Coloration of natural beryl by iron ion implantation

Natural colorless crystals of Ural beryl were implanted at room temperature with 40 keV Fe+ ions with fluences in the range of 0.5-1.5×1017 ion/cm2. As-implanted samples show dark-grey tone due to radiation damage of beryl crystal. Subsequent thermal annealing of irradiated crystals in oxygen at 600 °C for 30 min results in the color change, to yellowish or yellow-orange tones with golden luster, depending on value of iron fluence. The nature of beryl coloration was studied by optical absorption, Mössbauer and Rutherford backscattering (RBS) spectroscopes. It was established that the thermal treatment of iron-irradiated beryl lead to inward diffusive redistribution of iron ions. An appearance of optical absorption bands connected with charge-transfers O2-→FeVI 3+ and O2-→FeIV 2+, FeIV 3+ determine the yellow tone in colored beryls. Most of implanted iron ions are founded in both tetrahedral FeIV 2+ and octahedral FeVI 3+ sites where they may substitute beryllium and aluminum host ions by isomorphic way. © 2003 Elsevier Science B.V. All rights reserved

Magnetic Resonance Study of Fe-Implanted TiO<inf>2</inf> Rutile

© 2017, Springer-Verlag Wien.Single-crystal (100) and (001) TiO2 rutile substrates have been implanted with 40 keV Fe+ at room temperature with high doses in the range of (0.5–1.5) × 1017 ions/cm2. A ferromagnetic resonance (FMR) signal has been observed for all samples with the intensity and the out-of-plane anisotropy increasing with the implantation dose. The FMR signal has been related to the formation of a percolated metal layer consisting of close-packed iron nanoparticles in the implanted region of TiO2 substrate. Electron spin resonance (ESR) signal of paramagnetic Fe3+ ions substituting Ti4+ positions in the TiO2 rutile structure has been also observed. The dependences of FMR resonance fields on the DC magnetic field orientation reveal a strong in-plane anisotropy for both (100) and (001) substrate planes. An origin of the in-plane anisotropy of FMR signal is attributed to the textured growth of the iron nanoparticles. As result of the nanoparticle growth aligned with respect to the structure of the rutile host, the in-plane magnetic anisotropy of the samples reflects the symmetry of the crystal structure of the TiO2 substrates. Crystallographic directions of the preferential growth of iron nanoparticles have been determined by computer modeling of anisotropic ESR signal of substitutional Fe3+ ions

Gizli el

Reşat Nuri'nin Dersaadet'te yayımlanan Gizli El adlı romanının ilk ve son tefrikalarıTelif hakları nedeniyle romanın tam metni verilememiştir

The reaction of triphenylarsine oxide with ethyl Iodo-acetate leading to triphenyl (carboethoxy)methylarsonium triiodide

New data are presented for some processes accompaning "retro-Arbuzov" reaction of tertiary arsine oxides with halogen-containing reagents. Triphenyl (carboethoxy)methylarsonium triiodide 10a was obtained in the reaction of triphenylarsine oxide la with excess of ethyl iodoacetate 2a. The structure of 10a was established by X-ray single crystal diffraction. © 2004 Wiley Periodicals, Inc

Disilyl dithiophosphonates in the synthesis of open chain and cyclic organothiophosphorus compounds

O-(Trimethylsiloxy)alkyl S-trimethylsilyl aryldithiophosphonates 7a-d were obtained by the reaction of 2,4-diaryl-1,3,2,4-dithiadiphosphetane-2,4- disulfides 5a,b with disilyl derivatives of glycols 6a,c and salicyl alcohol 6b. The reactions of mixed O,S-bis(trimethylsilyl) 2,4-di(3,5-di-tert-butyl-4- hydroxyphenyl)dithiophosphonate 1 and S-silyl aryldithiophosphonates 7a,b with S,S-diethyldithiodiphenylgermane 2, dichlorodiphenylgermane 8a, and dichlorodiphenylstannane 8b were studied. The structure of hexaphenyl-2,4,6,1,3, 5-trithiatrigerminane 11 was established by X-ray single crystal diffraction. © 2004 Wiley Periodicals, Inc

Coloration of natural beryl by iron ion implantation

Natural colorless crystals of Ural beryl were implanted at room temperature with 40 keV Fe+ ions with fluences in the range of 0.5-1.5×1017 ion/cm2. As-implanted samples show dark-grey tone due to radiation damage of beryl crystal. Subsequent thermal annealing of irradiated crystals in oxygen at 600 °C for 30 min results in the color change, to yellowish or yellow-orange tones with golden luster, depending on value of iron fluence. The nature of beryl coloration was studied by optical absorption, Mössbauer and Rutherford backscattering (RBS) spectroscopes. It was established that the thermal treatment of iron-irradiated beryl lead to inward diffusive redistribution of iron ions. An appearance of optical absorption bands connected with charge-transfers O2-→FeVI 3+ and O2-→FeIV 2+, FeIV 3+ determine the yellow tone in colored beryls. Most of implanted iron ions are founded in both tetrahedral FeIV 2+ and octahedral FeVI 3+ sites where they may substitute beryllium and aluminum host ions by isomorphic way. © 2003 Elsevier Science B.V. All rights reserved

Coloration of natural beryl by iron ion implantation

Natural colorless crystals of Ural beryl were implanted at room temperature with 40 keV Fe+ ions with fluences in the range of 0.5-1.5×1017 ion/cm2. As-implanted samples show dark-grey tone due to radiation damage of beryl crystal. Subsequent thermal annealing of irradiated crystals in oxygen at 600 °C for 30 min results in the color change, to yellowish or yellow-orange tones with golden luster, depending on value of iron fluence. The nature of beryl coloration was studied by optical absorption, Mössbauer and Rutherford backscattering (RBS) spectroscopes. It was established that the thermal treatment of iron-irradiated beryl lead to inward diffusive redistribution of iron ions. An appearance of optical absorption bands connected with charge-transfers O2-→FeVI 3+ and O2-→FeIV 2+, FeIV 3+ determine the yellow tone in colored beryls. Most of implanted iron ions are founded in both tetrahedral FeIV 2+ and octahedral FeVI 3+ sites where they may substitute beryllium and aluminum host ions by isomorphic way. © 2003 Elsevier Science B.V. All rights reserved

Coloration of natural beryl by iron ion implantation

Natural colorless crystals of Ural beryl were implanted at room temperature with 40 keV Fe+ ions with fluences in the range of 0.5-1.5×1017 ion/cm2. As-implanted samples show dark-grey tone due to radiation damage of beryl crystal. Subsequent thermal annealing of irradiated crystals in oxygen at 600 °C for 30 min results in the color change, to yellowish or yellow-orange tones with golden luster, depending on value of iron fluence. The nature of beryl coloration was studied by optical absorption, Mössbauer and Rutherford backscattering (RBS) spectroscopes. It was established that the thermal treatment of iron-irradiated beryl lead to inward diffusive redistribution of iron ions. An appearance of optical absorption bands connected with charge-transfers O2-→FeVI 3+ and O2-→FeIV 2+, FeIV 3+ determine the yellow tone in colored beryls. Most of implanted iron ions are founded in both tetrahedral FeIV 2+ and octahedral FeVI 3+ sites where they may substitute beryllium and aluminum host ions by isomorphic way. © 2003 Elsevier Science B.V. All rights reserved