6 research outputs found

    Anomalous Workfunction Anisotropy in Ternary Acetylides

    Full text link
    Anomalous anisotropy of workfunction values in ternary alkali metal transition metal acetylides is reported. Workfunction values of some characteristic surfaces in these emerging semiconducting materials may differ by more than ≈\approx 2 eV as predicted by Density Functional Theory calculations. This large anisotropy is a consequence of the relative orientation of rod-like [MC2_{2}]∞_{\infty} negatively charged polymeric subunits and the surfaces, with M being a transition metal or metalloid element and C2_{2} refers to the acetylide ion C22−_{2}^{2-}, with the rods embedded into an alkali cation matrix. It is shown that the conversion of the seasoned Cs2_{2}Te photo-emissive material to ternary acetylide Cs2_{2}TeC2_{2} results in substantial reduction of its ≈\approx 3 eV workfunction down to 1.71-2.44 eV on the Cs2_{2}TeC2_{2}(010) surface while its high quantum yield is preserved. Similar low workfunction values are predicted for other ternary acetylides as well, allowing for a broad range of applications from improved electron- and light-sources to solar cells, field emission displays, detectors and scanners.Comment: Accepted for publication in Phys. Rev.

    BEAM-BASED ALIGNMENT OF THE FIRST SUPERCONDUCTING UNDULATOR AT THE APS*

    No full text
    Abstract The first test superconducting undulator (SCU0) was successfully installed and commissioned at the Advanced Photon Source (APS) and is delivering 80-to 100-keV photons for user science. The magnet cores are mounted on but thermally isolated from the beam vacuum chamber. Protecting the SCU0 from high beam-induced heat loads was an important requirement before operating the SCU0 in the storage ring. Precise alignment of the beam vacuum chamber with respect to both the electron beam orbit as well as the synchrotron radiation generated in the upstream dipole magnet was therefore extremely important. The beam vacuum chamber was instrumented with nine thermal sensors. Using the sensors, the chamber alignment was determined with 100-micron accuracy. This accuracy is 10 times higher than in a standard aperture scan. Other advantages of the thermal sensorbased alignment method include isolating the SCU0 alignment from other components in the orbit bump and providing good longitudinal spatial resolution. The chamber temperatures agreed well with the predicted heat load and dependence on steering. This novel beam-based alignment method and results will be presented
    corecore