Nonresonant effects in one- and two-photon transitions

We investigate nonresonant contributions to resonant Rayleigh scattering cross sections of atoms. The problematic nonresonant contributions set a limit to the accuracy to which atomic spectra determine energy levels. We discuss the off-resonance effects in one-photon transitions. We also show that off-resonance contributions for the 1S-2S two-photon transition in atomic hydrogen are negligible at current and projected levels of experimental accuracy. The possibility of a differential measurement for the detection of off-resonance effects in one-photon transitions in atomic hydrogen is discussed.Comment: 13 pages, LaTeX, 3 figures; submitted to Can. J. Phys. (Oct 2001); discussion of one-photon transitions enhance

QED theory of transition probabilities and line profiles in highly-charged ions

A rigorous QED theory of the spectral line profiles is applied to transition probabilities in few-electron highly charged ions. Interelectron interaction corrections are included as well as radiative corrections. Parity nonconserving (PNC) amplitudes with effective weak interactions between the electrons and nucleus are also considered. QED and interelectron interaction corrections to the PNC amplitudes are derived

Evaluation of the low-lying energy levels of two- and three-electron configurations for multi-charged ions

Accurate QED evaluations of the one- and two-photon interelectron interaction for low lying two- and three-electron configurations for ions with nuclear charge numbers $60\le Z \le 93$ are performed. The three-photon interaction is also partly taken into account. The Coulomb gauge is employed. The results are compared with available experimental data and with different calculations. A detailed investigation of the behaviour of the energy levels of the configurations $1s_{1/2}2s_{1/2} {}^1 S_0$, $1s_{1/2}2p_{1/2} {}^3 P_0$ near the crossing points Z=64 and Z=92 is carried out. The crossing points are important for the future experimental search for parity nonconserving (PNC) effects in highly charged ions

Accurate spline solutions of the Dirac equation with parity-nonconserving potential

The complete system of the B-spline solutions for the Dirac equation with the parity-nonconserving (PNC) weak interaction effective potential is obtained. This system can be used for the accurate evaluation of the radiative corrections to the PNC amplitudes in the multicharged ions and neutral atoms. The use of the scaling procedure allows for the evaluation of the PNC matrix elements with relative accuracy $10^{-7}$.Comment: 7 page