Dust in the wind: Crystalline silicates, corundum and periclase in PG 2112+059

We have determined the mineralogical composition of dust in the Broad Absorption Line (BAL) quasar PG 2112+059 using mid-infrared spectroscopy obtained with the Spitzer Space Telescope. From spectral fitting of the solid state features, we find evidence for Mg-rich amorphous silicates with olivine stoichiometry, as well as the first detection of corundum (Al_2O_3) and periclase (MgO) in quasars. This mixed composition provides the first direct evidence for a clumpy density structure of the grain forming region. The silicates in total encompass 56.5% of the identified dust mass, while corundum takes up 38 wt.%. Depending on the choice of continuum, a range of mass fractions is observed for periclase ranging from 2.7% in the most conservative case to 9% in a less constrained continuum. In addition, we identify a feature at 11.2 micron as the crystalline silicate forsterite, with only a minor contribution from polycyclic aromatic hydrocarbons. The 5% crystalline silicate fraction requires high temperatures such as those found in the immediate quasar environment in order to counteract rapid destruction from cosmic rays.Comment: 2 figure

The mineralogy of newly formed dust in active galactic nuclei

The tori around active galactic nuclei (AGN) are potential formation sites for large amounts of dust, and they may help resolve the so-called dust budget crisis at high redshift. We investigate the dust composition in 53 of the 87 Palomar Green (PG) quasars showing the 9.7 micron silicate feature in emission. By simultaneously fitting the mid-infrared spectroscopic features and the underlying continuum, we estimate the mass fraction in various amorphous and crystalline dust species. We find that the dust consists predominantly of alumina and amorphous silicates, with a small fraction in crystalline form. The mean crystallinity is 8 +/- 6%, with more than half of the crystallinities greater than 5%, well above the upper limit determined for the Galaxy. Higher values of crystallinity are found for higher oxide fractions and for more luminous sources.Comment: 24 pages, 9 figures, accepted for publication in Planetary and Space Scienc

Is the structure of 42Si understood?

A more detailed test of the implementation of nuclear forces that drive shell evolution in the pivotal nucleus \nuc{42}{Si} -- going beyond earlier comparisons of excited-state energies -- is important. The two leading shell-model effective interactions, SDPF-MU and SDPF-U-Si, both of which reproduce the low-lying \nuc{42}{Si}($2^+_1$) energy, but whose predictions for other observables differ significantly, are interrogated by the population of states in neutron-rich \nuc{42}{Si} with a one-proton removal reaction from \nuc{43}{P} projectiles at 81~MeV/nucleon. The measured cross sections to the individual \nuc{42}{Si} final states are compared to calculations that combine eikonal reaction dynamics with these shell-model nuclear structure overlaps. The differences in the two shell-model descriptions are examined and linked to predicted low-lying excited $0^+$ states and shape coexistence. Based on the present data, which are in better agreement with the SDPF-MU calculations, the state observed at 2150(13)~keV in \nuc{42}{Si} is proposed to be the ($0^+_2$) level.Comment: accepted in Physical Review Letter

Thermodynamic properties and thermal correlation lengths of a Hubbard model with bond-charge interaction

We investigate the thermodynamics of a one-dimensional Hubbard model with bond-charge interaction X using the transfer matrix renormalization group method (TMRG). Numerical results for various quantities like spin and charge susceptibilities, particle densities, specific heat and thermal correlation lengths are presented and discussed. We compare our data also to results for the exactly solvable case X/t=1 as well as to bosonisation results for weak coupling X/t << 1, which shows excellent agreement. We confirm the existence of a Tomonaga-Luttinger and a Luther-Emery liquid phase, in agreement with previous studies at zero temperature. Thermal singlet-pair correlation lengths are shown to dominate density and spin correlations for finite temperatures in certain parameter regimes.Comment: 13 pages, revte

Curvature effect on the interaction between folded graphitic surface and silver clusters

Evidence of curvature effects on the interaction and binding of silver clusters on folded graphitic surfaces has been shown from both experiment and theory. Density Functional Theory (DFT) calculations within the local density and generalized gradient approximations have been performed for the structural relaxation of both Ag and Ag$_2$ on curved surfaces, showing a cross-over from quantum to classical behaviour. Using Lennard-Jones potential to model the interaction between a single cluster and the graphene surface, evidence is found for the curvature effect on the binding of silver nano-particles to folding graphitic surfaces. The theoretical results are compared to SEM and AFM images of samples obtained from pre-formed silver cluster deposition on carboneous substrates exhibiting anisotropic pleat structures

Cochlear implant positioning:development and validation of an automatic method using computed tomography image analysis

The aim of this study was to preoperatively asses the feasibility of drilling a bony recess for the fixation of a cochlear implant in the temporal bone. Even though complications are rare with cochlear implantations, drilling at the site of implantation have resulted in hematoma or cerebrospinal fluid leakage. Mainly in cases with a reduced temporal bone thickness, the risk for complications has increased, such as in paediatric patients.Methods An in-house designed semi-automatic algorithm was developed to analyse a 3D model of the skull. The feasibility of drilling the recess was determined by a gradient descent method to search for the thickest part of the temporal bone. Feasibility was determined by the residual bone thickness which was calculated after a simulated drilling of the recess at the thickest position. An initial validation of the algorithm was performed by measuring the accuracy of the algorithm on five 3D models with known thickest locations for the recess. The accuracy was determined by a part comparison between the known position and algorithm provided position.Results In four of the five validation models a standard deviation for accuracy below the predetermined cut-off value of 4.2 mm was achieved between the actual thickest position and the position determined by the algorithm. Furthermore, the residual thickness calculated by the algorithm showed a high agreement (max. 0.02 mm difference) with the actual thickness.Conclusion With the developed algorithm, a semi-automatic method was created to analyse the temporal bone thickness within a specified region of interest on the skull. Thereby, providing indications for surgical feasibility, potential risks for anatomical structures and impact on procedure time of cochlear implantation. This method could be a valuable research tool to objectively assess feasibility of drilling a recess in patients with thin temporal bones preoperatively

Changes in use of herbs and dietary supplements (HDS) among clinicians enrolled in an online curriculum

<p>Abstract</p> <p>Background</p> <p>Little is known about clinicians' use of herbs and dietary supplements (HDS), how their personal HDS use changes with time and training, and how changes in their personal use affect their confidence or communication with patients about HDS.</p> <p>Methods</p> <p>We conducted a prospective cohort study of clinicians before and after an on-line curriculum about HDS in winter-spring, 2005.</p> <p>Results</p> <p>Of the 569 clinicians who completed surveys both at baseline and after the course, 25% were male and the average age was 42 years old; 88% used HDS before and after the course. The average number of supplements used fell slightly from 6.2 at baseline to 5.8 after the course (P < 0.01). The most commonly used supplements at baseline were: multivitamins (65%), calcium (42%), B vitamins (34%), vitamin C (34%), green tea (27%), fish oil (27%) and vitamin E (25%). Use of fish oil increased to 30% after the course (P = 0.01). Use of supplements traditionally used to treat colds decreased: vitamin C (34% to 27%), zinc (13% to 10%), and echinacea (7% to 5%, P < 0.05 for all three). Changes in personal HDS use were not associated with significant changes in confidence or communication with patients.</p> <p>Conclusion</p> <p>Many clinicians use HDS personally; use changes seasonally and to a small extent with professional education. Professional use of HDS is dynamic and seasonal. Additional research is needed to understand the impact of personal use on professional attitudes and behavior in populations with lower baseline uses of HDS.</p