3,182 research outputs found
Scattering series in mobility problem for suspensions
The mobility problem for suspension of spherical particles immersed in an
arbitrary flow of a viscous, incompressible fluid is considered in the regime
of low Reynolds numbers. The scattering series which appears in the mobility
problem is simplified. The simplification relies on the reduction of the number
of types of single-particle scattering operators appearing in the scattering
series. In our formulation there is only one type of single-particle scattering
operator.Comment: 11 page
Improved spatial separation of neutral molecules
We have developed and experimentally demonstrated an improved electrostatic
deflector for the spatial separation of molecules according to their
dipole-moment-to-mass ratio. The device features a very open structure that
allows for significantly stronger electric fields as well as for stronger
deflection without molecules crashing into the device itself. We have
demonstrated its performance using the prototypical OCS molecule and we discuss
opportunities regarding improved quantum-state-selectivity for complex
molecules and the deflection of unpolar molecules.Comment: 6 figure
Prioritizing testing of organic compounds detected as gas phase air pollutants: structure-activity study for human contact allergens.
Organic compounds that are used or generated anthropogenically in large quantities in cities can be identified through their presence in the urban atmosphere and in air pollutant source emissions. Compounds identified by this method were screened to evaluate their potential to act as contact allergens. The CASE and MULTICASE computer programs, which are based on the detection of structure-activity relationships (SAR), were used to evaluate this potential. These relationships first are determined by comparing chemical structures to biological activity within a learning set comprised of 458 compounds, each of which had been tested experimentally in human trials for its sensitization potential. Using the information contained in this learning set, CASE and MULTICASE predicted the activity of 238 compounds found in the atmosphere for their ability to act as contact allergens. The analysis finds that 21 of 238 compounds are predicted to be active contact allergens (probability >0.5), with potencies ranging from mild to very strong. The compounds come from chemical classes that include chlorinated aromatics and chlorinated hydrocarbons, N-containing compounds, phenols, alkenes, and an S-containing compound. Using the measured airborne concentrations or emission rates of these compounds as an indication of the extent of their use, together with their predicted potencies, provides an efficient method to prioritize the experimental assessment of contact sensitization of untested organic compounds that can be detected as air pollutants
Extremal spacings between eigenphases of random unitary matrices and their tensor products
Extremal spacings between eigenvalues of random unitary matrices of size N
pertaining to circular ensembles are investigated. Explicit probability
distributions for the minimal spacing for various ensembles are derived for N =
4. We study ensembles of tensor product of k random unitary matrices of size n
which describe independent evolution of a composite quantum system consisting
of k subsystems. In the asymptotic case, as the total dimension N = n^k becomes
large, the nearest neighbor distribution P(s) becomes Poissonian, but
statistics of extreme spacings P(s_min) and P(s_max) reveal certain deviations
from the Poissonian behavior
On the structure of the body of states with positive partial transpose
We show that the convex set of separable mixed states of the 2 x 2 system is
a body of constant height. This fact is used to prove that the probability to
find a random state to be separable equals 2 times the probability to find a
random boundary state to be separable, provided the random states are generated
uniformly with respect to the Hilbert-Schmidt (Euclidean) distance. An
analogous property holds for the set of positive-partial-transpose states for
an arbitrary bipartite system.Comment: 10 pages, 1 figure; ver. 2 - minor changes, new proof of lemma
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