42 research outputs found

    Evaluation of the affect of speech intonation using a model of the perception of interval dissonance and harmonic tension

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    Abstract We report the application of a psychophysical model of pitch perception to the analysis of speech intonation. The model was designed to reproduce the empirical findings on the perception of musical phenomena (the dissonance/consonance of intervals and the tension/sonority of chords), but does not depend on specific musical scales or tuning systems. Application to intonation allows us to calculate the total dissonance and tension among the pitches in the speech utterance. In an experiment using the 144 utterances of 18 male and female subjects, we found greater dissonance and harmonic tension in sentences with negative affect, in comparison with sentences with positive affect

    Stabilizing the Structure of LiCoPO4 Nanocrystals via Addition of Fe3+: Formation of Fe3+ Surface Layer, Creation of Diffusion-Enhancing Vacancies, and Enabling High-Voltage Battery Operation

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    Factors affecting the cyclability of the Fe-substituted LiCoPO4 (LiCo0.8Fe0.2PO4, LCFP) material were elucidated, including both the structural and electrode/electrolyte stability. Electrochemical characterization of the synthesized LCFP nanoparticles lends clear evidence for improved electrochemical stability of LCP, as well as enhanced rate capability, with Fe3+ substitution. Surface analysis using X-ray photoelectron spectroscopy (XPS) and electron energy loss spectroscopy (EELS) suggest that Fe enrichment on the surface of LCFP occurs through the oxidation of Fe2+ into Fe3+ in the synthesis process. The Fe3+-rich phase on the LCP surface enhances the stability of the delithiated phase, preventing oxidative reactions with electrolytes during high-voltage operation. This surface protection persists as long as the electrochemical reduction of Fe3+ is avoided by ensuring that the full range of operating voltages lie above the Fe3+/Fe2+ redox potential. Our findings may offer new approaches to stabilize the structure of LCP and other high-voltage positive electrodes for use in 5 V-class Li-ion batteries

    A novel underuse model shows that inactivity but not ovariectomy determines the deteriorated material properties and geometry of cortical bone in the tibia of adult rats

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    Our goal in this study was to determine to what extent the physiologic consequences of ovariectomy (OVX) in bones are exacerbated by a lack of daily activity such as walking. We forced 14-week-old female rats to be inactive for 15 weeks with a unique experimental system that prevents standing and walking while allowing other movements. Tibiae, femora, and 4th lumbar vertebrae were analyzed by peripheral quantitative computed tomography (pQCT), microfocused X-ray computed tomography (micro-CT), histology, histomorphometry, Raman spectroscopy, and the three-point bending test. Contrary to our expectation, the exacerbation was very much limited to the cancellous bone parameters. Parameters of femur and tibia cortical bone were affected by the forced inactivity but not by OVX: (1) cross-sectional moment of inertia was significantly smaller in Sham-Inactive rat bones than that of their walking counterparts; (2) the number of sclerostin-positive osteocytes per unit cross-sectional area was larger in Sham-Inactive rat bones than in Sham-Walking rat bones; and (3) material properties such as ultimate stress of inactive rat tibia was lower than that of their walking counterparts. Of note, the additive effect of inactivity and OVX was seen only in a few parameters, such as the cancellous bone mineral density of the lumbar vertebrae and the structural parameters of cancellous bone in the lumbar vertebrae/tibiae. It is concluded that the lack of daily activity is detrimental to the strength and quality of cortical bone in the femur and tibia of rats, while lack of estrogen is not. Our inactive rat model, with the older rats, will aid the study of postmenopausal osteoporosis, the etiology of which may be both hormonal and mechanical

    ガリウム オヨビ インジウム カゴウブツ オ モチイタ シンキ ユウキ ゴウセイ ハンノウ ニ カンスル ケンキュウ

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    京都大学0048新制・課程博士博士(工学)甲第11531号工博第2477号新制||工||1335(附属図書館)23174UT51-2005-D281京都大学大学院工学研究科材料化学専攻(主査)教授 大嶌 幸一郎, 教授 檜山 爲次郎, 教授 吉田 潤一学位規則第4条第1項該当Doctor of EngineeringKyoto UniversityDA

    Routing Based on Information about the Routes of Fixed-Route Traveling Nodes and on Destination Areas Aimed at Reducing the Load on the DTN

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    In recent years, the interest in delay/disruption tolerant networking (DTN) is growing as a means of communication in times of disaster. To ensure that a DTN works well in an emergency, it is desirable to promote general use of the DTN, so that it will also be used in normal times. Since the DTN uses mobile terminals and vehicles, which are not dedicated network devices, as relay nodes, the routing method should be such that it does not impose a large processing load on relay nodes. This paper considers use of a DTN for a day-to-day service of delivering content to a specific area and proposes a new routing method that is based on information about the routes of fixed-route traveling nodes, such as public transportation vehicles. The destination of a bundle is specified not by a terminal identifier, but by an area, which is identified by its location information. This paper presents an outbound-type bundle protocol, which is used by relay nodes when they have received a forwarding-bundle request from a sending terminal and try to determine whether the bundle can reach its destination area. Using simulation, the superiority of the proposed routing was confirmed by comparing it to existing routing methods in terms of the bundle arrival rate and factors that affect the network load, such as the number of bundle copies, the number of hops and the maximum required buffer size

    Routing Based on Information about the Routes of Fixed-Route Traveling Nodes and on Destination Areas Aimed at Reducing the Load on the DTN

    No full text
    In recent years, the interest in delay/disruption tolerant networking (DTN) is growing as a means of communication in times of disaster. To ensure that a DTN works well in an emergency, it is desirable to promote general use of the DTN, so that it will also be used in normal times. Since the DTN uses mobile terminals and vehicles, which are not dedicated network devices, as relay nodes, the routing method should be such that it does not impose a large processing load on relay nodes. This paper considers use of a DTN for a day-to-day service of delivering content to a specific area and proposes a new routing method that is based on information about the routes of fixed-route traveling nodes, such as public transportation vehicles. The destination of a bundle is specified not by a terminal identifier, but by an area, which is identified by its location information. This paper presents an outbound-type bundle protocol, which is used by relay nodes when they have received a forwarding-bundle request from a sending terminal and try to determine whether the bundle can reach its destination area. Using simulation, the superiority of the proposed routing was confirmed by comparing it to existing routing methods in terms of the bundle arrival rate and factors that affect the network load, such as the number of bundle copies, the number of hops and the maximum required buffer size

    Trial calculation of the AC test voltage using a new cumulative failure probability model

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