Mitigation of large-scale organic waste damage incorporating a demonstration of a closed loop conversion of poultry waste to energy at the point of source (2000-LS-1-M2) Final Report

peer-reviewedThe increase in the world population and urbanisation, have changed the way the world produces food. As the demand for cheap and readily available food in the developed world increases, high-density, intensive farming practices have replaced subsistence farming to allow for the mass production of food. An unavoidable consequence of these farming\ud practices is the generation of significant quantities of organic waste

The use of multibeam backscatter angular response for marine sediment characterisation by comparison with shallow electromagnetic conductivity

11 pages, 7 figures, 3 tablesIn this empirically-driven research, multibeam backscatter angular response analysis is presented, together with shallow electromagnetic data and groundtruthing, to examine its suitability as a proxy for sediment characterisation. Backscatter angular curves extracted from Kongsberg EM1002 sonar (95-98 kHz), acquired in the Malin Basin to the northwest of Ireland, have been selected as a case study. Standard angular backscatter features and newly derived curvature features are examined and cross compared. Exhaustive statistical analysis has been performed on the data to elucidate the complex relationship between multibeam backscatter and sediment properties. Subtle subsurface sediment property gradients across the basin identified by the conductivity system are also captured by the newly derived backscatter features. The results reveal that Near-range backscatter is better suited for subsurface sediment characterisation in soft, fine-grained sediments than far-range. Furthermore, the analysis has constrained the optimum interval for such characterisation to in-between 4° and 16° for the parameters of this study. A number of shape features (slope, first derivative, second derivative and Fourier-smoothed least-squares-fitted curvature) have been examined, and their suitability discussed, in terms of sediment characterisation and, in particular, as potential proxies for delineating the boundary between sand- or silt-dominated sediment facies. Nonetheless, curvature features are found to be independent from average angular backscatter response, but outperform both first and second derivatives when correlating with conductivity in the central part of this case-study with fine-grained homogeneous sedimentsWe wish to thank the Geological Survey of Ireland, the Integrated Mapping For the Sustainable Development of Ireland’s Marine Resources (INFOMAR) programme, the Petroleum Affairs Division (Ireland) and the Dublin Institute for Advanced Studies for funding this study. Research presented in this paper is supported by a Strategic Research Cluster grant (07/SRC/I1168) – StratAG, awarded to the National Centre of Geocomputation by Science Foundation Ireland under the National Development Plan. The survey data utilized in the research has been co-funded by the Geological Survey of Ireland and the Offshore Irish Petroleum Infrastructure Programme (PIP; Ref. No: IS05/16 Malin Basin EM)Peer Reviewe

Emissions modeling of fluidised bed co-combustion of poultry litter and peat

Gaseous emissions from the fluidised bed co-combustion of 50% w/w chicken litter and peat were monitored and recorded. Emission data were used to create a dispersion model for a proposed site on a poultry farm in Ireland. Variables within the combustion unit influenced both combustion and emission levels of pollutants such as SO2 and NOx, CO. Concentrations of atmospheric pollutants decreased with use of the correct ratio between fluidising and secondary air. Dispersion modelling of combustion at a proposed poultry unit predicted that ground level concentrations for the set of emissions data would be below the limits and guidelines set by air quality standards

Mid-holocene climate change and landscape formation in ireland: evidence from a geochemical investigation of a coastal peat bog

Following a period of unusually strong winds and high seas in the spring of 2014, a blanket peat bog formerly covered by a beach comprised of fine sand and large rocks was uncovered at a coastal site in Spiddal, Co. Galway, Ireland. The surface of the bog was littered with standing tree stumps, the remnants of a Holocene forest that had succumbed to a relatively sudden drowning. A combination of inorganic and organic geochemical techniques was applied to determine the cause of this rapid submersion and to glean palaeoclimatic information from the preserved record within the peat. The study represents the first use of a multiproxy lipid biomarker approach to investigate palaeoclimate conditions from a peat bog in Ireland. The results provide evidence of climatic variation throughout a ca. 3400 yr timeframe during the mid-Holocene. Biomarker proxies displaying the relative contribution of Sphagnum spp. vs. higher plants were used to show changes in precipitation and temperature during peat formation. The data correlate with described events, including the 4.2 ka event and the Subboreal-Subatlantic transition and show the benefit of a lipid biomarker method for investigating Ireland’s peatland resources. In particular, the indication of colder/wetter conditions coinciding with the 4.2 ka event implies the possibility that its effects were felt in Ireland, contrary to some reports. The results suggest that a combination of warm and dry conditions followed by a rapid rise in sea level led to the growth and subsequent drowning of the ancient forest landscape

Occurrence, characteristics and formation mechanisms of methane generated micro-pockmarks in Dunmanus Bay, Ireland

A small gas pockmark field in Dunmanus Bay, SW Ireland was surveyed and ground-truthed to assess its activity, geomorphology, explore its formation mechanisms and to investigate its potential influence on the benthic community. The field consisted of 121 circular, shallow units ranging from 5 to 17 m in diameter and not exceeding 1 m in relief. Sub-bottom profiles revealed broad acoustic signatures typical of shallow gas accumulation in the subsurface in addition to vertically elongated signals of ascending bubbles captured in the echo sounder data. The pockmarks show strong correlation with the depth of sub-surface gas fronts. However methane concentrations in the water column and directly above the features were close to typical marine, background values and did not exceed 15 nM. This suggests a very mild, periodic venting scenario. Sediment core samples revealed permeable sandy layers with slightly elevated methane concentrations indicative of stratified, diffusive flow. Pore-water sulphate and chloride data show no sign of pore water freshening and thus suggest that methane gas is the sole fluid responsible for formation of these pockmarks. Benthic infauna distributions showed reduced diversity in pockmarked regions, primarily influenced by the sediment composition. Few species utilising chemosymbiotic associations were identified, and there was little indication of a community influenced by methane venting in Dunmanus Bay

Geophysical and geochemical analysis of shallow gas and an associated pockmark field in Bantry Bay, Co. Cork, Ireland

An integrated geophysical, geological, and geochemical investigation of seabed fluid venting was carried out in upper Bantry Bay, a large marine inlet on the southwest coast of Ireland. The results provide evidence of the seafloor venting of gas rich fluids, resulting in the formation of a pockmark field identified here for the first time. The pockmarks occur in an area where sub-bottom profiles provide evidence of chimney-like features interpreted to record upward gas migration through Quaternary sediments to the seafloor. Three vibrocores up to 6 m long were acquired in water depths of 24–34 m, two from the pockmark field and one from outside. Methane of predominantly biogenic origin was quantified in all three cores by headspace analysis of sediment sub-samples. Well-defined sulfate methane transition zones (SMTZs) were observed in two of the cores, the shallowest (1.25 m below sea floor (mbsf)) inside the pockmark field and the other (3.75 mbsf) outside. It is likely that an SMTZ occurs at the location of the third core, also within the pockmark field, although deeper than the samples obtained during this study. Gas migration towards the seafloor is suggested to involve both diffuse pore fluid migration across wide areas and focused flow through the pockmarks, together driven by methanogenesis of pre-glacial lacustrine sediments preserved in a bedrock basin, and possible gas release from the Owenberg River Fault. Analysis of phospholipid fatty acids (PLFAs) and archaeal isoprenoid hydrocarbons was used to investigate the microbial ecology of these sediments. Anaerobic oxidation of methane (AOM) may play a role in controlling release of CH4 to the water column and atmosphere in this shallow gas setting, potentially mediated by syntrophic sulfate reducing bacteria (SRB) and anaerobic methanotrophic archaea (ANME)