Observation of enhanced rate coefficients in the H2+_2^+ + H2_2 →\rightarrow H3+_3^+ + H reaction at low collision energies

The energy dependence of the rate coefficient of the H$_2^+\ + {\rm H}_2 \rightarrow {\rm H}_3^+ + {\rm H}$ reaction has been measured in the range of collision energies between $k_\mathrm{B}\cdot 10$ K and $k_\mathrm{B}\cdot 300$ mK. A clear deviation of the rate coefficient from the value expected on the basis of the classical Langevin-capture behavior has been observed at collision energies below $k_\mathrm{B}\cdot 1$ K, which is attributed to the joint effects of the ion-quadrupole and Coriolis interactions in collisions involving ortho-H$_2$ molecules in the $j = 1$ rotational level, which make up 75% of the population of the neutral H$_2$ molecules in the experiments. The experimental results are compared to very recent predictions by Dashevskaya, Litvin, Nikitin and Troe (J. Chem. Phys., in press), with which they are in agreement.Comment: 14 pages, 3 figure

Risiken und Nebenwirkungen in der Psychotherapie vermeiden: Was TherapeutInnen von PatientInnen lernen können

Auf der Basis einer Reihe von Wirksamkeitsanalysen wird davon ausgegangen, dass Psychotherapie für die behandelten PatientInnen in der Regel positive Wirkung zeigt. Weniger beforscht und bekannt sind unerwünschte Effekte und Nebenwirkungen in psychotherapeutischen Prozessen. An der Donau-Universität Krems ist ein Forschungsteam den potenziellen Risiken und Fehlerquellen in einem komplexen Forschungsdesign nachgegangen. Unerwünschte Wirkungen in psychotherapeutischen Prozessen treten demnach in einem gewissen Prozentsatz der Behandlungen auf. Negativen Verläufe kann daher nur präventiv und interventiv vorgebeugt werden. Wichtige Faktoren in der Fehlerprävention und -intervention sind Transparenz und Partizipation. Das für die therapeutische Praxis relevante Ergebnis wird im Artikel zur Diskussion gestellt.Based on the results of a series of efficacy studies it is assumed that psychotherapy is generally experienced by patients as having a positive effect. Less well researched and less well-known are undesirable effects and side effects in psychotherapeutic processes. A research team at Donau University, Krems, Austria has investigated the potential risks and sources of error in a complex research design. According to their results, adverse events in psychotherapeutic processes do occur in a certain percentage of cases. Negative processes and outcomes can therefore only be addressed by preventive and remedial interventions. Important factors in error prevention and repair are transparency and participation. The article presents and discusses the results with relevance for therapeutic practice

Reaching and Supporting Trafficked Women in Austria and Germany: A Call for Training on Attachment and Trust-Building

Many victims of trafficking in women are not reached by the available support services despite numerous measures that have been put in place on both the national and international levels. This deficiency is due to the inadequacy of the support systems, which do not meet the needs of the women concerned. A bilateral Austro-German research project entitled “Prävention und Intervention bei Menschenhandel zum Zweck sexueller Ausbeutung (PRIMSA) [“Prevention and intervention in the trafficking of human beings for the purpose of sexual exploitation”] was set up with the aim of developing ideas for a multidisciplinary prevention and intervention scheme. This article presents a case study of one of the women from a Central European country who was interviewed and the selected results on the need for training on trust-building and attachment with victims

New method to study ion-molecule reactions at low temperatures and application to the H2+_2^+ + H2_2 →\rightarrow H3+_3^+ + H reaction

