3 research outputs found
Highly Bendable, Conductive, and Transparent Film by an Enhanced Adhesion of Silver Nanowires
Recently,
silver nanowires (AgNWs) have attracted considerable
interest for their potential application in flexible transparent conductive
films (TCFs). One challenge for the commercialization of AgNW-based
TCFs is the low conductivity and stability caused by the weak adhesion
forces between the AgNWs and the substrate. Here, we report a highly
bendable, conductive, and transparent AgNW film, which consists of
an underlying polyÂ(diallyldimethyl-ammonium chloride) (PDDA) and AgNW
composite bottom layer and a top layer-by-layer (LbL) assembled graphene
oxide (GO) and PDDA overcoating layer (OCL). We demonstrated that
PDDA could increase the adhesion between the AgNW and the substrate
to form a uniform AgNW network and could also serve to improve the
stability of the GO OCL. Hence, a highly bendable, conductive, and
transparent AgNW–PDDA–GO composite TCF on a polyÂ(ethylene
terephthalate) (PET) substrate with Rs ≈ 10 Ω/sq and <i>T</i> ≈ 91% could be made by an all-solution processable
method at room temperature. In addition, our AgNW–PDDA–GO
composite TCF is stable without degradation after exposure to H<sub>2</sub>S gas or sonication
Highly Bendable, Conductive, and Transparent Film by an Enhanced Adhesion of Silver Nanowires
Recently,
silver nanowires (AgNWs) have attracted considerable
interest for their potential application in flexible transparent conductive
films (TCFs). One challenge for the commercialization of AgNW-based
TCFs is the low conductivity and stability caused by the weak adhesion
forces between the AgNWs and the substrate. Here, we report a highly
bendable, conductive, and transparent AgNW film, which consists of
an underlying polyÂ(diallyldimethyl-ammonium chloride) (PDDA) and AgNW
composite bottom layer and a top layer-by-layer (LbL) assembled graphene
oxide (GO) and PDDA overcoating layer (OCL). We demonstrated that
PDDA could increase the adhesion between the AgNW and the substrate
to form a uniform AgNW network and could also serve to improve the
stability of the GO OCL. Hence, a highly bendable, conductive, and
transparent AgNW–PDDA–GO composite TCF on a polyÂ(ethylene
terephthalate) (PET) substrate with Rs ≈ 10 Ω/sq and <i>T</i> ≈ 91% could be made by an all-solution processable
method at room temperature. In addition, our AgNW–PDDA–GO
composite TCF is stable without degradation after exposure to H<sub>2</sub>S gas or sonication
Vertical Alignments of Graphene Sheets Spatially and Densely Piled for Fast Ion Diffusion in Compact Supercapacitors
Supercapacitors with porous carbon structures have high energy storage capacity. However, the porous nature of the carbon electrode, composed mainly of carbon nanotubes (CNTs) and graphene oxide (GO) derivatives, negatively impacts the volumetric electrochemical characteristics of the supercapacitors because of poor packing density (<0.5 g cm<sup>–3</sup>). Herein, we report a simple method to fabricate highly dense and vertically aligned reduced graphene oxide (VArGO) electrodes involving simple hand-rolling and cutting processes. Because of their vertically aligned and opened-edge graphene structure, VArGO electrodes displayed high packing density and highly efficient volumetric and areal electrochemical characteristics, very fast electrolyte ion diffusion with rectangular CV curves even at a high scan rate (20 V/s), and the highest volumetric capacitance among known rGO electrodes. Surprisingly, even when the film thickness of the VArGO electrode was increased, its volumetric and areal capacitances were maintained