Bifurcation structure of two Coupled Periodically driven double-well Duffing Oscillators

The bifurcation structure of coupled periodically driven double-well Duffing oscillators is investigated as a function of the strength of the driving force $f$ and its frequency $\Omega$. We first examine the stability of the steady state in linear response, and classify the different types of bifurcation likely to occur in this model. We then explore the complex behaviour associated with these bifurcations numerically. Our results show many striking departures from the behaviour of coupled driven Duffing Oscillators with single well-potentials, as characterised by Kozlowski et al \cite{k1}. In addition to the well known routes to chaos already encountered in a one-dimensional Duffing oscillator, our model exhibits imbricated period-doubling of both types, symmetry-breaking, sudden chaos and a great abundance of Hopf bifurcations, many of which occur more than once for a given driving frequency. We explore the chaotic behaviour of our model using two indicators, namely Lyapunov exponents and the power spectrum. Poincar\'e cross-sections and phase portraits are also plotted to show the manifestation of coexisting periodic and chaotic attractors including the destruction of $T^2$ tori doubling.Comment: 16 pages, 8 figure

Stochastic dissociation of diatomic molecules

The fragmentation of diatomic molecules under a stochastic force is investigated both classically and quantum mechanically, focussing on their dissociation probabilities. It is found that the quantum system is more robust than the classical one in the limit of a large number of kicks. The opposite behavior emerges for a small number of kicks. Quantum and classical dissociation probabilities do not coincide for any parameter combinations of the force. This can be attributed to a scaling property in the classical system which is broken quantum mechanically.Comment: 5 pages, 1 figure, accepted by J Chem Phy

Femtosecond Photodissociation of Molecules Facilitated by Noise

We investigate the dynamics of diatomic molecules subjected to both a femtosecond mid-infrared laser pulse and Gaussian white noise. The stochastic Schr\"odinger equation with a Morse potential is used to describe the molecular vibrations under noise and the laser pulse. For weak laser intensity, well below the dissociation threshold, it is shown that one can find an optimum amount of noise that leads to a dramatic enhancement of the dissociation probability. The enhancement landscape which is shown as a function of both the noise and the laser strength, exhibits a global maximum. A frequency-resolved gain profile is recorded with a pump-probe set-up which is experimentally realizable. With this profile we identify the linear and nonlinear multiphoton processes created by the interplay between laser and noise and assess their relative contribution to the dissociation enhancement.Comment: 5 pages,5 figure

Husimi-Wigner representation of chaotic eigenstates

Just as a coherent state may be considered as a quantum point, its restriction to a factor space of the full Hilbert space can be interpreted as a quantum plane. The overlap of such a factor coherent state with a full pure state is akin to a quantum section. It defines a reduced pure state in the cofactor Hilbert space. The collection of all the Wigner functions corresponding to a full set of parallel quantum sections defines the Husimi-Wigner reresentation. It occupies an intermediate ground between drastic suppression of nonclassical features, characteristic of Husimi functions, and the daunting complexity of higher dimensional Wigner functions. After analysing these features for simpler states, we exploit this new representation as a probe of numerically computed eigenstates of chaotic Hamiltonians. The individual two-dimensional Wigner functions resemble those of semiclassically quantized states, but the regular ring pattern is broken by dislocations.Comment: 21 pages, 7 figures (6 color figures), submitted to Proc. R. Soc.

Dissociation and ionization of small molecules steered by external noise

We show that ionization and dissociation can be influenced separately in a molecule with appropriate external noise. Specifically we investigate the hydrogen molecular ion under a stochastic force quantum mechanically beyond the Born-Oppenheimer approximation. We find that up to 30% of dissociation without ionization can be achieved by suitably tuning the forcing parameters.Comment: 13 pages, 6 figure

Negativity of the Wigner function as an indicator of nonclassicality

A measure of nonclassicality of quantum states based on the volume of the negative part of the Wigner function is proposed. We analyze this quantity for Fock states, squeezed displaced Fock states and cat-like states defined as coherent superposition of two Gaussian wave packets.Comment: 10 pages, 7 figure