Preparation of zeolite filled glassy polymer membranes

The incorporation of zeolite particles in the micrometer range into polymeric matrices was investigated as a way to improve the gas separation properties of the polymer materials used in the form of membranes. The adhesion between the polymer phase and the external surface of the particles appeared to be a major problem in the preparation of such membranes when the polymer is in the glassy state at room temperature. Various methods were investigated to improve the internal membrane structure, that is, surface modification of the zeolite external surface, preparation above the glass-transition temperature, and heat treatment. Improved structures were obtained as observed by scanning electron microscopy, but the influence on the gas separation properties was not in agreement with the observed structural improvements

Limitations, improvements and alternatives of the silt density index

Reverse osmosis (RO) membrane systems are widely used in the desalination of water. However, flux decline due to fouling phenomena in RO remains a challenge. To minimize fouling, a reliable index is necessary to predict the fouling potential of the RO feed water. The ASTM introduced the silt density index (SDI) as a standard fouling index to measure the fouling potential due to colloidal and suspended particles. For decades, the SDI is worldwide accepted and applied. There are growing doubts about the predictive value of this parameter. In addition there are several deficiencies observed, affecting the accuracy and reproducibility e.g. no correction factor for temperature, nor for variations in membrane resistance, and no linear correlation with the concentration of colloidal/suspended particles. This paper gives an overview of our work on limitations, improvements and alternatives for the SDI. Firstly, the influence of the applied 0.45 μm test membrane on the SDI will be investigated. Variations in SDI values can be attributed to differences in properties of these membranes. In order to quantify the influence of pressure, temperature and membrane resistance on the SDI a mathematical relation was developed between the SDI and the MFI0.45, assuming cake filtration. In addition, also other fouling mechanisms were incorporated in the model using the well-known blocking laws. Based on a cake filtration fouling mechanism and assuming 100% particle retention, the models were used to normalize the experimental SDI values for temperature, pressure and membrane resistance to the SDI+. By applying this normalization, the results of SDI tests carried out under different conditions and/or with different membranes can be compared easily as was proven experimentally in the lab and at a seawater desalination plant. Finally, an alternative filtration index will be introduced, the volume-based SDI_v. The SDI_v compares the initial flow rate to the flow rate after filtering a standard volume of feed water using MF membranes with an average pore size of 0.45 μm. Our experimental results show that SDI_v is independent of the membrane resistance. In that way, it eliminates most of the disadvantages of the SDI and has great potential to replace the SDI in the fiel

A novel method for fabricating composite mosaic membrane with unique NF selectivity

A novel method of fabricating composite mosaic membranes was studied on the basis of interfacial polymerization (IP) by coating a thin selective layer onto the surface of a micro-porous hollow-fiber membrane, in which, 2,5-diaminobenzene sulfonic acid was used as one monomer of the IP reaction, and a mixture of trimesoyl chloride (TMCl) and 4-(chloromethyl) benzoyl chloride as the other monomer. Through the IP reaction a thin selective layer with negatively charged groups could be first formed on the polyethersulfone (PES) support membrane. Then trimethylamine solution was introduced to modify the IP layer through a quaternization reaction. Thus the selective layer of this composite membrane contained both negatively charged and positively charged groups to perform the mosaic functionality. Characterization of the composite mosaic membranes was carried out through permeation experiments using different inorganic salts and dyes. The experimental results showed that the membranes could permeate both mono- and bi-valent inorganic salts, but reject larger organic molecules. Such a mosaic membrane is potentially useful for the separation of salts from water-soluble organics, especially in dye and textile industries