6 research outputs found

    How activated carbon improves the performance of non-thermal plasma removing methyl ethyl ketone from a gas stream

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    The combination of non-thermal plasma (NTP), operated at room temperature and at atmospheric pressure in air and in combination with activated carbon filters offers a more efficient removal of VOCs from gas streams than each individual method alone. Efficiencies, synergies and mechanisms of this combination were investigated by means of comprehensive quantitative Fourier transform infrared spectroscopy analysis. Therefore, dry and wet synthetic air containing about 90 ppm of methyl ethyl ketone (MEK) were treated with non-thermal plasma (NTP) and an intentionally undersized activated carbon (AC) filter, separately and in combination. As a result, removal of about 50 % was achieved for NTP or AC alone but a removal close to 95 % was found for the combination. Ozone, generated by the NTP, was reduced by 55 % with the AC-filter. For the operation of the NTP with humid air, a decomposition of the pollutant on AC was observed even after the plasma was switched off

    Discharge propagation on a dielectric surface in a single-filament arrangement

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    Discharge development and streamer propagation on a dielectric surface were investigated in nitrogen-oxygen gas mixtures at atmospheric pressure. A coaxial pin-to-pin arrangement was used to generate single surface discharges driven by positive unipolar square wave high voltages of between 7 and 9 kV at 4.3 kHz. The development of surface discharges was recorded by ICCD and streak cameras. The discharges developed on the surface using pin electrodes attached directly to the dielectric plate. The accumulation over several discharge events showed a propagation front evolving from the electrode tip, while images of single discharges showed a non-uniform and branched structure of discharge channels. The electrode polarity influenced the discharge expansion and propagation velocity. Positive polarity of the metallic electrode (rising slope of HV pulses) led to a cathode-directed streamer with higher propagation velocities (5 Ă— 105 m/s) than for negative polarity (relative to surface charges; falling slope). The increase in the O2 content in N2 from 0.1 to 20 vol% resulted in a decrease in discharge duration and an increase in streamer velocities

    Impact of volume and surface processes on the pre-ionization of dielectric barrier discharges: advanced diagnostics and fluid modeling

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    The phenomenology and breakdown mechanism of dielectric barrier discharges are strongly determined by volume and surface memory effects. In particular, the pre-ionization provided by residual species in the volume or surface charges on the dielectrics influences the breakdown behavior of filamentary and diffuse discharges. This was investigated by advanced diagnostics such as streak camera imaging, laser photodetachment of negative ions and laser photodesorption of electrons from dielectric surfaces in correlation with 1D fluid modeling. The streak camera images show that an increasing number of residual charges in the volume changes the microdischarge breakdown in air-like gas mixtures from a cathode-directed streamer to a simultaneous propagation of cathode- and anode-directed streamers. In contrast, seed electrons are important for the pre-ionization if the density of residual charges in the volume is low. One source of seed electrons are negative ions, whose density exceeds the electron density during the pre-phase of diffuse helium–oxygen barrier discharges as indicated by the laser photodetachment experiments. Electrons desorbed from the cathodic dielectric have an even larger influence. They induce a transition from the glow-like to the Townsend-like discharge mode in nominally pure helium. Apart from analyzing the importance of the pre-ionization for the breakdown mechanism, the opportunities for manipulating the lateral structure and discharge modes are discussed. For this purpose, the intensity and diameter of a diffuse discharge in helium are controlled by an illuminated semiconducting barrier
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