Occurrence of arsenic in the riverbed sediments of the Selenga river system

Over the past few decades, anthropogenic activities have concentrated in the transboundary Selenga River basin, especially in the two-thirds of it located in the Mongolian territory. In this study, we measure the concentration of arsenic (As) in riverbed sediments and the mobilization and accumulation of this metalloid in sediments of the Selenga River system. Higher concentrations of As were detected in the sediments collected from the Orkhon River system than those from downstream of Selenga River in Russia. The observed difference indicates that the Orkhon River watershed is highly affected by anthropogenic activities involving soil excavation. In particular, high concentrations of As (3.6-4.9 mg kg^), in comparison with the average for the entire Selenga River system (2.8 mg kg^), were detected in sediment samples collected downstream of gold mining areas and near Darkhan City. Around this city, As pollution might be related to the combustion of coal with high As content. Gold mining is a main source of As pollution in rural areas. Notably, the content of fine fractions in sediment samples collected downstream of the Zaamar mining area was half that measured in samples collected upstream of it. However, no correlation was observed between As concentration and fine particle content in sediment samples collected throughout the whole research area, suggesting that the proportion of fine particle sediments is not a controlling factor in As distribution in the riverbed. Heavy and coarse particles released by mining sites seem to quickly deposit on the riverbed near their source. However, fine particles can co-precipitate at river junctions due to changes in water quality. These deposition processes can limit the extent to which As pollution can spread in a large area, but redissolution of As from secondary minerals is now recognized as a key factor in the widespread groundwater As contamination observed around the world