Extraction of Linear Carbon Chains Unravels the Role of the Carbon Nanotube Host

Linear carbon chains (LCCs) have been shown to grow inside double-walled carbon nanotubes (DWCNTs), but isolating them from this hosting material represents one of the most challenging tasks toward applications. Herein we report the extraction and separation of LCCs inside single-walled carbon nanotubes (LCCs@SWCNTs) extracted from a double-walled host LCCs@DWCNTs by applying a combined tip-ultrasonic and density gradient ultracentrifugation (DGU) process. High-resolution transmission electron microscopy, optical absorption, and Raman spectroscopy show that not only short LCCs but clearly long LCCs (LLCCs) can be extracted and separated from the host. Moreover, the LLCCs can even be condensed by DGU. The Raman spectral frequency of LCCs remains almost unchanged regardless of the presence of the outer tube of the DWCNTs. This suggests that the major importance of the outer tubes is making the whole synthesis viable. We have also been able to observe the interaction between the LCCs and the inner tubes of DWCNTs, playing a major role in modifying the optical properties of LCCs. Our extraction method suggests the possibility toward the complete isolation of LCCs from CNTs

Monomer Symmetry-Regulated Defect Engineering: In Situ Preparation of Functionalized Covalent Organic Frameworks for Highly Efficient Capture and Separation of Carbon Dioxide

Developing crystalline porous materials with highly efficient CO2 selective adsorption capacity is one of the key challenges to carbon capture and storage (CCS). In current studies, much more attention has been paid to the crystalline and porous properties of crystalline porous materials for CCS, while the defects, which are unavoidable and ubiquitous, are relatively neglected. Herein, for the first time, we propose a monomer-symmetry regulation strategy for directional defect release to achieve in situ functionalization of COFs while exposing uniformly distributed defect-aldehyde groups as functionalization sites for selective CO2 capture. The regulated defective COFs possess high crystallinity, good structural stability, and a large number of organized and functionalized aldehyde sites, which exhibit one of the highest selective separation values of all COF sorbing materials in CO2/N2 selective adsorption (128.9 cm3/g at 273 K and 1 bar, selectivity: 45.8 from IAST). This work not only provides a new strategy for defect regulation and in situ functionalization of COFs but also provides a valuable approach in the design and preparation of new adsorbents for CO2 adsorption and CO2/N2 selective separation