Studies of ion-molecule reactions at low temperatures are difficult because stray electric fields in the reaction volume affect the kinetic energy of charged reaction partners. We describe a new experimental approach to study ion-molecule reactions at low temperatures and present, as example, a measurement of the ${\rm H}_2^+ + {\rm H}_2\rightarrow {\rm H}_3^+ + {\rm H}$ reaction with the ${\rm H}_2^+$ ion prepared in a single rovibrational state at collision energies in the range $E_{\rm col}/k_{\rm B} = 5$-60 K. To reach such low collision energies, we use a merged-beam approach and observe the reaction within the orbit of a Rydberg electron, which shields the ions from stray fields. The first beam is a supersonic beam of pure ground-state H$_2$ molecules and the second is a supersonic beam of H$_2$ molecules excited to Rydberg-Stark states of principal quantum number $n$ selected in the range 20-40. Initially, the two beams propagate along axes separated by an angle of 10$^\circ$. To merge the two beams, the Rydberg molecules in the latter beam are deflected using a surface-electrode Rydberg-Stark deflector. The collision energies of the merged beams are determined by measuring the velocity distributions of the two beams and they are adjusted by changing the temperature of the pulsed valve used to generate the ground-state ${\rm H}_2$ beam and by adapting the electric-potential functions to the electrodes of the deflector. The collision energy is varied down to below $E_{\rm col}/k_{\rm B}= 10$ K, i.e., below $E_{\rm col}\approx 1$ meV, with an energy resolution of 100 $\mu$eV. We demonstrate that the Rydberg electron acts as a spectator and does not affect the cross sections, which are found to closely follow a classical-Langevin-capture model in the collision-energy range investigated. Because all neutral atoms and molecules can be excited to Rydberg states, this method of studyingComment: 39 pages, 10 figure

Patients' perceptions of risky developments during psychotherapy

Research on risks and unwanted effects is largely missing in psychotherapy. Using exploratory factor analysis six dimensions of personal therapy situation were identified in a preliminary study, three of them were associated with risky developments during the psychotherapeutic process: (1) (poor) quality of therapeutic relationship, (2) burden caused by psychotherapy, and (3) dependency/isolation. Based on the finding of this study an online survey was performed to examine these three dimensions. Aside from these three factors another variable was associated with risky therapy developments: the online questionnaire also asked for premature terminations of psychotherapy as a consequence of risky conditions for the therapeutic development. Risky conditions were found to be associated with the following variables: (1) the combination of female patient–male therapist, (2) the therapeutic orientation (particularly with the psychodynamic approaches) and (3) the duration of therapy. Fewer humanistic and systemic psychotherapies were found among the high risk-prone group of patients who were at risk in at least three of the four variables which were associated with risky developments. Differences in the findings of the study regarding the four therapeutic orientations stress the importance of an extensive differential indication and a cooperative partnership between patient and therapist, in order to facilitate a positive patient participation towards the choice of therapy method and subsequent successful participation throughout the course of treatment. Further studies should also focus on female patient and male therapist psychotherapies

Patients’ Perceptions of Risky Developments During Psychotherapy

Research on risks and unwanted effects is largely missing in psychotherapy. Using exploratory factor analysis six dimensions of personal therapy situation were identified in a preliminary study, three of them were associated with risky developments during the psychotherapeutic process: (1) (poor) quality of therapeutic relationship, (2) burden caused by psychotherapy, and (3) dependency/isolation. Based on the finding of this study an online survey was performed to examine these three dimensions. Aside from these three factors another variable was associated with risky therapy developments: the online questionnaire also asked for premature terminations of psychotherapy as a consequence of risky conditions for the therapeutic development. Risky conditions were found to be associated with the following variables: (1) the combination of female patient–male therapist, (2) the therapeutic orientation (particularly with the psychodynamic approaches) and (3) the duration of therapy. Fewer humanistic and systemic psychotherapies were found among the high risk-prone group of patients who were at risk in at least three of the four variables which were associated with risky developments. Differences in the findings of the study regarding the four therapeutic orientations stress the importance of an extensive differential indication and a cooperative partnership between patient and therapist, in order to facilitate a positive patient participation towards the choice of therapy method and subsequent successful participation throughout the course of treatment. Further studies should also focus on female patient and male therapist psychotherapies