Experimental and numerical study of chemiluminescence characteristics in premixed counterflow flames of methane based fuel blends

Non-intrusive chemiluminescence measurements have been used as heat release rate and equivalence ratio indicators for gas turbine combustor active control. In the present study, measurements and modelling of OH*, CH(A)*, C 2 *, and CO 2 * chemiluminescence are used to examine chemiluminescence sensing of heat release rate and equivalence ratio in premixed counterflow methane – air flames with equivalence ratio from 0.6 to 1.3 and strain rate from 80 to 400 s -1 . Two spectrally resolved detecting optical systems were used to detect spatially-averaged (global) and spatially resolved (local) chemiluminescence characteristics in the reaction zone. A recently published reaction mechanism 1 for the chemiluminescence of the OH*, CH*, and C 2 * species is incorporated to GRI-Mech 3.0. The augmented mechanism is further validated against the experimental results of the present study and is used to predict the chemiluminescence characteristics of premixed counterflow methane – air flames. The mechanism includes OH* chemiluminescence formation paths from hydrogen reaction, which have not been evaluated before in premixed counterflow flames. The CHEMKIN based counterflow flame code, OPPDIF is employed to simulate the experiments. The calculated OH* and CH(A)* chemiluminescence agrees well with the experimental results measured by both optical methods. Both the experimental and numerical results demonstrate the ability of OH* and CH(A)* intensities to mark heat release rate in methane – air flames. Overall, CH* may be preferable for heat release rate sensing applications at elevated equivalence ratio and strain rate. For equivalence ratio sensing in methane combustion, the measured and simulated OH*/CH(A)* chemiluminescent intensity ratio is highly dependent on equivalence ratio and nearly independent of strain rate. Thus, this ratio can be used to monitor equivalence ratio. However, a non-monotonic behavior of the OH*/CH* ratio for very lean combustion (ER < 0.7) is observed, in agreement with previous studies. This behavior can be reproduced by the reaction mechanisms. The behavior of OH*/CH(A)* chemiluminescent intensity ratio for flames of methanepropane blends are also calculated with the detailed chemistry model. The addition of propane in methane modifies the behaviour of OH*/CH(A)* chemiluminescent intensity ratio dramatically. However, the numerical results suggest that the OH*/CH(A)* chemiluminescent intensity ratio is an indicator of equivalence ratio in lean methanepropane fuel blended flames

Experimental and numerical study of chemiluminescent species in low-pressure flames

Kathrotia T, Riedel U, Seipel A, Moshammer K, Brockhinke A. Experimental and numerical study of chemiluminescent species in low-pressure flames. APPLIED PHYSICS B. 2012;107(3):571-584