Nanocrystal growth and morphology of PbTeSe-ZnSe composite thin films prepared by one-step synthesis method

The microstructure of polycrystalline PbTe₁₋ₓSeₓ-ZnSe composite thin films has been studied by scanning transmission electron microscopy and electron diffraction. The films were prepared by the one-step synthesis method using simultaneous evaporation of PbTe and ZnSe. The nanocrystals of PbTe₁₋ₓSeₓ are formed in a ZnSe matrix. Tellurium concentration can be tuned by controlling the PbTe evaporation source temperatures between 753 K and 793 K. Binary PbSe nanocrystals were formed at 753 K, while ternary PbTe₁₋ₓSeₓ nanocrystals were formed at 793 K. The nanocrystals grow in a granular shape at the initial stage of film growth, and the morphology changes to nanowire-shape as the film grows, irrespective of the Te concentration. The ternary PbTe₁₋ₓSeₓ nanocrystals were composed of two phases with different Te concentration; Te-rich (Se-poor) granular crystals were formed near the bottom half parts of the film and Te-poor (Se-rich) nanowires were formed at the upper half parts of the film. Columnar ZnSe crystals contain high-density {111} stacking faults due to the low stacking fault energy of ZnSe. A balance of deposition and re-evaporation on the substrate during the film growth will be responsible for the resultant nanocrystal morphology.Kazuhisa Sato and Seishi Abe, "Nanocrystal growth and morphology of PbTeSe-ZnSe composite thin films prepared by one-step synthesis method", Journal of Applied Physics 120, 155301 (2016) https://doi.org/10.1063/1.496487

Near-Ultraviolet and Visible Spectroscopy of HAYABUSA Spacecraft Re-entry

HAYABUSA is the first spacecraft ever to land on and lift off from any celestial body other than the moon. The mission, which returned asteroid samples to the Earth while overcoming various technical hurdles, ended on June 13, 2010, with the planned atmospheric re-entry. In order to safely deliver the sample return capsule, the HAYABUSA spacecraft ended its 7-year journey in a brilliant "artificial fireball" over the Australian desert. Spectroscopic observation was carried out in the near-ultraviolet and visible wavelengths between 3000 and 7500 \AA at 3 - 20 \AA resolution. Approximately 100 atomic lines such as Fe I, Mg I, Na I, Al I, Cr I, Mn I, Ni I, Ti I, Li I, Zn I, O I, and N I were identified from the spacecraft. Exotic atoms such as Cu I, Mo I, Xe I and Hg I were also detected. A strong Li I line (6708 \AA) at a height of ~55 km originated from the onboard Li-Ion batteries. The FeO molecule bands at a height of ~63 km were probably formed in the wake of the spacecraft. The effective excitation temperature as determined from the atomic lines varied from 4500 K to 6000 K. The observed number density of Fe I was about 10 times more abundant than Mg I after the spacecraft explosion. N2+(1-) bands from a shock layer and CN violet bands from the sample return capsule's ablating heat shield were dominant molecular bands in the near-ultraviolet region of 3000 - 4000 \AA. OH(A-X) band was likely to exist around 3092 \AA. A strong shock layer from the HAYABUSA spacecraft was rapidly formed at heights between 93 km and 83 km, which was confirmed by detection of N2+(1-) bands with a vibration temperature of ~13000 K. Gray-body temperature of the capsule at a height of ~42 km was estimated to be ~2437 K which is matched to a theoretical prediction. The final message of the HAYABUSA spacecraft and its sample return capsule are discussed through our spectroscopy.Comment: Accepted for publication in PASJ, 22 pages, 7 figures, 6 table

High Resolution Simultaneous Measurements of Airborne Radionuclides at Sub-regional Sampling Points by Ultra Low Background Gamma Spectrometry

金沢大学環日本海域環境研究センター地球環境計測研究部門Promoting Environmental Pesearch in Pan-Japan Sea Area : Young Researchers\u27 Network, Schedule: March 8-10,2006,Kanazawa Excel Hotel Tokyu, Japan, Organized by: Kanazawa University 21st-Century COE Program, Environmental Monitoring and Prediction of Long- & Short- Term Dynamics of Pan-Japan Sea Area ; IICRC(Ishikawa International Cooperation Research Centre), Sponsors : Japan Sea Research ; UNU-IAS(United Nations University Institute of Advanced Studies)+Ishikawa Prefecture Government ; City of Kanazaw

