Electrochemical SERS at a structured gold surface

Templated electrodeposition of gold to produce thin (<1 ?m) films containing a close packed hexagonal array of uniform sphere segment voids is shown to give surfaces which show strong surface enhancement for Raman scattering from molecules adsorbed at the surface. The magnitude of this is enhancement is determined by the precise geometry of the surface and depends on the choice of void diameter and film thickness. The resulting SER active surfaces are stable, reusable, give reproducible surface enhancement and can be used for in situ electrochemical SERS studies

Retroemission by a glass bead monolayer for high-sensitivity, long-range imaging of upconverting phosphors

We introduce a retroemitter (REM) device comprising a planar glass bead set placed on a luminescent material substrate, which converges an excitation beam into a set of foci (voxels). The in-voxel emission is collimated by the beads, and propagates upstream over the long range, unlike the out-of-voxel emission spreading in all angles. The REM signal contrast is characterized as a function of incidence and observation angles and propagation distance. REM signal contrasts of approximately 20 and 1600 were found for the organic fluorescent dye and upconverting phosphor substrates, respectively. In the latter case, nonlinear optical signal enhancement plays a role in addition to the retroemission effect. This allows centimeter-scale REM patterns to be read out at the meter-scale distance using eye-safe sub-mW=cm2 excitation intensities.3 page(s

Engineering localised plasmons on nanostructured metallic surfaces for surface-enhanced Raman spectroscopy

Reproducible SERS-active substrates with Raman enhancements > 10,000 are designed by nano-templating gold and silver surfaces. Optimisation of the surface and localised plasmons matched to the exciting laser provide highly specific control, opening new applications spaces

Mie plasmon enhanced diffraction of light from nanoporous metal surfaces

The diffractive properties of gold films with a periodic lattice of sub-micron voids beneath the surface are investigated. It has been shown that nanoporous metal surfaces exhibit frequency-selective non-dispersive diffraction enhanced by Mie plasmons in nanovoids, which leads to absolute angular tolerance of the diffracted beam intensity that can be useful for a variety of applications covering angle-tolerant optical filters, deflectors, absorbers, and beam splitters. Diffraction spectra are measured and calculated to support these conclusions, showing good qualitative agreement

Strong coupling of light to flat metals via a buried nanovoid lattice: the interplay of localized and free plasmons

We study the optical plasmonic properties of metal surfaces which have a periodic lattice of voids buried immediately beneath their flat upper surface. Light reflection spectra calculated in the framework of a selfconsistent electromagnetic multiple-scattering layer-KKR approach exhibit two types of plasmon resonances originating from the excitation of different plasmon modes: surface plasmon-polaritons propagating on the planar surface of metal and Mie plasmons localized in the buried voids. Coupling between these two types of plasma oscillation leads to an enhancement of the surface plasmon-polariton resonances even for close-packed void lattices. Our theoretical model quantitatively agrees with experimental results, demonstrating that planar surfaces can exhibit strong plasmonic field enhancements