A Spatially Continuous Driving Rain Map of India at 0.5°×0.5° Gridded Scale

Driving rain is one of the most critical sources of moisture affecting the hygrothermal and durability performance of building envelopes. The estimation of severity in terms of annual driving rain indices using annual and monthly weather data (aaDRI and maDRI respectively) aids towards contemplating potential moisture loads, and hence in the efficient design of buildings in the geographical area of interest. In this study, monthly and annual gridded datasets of wind and rainfall, pertaining to the thirty-year period of 1988-2017 have been used to design a spatially continuous driving rain map for India at 0.5°×0.5°(lat./long.) resolution. The observations reveal that the use of annually averaged data leads to underestimation of the driving rain severity thereby highlighting the inefficiency of a coarser temporal scale. A linear relationship has subsequently been developed to enable refinement of aaDRI into maDRI. The analysis of the monthly driving rain map reveals that the entire western coastal belt and a few regions in the north-eastern part of the country observe high to severe exposure conditions. Furthermore, a trend analysis of the yearly driving rain index values reveals statistically significant decreasing trends over the northern and eastern regions of the country, whereas increasing trends in the shielded regions surrounding central India is observed

Aspergillus fumigatus

A cellulolytic fungal strain, Aspergillus fumigatus NITDGPKA3, was isolated from straw retting ground. Cellulase and xylanase production by A. fumigatus NITDGPKA3 in submerged fermentation of rice straw was studied. The culture conditions for maximum enzyme production were found to be initial pH 4, 1% substrate concentration, temperature 30°C, incubation time 5 days, 0.2% tryptone as nitrogen source, and inoculum volumes 7% v/v (for cellulase) and 5% v/v (for xylanase). Addition of Tween 80 in fermentation broth improved xylanase production (193.58 IU/ml) much more compared to cellulase production (6.53 IU/ml). Xylanase activity found in the culture broth was approximately 50% higher compared to most of the reported data. The crude enzyme was further applied for reducing sugar production from alkali pretreated rice straw, where a dosage of 40 IU/g CMCase produced 0.522 g reducing sugar/g dry substrate after 36 hours which was higher than that in the reported literature. The high concentration of reducing sugar yield was most probably due to the extraordinarily high titer of β-glucosidase (80.1 IU/ml) found in the crude enzyme. The crude enzymes secreted by Aspergillus fumigatus NITDGPKA3 efficiently hydrolyzed alkali pretreated rice straw suggesting that Aspergillus fumigatus NITDGPKA3 is a robust microorganism

Cellulase and Xylanase Production from Rice Straw by a Locally Isolated Fungus Aspergillus fumigatus NITDGPKA3 under Solid State Fermentation – Statistical Optimization by Response Surface Methodology

Alkali pretreated rice straw was used as substrate for cellulase production by a locally isolated fungus Aspergillus fumigatus NITDGPKA3 under solid state fermentation. Critical process parameters such as incubation period, temperature, basal medium content and pH were statistically optimized for an enhanced cellulase and xylanase yield by response surface methodology. The design predicted an optimum yield of 3.1 IU/g dry substrate, 64.18 IU/g dry substrate and 1040.57 IU/g dry substrate for FPase, CMCase and xylanase respectively under the optimum conditions of incubation period of 90 h, temperature at 33oC, initial basal medium content of 62% and initial pH 4. The experimental values under optimum conditions correlated well with the predicted results. Further, crude enzyme extract from Aspergillus fumigatus NITDGPKA3 was used for saccharification of pretreated rice straw and this released 189.50 mg/g of reducing sugar. This work was carried out in the Department of Biotechnology, National Institute of Technology, Durgapur-713209, West Bengal, India, during the period 2010 to 2011

Interaction of urea with fluorophores bound to cyclodextrins. Fluorescence of p-toluidino naphthalene sulphonate

The effect of urea on the fluorescence properties of p-toluidino naphthalene sulphonate (TNS) bound to α- and β-cyclodextrin (CDx) has been studied by steady-state and time-resolved emission spectroscopy. From the observed emission yield, lifetime and emission maxima the polarity of the α-CDx and β-CDx environment is estimated. Addition of urea to aqueous CDx solutions decreases the fluorescence yield and lifetime of TNS. The effect is more pronounced for α-CDx and less for β-CDx. The results are interpreted in terms of the model that urea increases the local polarity of the CDx surface and, in the case of α-CDx, displaces TNS molecules form the cyclodextrin interface. The TNS molecules are easily accessed by the urea molecule in the smallest α-CDx where a major part of the bound TNS molecule is projected outside the cavity. In β-CDx two kinds of TNS: β-CDx complexes (1:1 and 1:2) are formed. Addition of urea causes removal of TNS molecules bound to CDx in the 1:1 complex, but TNS in the 1:2 complex remains more or less unaffected because urea cannot approach it

Subthreshold-swing physics of tunnel field-effect transistors

Band-to-band tunnel field-effect-transistors (TFETs) are considered a possible replacement for the conventional metal-oxide-semiconductor field-effect transistors due to their ability to achieve subthreshold swing (SS) below 60 mV/decade. This letter reports a comprehensive study of the SS of TFETs by examining the effects of electrostatics and material parameters of TFETs on their SS through a physics based analytical model. Based on the analysis, an intrinsic SS degradation effect in TFETs is uncovered. Meanwhile, it is also shown that designing a strong onset condition, quantified by an introduced concept - “onset strength”, for TFETs can effectively overcome this degradation at the onset stage, and thereby achieve ultra-sharp switching characteristics. The uncovered physics provides theoretical support to recent experimental results, and forward looking insight into more advanced TFET design

Computational Study of Metal Contacts to Monolayer Transition-Metal Dichalcogenide Semiconductors

Among various 2D materials, monolayer transition-metal dichalcogenide (mTMD) semiconductors with intrinsic band gaps (1–2 eV) are considered promising candidates for channel materials in next-generation transistors. Low-resistance metal contacts to mTMDs are crucial because currently they limit mTMD device performances. Hence, a comprehensive understanding of the atomistic nature of metal contacts to these 2D crystals is a fundamental challenge, which is not adequately addressed at present. In this paper, we report a systematic study of metal-mTMD contacts with different geometries (top contacts and edge contacts) by ab initio density-functional theory calculations, integrated with Mulliken population analysis and a semiempirical van der Waals dispersion potential model (which is critical for 2D materials and not well treated before). Particularly, In, Ti, Au, and Pd, contacts to monolayer MoS_{2} and WSe_{2} as well as Mo-MoS_{2} and W-WSe_{2} contacts are evaluated and categorized, based on their tunnel barriers, Schottky barriers, and orbital overlaps. Moreover, going beyond Schottky theory, new physics in such contact interfaces is revealed, such as the metallization of mTMDs and abnormal Fermi level pinning. Among the top contacts to MoS_{2}, Ti and Mo show great potential to form favorable top contacts, which are both n-type contacts, while for top contacts to WSe_{2}, W or Pd exhibits the most advantages as an n- or p-type contact, respectively. Moreover, we find that edge contacts can be highly advantageous compared to top contacts in terms of electron injection efficiency. Our formalism and the results provide guidelines that would be invaluable for designing novel 2D semiconductor devices