Improvement of Cylindrical Deep Drawability in Hot Stamping

AbstractDeep drawability of steel sheets in hot stamping was investigated. In the case of deep drawing with a conventional die, the forming limit was significantly lower because the temperature of the sheet metal at the flange part decreased during the forming and the flow resistance increased. Therefore, the blank holding method to avoid temperature decrease at flange part of sheet metal was studied. In this study, application of gap supports and forming without blank holder were investigated. In the former method, the gap supports made clearance at the flange part. In the latter method, the blank holder was located at the lower dead point from the beginning of forming and the flange part of the blank was free during forming. The forming limit in both cases was improved as compared with that in the conventional blank holding method. For the application of gap supports, the limiting drawing ratio was also evaluated. In this experiment, the maximum value of limiting drawing ratio was 1.71

イネ ニオケル コメヌカ タンパクシツ ノ プロテオミクス

Rice bran has wide potential usage as a source of valuable nutrients, though little is known about its protein composition. Here, we identified rice bran proteins by using proteomic analysis. After extraction of crude protein from the bran of Koshihikari brown rice grains, we separated proteins by 2-D PAGE and analyzed 41 protein spots. N-terminal amino acid sequences were determined for 23 spots, 21 proteins of known function and 2 could not be identified by BLAST searching. For the other 18 spots, the N-terminal amino acids could not be determined. Of these, 4 were identified by using LC-MS/MS. After in-solution digestion of bran samples from Koshihikari and TN-1, we looked for differences in the bran proteins between these cultivars. A total of 83 proteins were detected and classified into 10 categories: storage proteins, carbohydrate metabolic enzymes, proteins related to synthesis and proteolysis, embryo proteins, stress-related proteins, regulatory proteins, antioxidant proteins, redox-related proteins, lipid biosynthesis proteins, and energy-related proteins. In the identified proteins, antioxidant proteins and redox-related proteins, such as peroxiredoxin and glyoxalase, respectively, considered to be unique to bran among seed proteins. Such proteins may play important roles as antioxidants for protecting cells in the embryo and aleurone layer from the stress of desiccation

High resolution simultaneous measurements of airborne radionuclides

金沢大学大学院自然科学研究科場所：東京大学弥生講堂，共催：文部科学省２１世紀COE「環日本海域の環境計測と長期・短期変動予測」，大気環境学

High resolution simultaneous measurements of airborne radionuclides

金沢大学大学院自然科学研究科場所：金沢大学自然科学研究科図書館棟1階，講演会場：図書館棟1階　大会議室，ポスター会場：図書館棟1階12会議室,主催・共催：文部科学省２１世紀COE「環日本海域の環境計測と長期・短期変動予測」， 大気環境学会， 金沢大学工学

Molecular characterization of buckwheat major immunoglobulin E-reactive proteins in allergic patients

ABSTRACTBuckwheat extract was analyzed by immunoblotting experiments using sera from nine allergic and three non-allergic individuals. Major IgE-reactive bands were 73, 70, 62, 58 and 54kDa under non-reducing conditions and were detected in allergic subjects, but not in non-allergic ones. Under reducing conditions, the 73, 70, 62 and 58kDa bands split to 56 and 24, 52 and 24, 45 and 24, and 43 and 24kDa, respectively. The 24kDa molecule was the most prominent band recognized with IgE as well as IgG or IgA. The FA02 cDNA clone, encoding the α and β subunits of the legumin-like storage protein, was isolated from a cDNA library made of immature buckwheat seeds. The deduced amino acid sequence of the cDNA clone is substantially identical to the N-terminal amino acid sequence of the 24kDa molecule, which may be identical to that of BW24KD reported by Urisu et al. Consistent with these results, the translation product of the cDNA encoding the putative β subunit was strongly recognized with serum IgE, IgG and IgA from buckwheat-allergic patients. These results suggested that the 24kDa molecule may be the β subunit of the legumin-like storage molecule of buckwheat

Measurements of short-lived cosmogenic nuclides in rain samples

金沢大学自然計測応用研究センター自然計測研究部門金沢大学理学部Extremely low activity levels of cosmic ray induced nuclides have been measured in freshly precipitated rainwater by quick chemical separation coupled with ultra low background gamma-spectrometry. The nuclides detected were 38S (T1/2 = 2.83 h)-38Cl (37.2 m), 39Cl (55.6 m), 24Na (14.96 h), 28Mg (20.9 h), 7Be (53.3 d) and 22Na (2.602 y). The number of atoms in rain water were evaluated to be ranging from 400-1900 l-1 for 39Cl (n = 6, mean: 1200), 30-1500 l-1 for 24Na (n = 16, mean: 520), 80-600 l-1 for 28Mg (n = 13, mean: 260), 1·106-4·107 l-17Be (n = 16, mean: 7·106) and 2·10 3-1·105 l-1 for 22Na (n = 9, mean: 2·104). Measurements of activity levels and activity ratios of short-lived cosmic-ray induced short-lived nuclides will open new method to understand atmospheric processes occurred at the altitude of rain cloud. © 2006 Akadémiai Kiadó