3-2 towards five AGB stars

We report the serendipitous detection with ALMA of the vibrationally-excited pure-rotational CO transition $v=1, J=3-2$ towards five asymptotic giant branch (AGB) stars, $o$ Cet, R Aqr, R Scl, W Aql, and $\pi^1$ Gru. The observed lines are formed in the poorly-understood region located between the stellar surface and the region where the wind starts, the so-called warm molecular layer. We successfully reproduce the observed lines profiles using a simple model. We constrain the extents, densities, and kinematics of the region where the lines are produced. R Aqr and R Scl show inverse P-Cygni line profiles which indicate infall of material onto the stars. The line profiles of $o$ Cet and R Scl show variability. The serendipitous detection towards these five sources shows that vibrationally-excited rotational lines can be observed towards a large number of nearby AGB stars using ALMA. This opens a new possibility for the study of the innermost regions of AGB circumstellar envelopes.Comment: 6 pages, 2 figures, 2 tables, 2016MNRAS.463L..74

Influence of additives on decrease of temperature of slag flow from energy coal in wet bottom boiler

This paper describes the features of the energy coal combusted in a power plant, its impact on energy production, while the possibility of using natural and secondary raw materials to modify the properties of energy coal. All selected types of additives (fluorspar, de-metallized steelmaking slag (DSS), dolomite, and limestone) in admixture of coal have clearly proved their ability to reduce the pour point of the ash in the laboratory experiments. The highest decrease of the temperature at 5 % of the additive was achieved by fluorspar and dolomite from the temperature of 1 593 °C to the temperature of 1 307 °C. In terms of the economy and the availability of the additives the most suitable seems to be DSS

HD101584: Circumstellar characteristics and evolutionary status

We have performed a study of the characteristics of the circumstellar environment of the binary object HD101584, that provides information on a likely evolutionary scenario. We have obtained and analysed ALMA observations, complemented with observations using APEX, of a large number of molecular lines. An analysis of the spectral energy distribution has also been performed. Emissions from 12 molecular species (not counting isotopologues) have been observed, and most of them mapped with angular resolutions in the range 0.1" to 0.6". Four circumstellar components are identified: i) a central compact source of size 0.15", ii) an expanding equatorial density enhancement (a flattened density distribution in the plane of the orbit) of size 3", iii) a bipolar high-velocity outflow (150 km/s), and iv) an hourglass structure. The outflow is directed almost along the line of sight. There is evidence of a second bipolar outflow. The mass of the circumstellar gas is 0.5[D/1 kpc]^2 Msun, about half of it lies in the equatorial density enhancement. The dust mass is 0.01[D/1 kpc]^2 Msun, and a substantial fraction of this is in the form of large-sized, up to 1 mm, grains. The estimated kinetic age of the outflow is 770[D/1 kpc] yr. The kinetic energy and the scalar momentum of the accelerated gas are estimated to be 7x10^(45)[D/1 kpc]^2 erg and 10^(39)[D/1 kpc]^2 g cm/s, respectively. We provide good evidence that the binary system HD101584 is in a post-common-envelope-evolution phase, that ended before a stellar merger. Isotope ratios combined with stellar mass estimates suggest that the primary star's evolution was terminated already on the first red giant branch (RGB). Most of the energy required to drive the outflowing gas was probably released when material fell towards the companion.Comment: Accepted for publication in A&

Modelling of copper and zinc adsorption onto zeolite

Adsorption of Cu(II) and Zn(II) ions from metallurgical solutions has been studied and the adsorption capacity of zeolite (Nižný Hrabovec, SK) has been determined. Zeolites are characterized by relatively high sorption capacity, i.e. Cu(II) and Zn(II) can be removed even at relatively low concentrations. The experiments were realised in a batch system and evaluated using isotherms. According to the results of the experiments the adsorption equilibrium of Cu(II) and Zn(II) on zeolite was best described by Freundlich isotherm. The maximum sorption capacity was 1,48 and 1,49 mg/g for Cu(II) and Zn(II), respectively. The experimental results of this study demonstrate that zeolite is suitable for adsorption of copper and zinc from aqueous solutions at low concentrations