2 research outputs found
Iron-Catalyzed Aromatic Amination for Nonsymmetrical Triarylamine Synthesis
Novel iron-catalyzed amination reactions of various aryl
bromides
have been developed for the synthesis of diaryl- and triarylamines.
The key to the success of this protocol is the use of <i>in situ</i> generated magnesium amides in the presence of a lithium halide,
which dramatically increases the product yield. The present method
is simple and free of precious and expensive metals and ligands, thus
providing a facile route to triarylamines, a recurrent core unit in
organic electronic materials as well as pharmaceuticals
Iron-Catalyzed Aromatic Amination for Nonsymmetrical Triarylamine Synthesis
Novel iron-catalyzed amination reactions of various aryl
bromides
have been developed for the synthesis of diaryl- and triarylamines.
The key to the success of this protocol is the use of <i>in situ</i> generated magnesium amides in the presence of a lithium halide,
which dramatically increases the product yield. The present method
is simple and free of precious and expensive metals and ligands, thus
providing a facile route to triarylamines, a recurrent core unit in
organic electronic materials as well as pharmaceuticals