Absence of long-range chemical ordering in equimolar FeCoCrNi

Equimolar FeCoCrNi alloys have been the topic of recent research as "high-entropy alloys," where the name is derived from the high configurational entropy of mixing for a random solid solution. Despite their name, no systematic study of ordering in this alloy system has been performed to date. Here, we present results from anomalous x-ray scattering and neutron scattering on quenched and annealed samples. An alloy of FeNi_3 was prepared in the same manner to act as a control. Evidence of long-range chemical ordering is clearly observed in the annealed FeNi_3 sample from both experimental techniques. The FeCoCrNi sample given the same heat treatment lacks long-range chemical order

Control of octahedral rotations in (LaNiO3_3)n_{n}/(SrMnO3_3)m_m superlattices

Oxygen octahedral rotations have been measured in short-period (LaNiO$_3$)$_n$/(SrMnO$_3$)$_m$ superlattices using synchrotron diffraction. The in-plane and out-of-plane bond angles and lengths are found to systematically vary with superlattice composition. Rotations are suppressed in structures with $m>n$, producing a nearly cubic form of LaNiO$_3$. Large rotations are present in structures with $m<n$, leading to reduced bond angles in SrMnO$_3$. The metal-oxygen-metal bond lengths decrease as rotations are reduced, in contrast to behavior previously observed in strained, single layer films. This result demonstrates that superlattice structures can be used to stabilize non-equilibrium octahedral behavior in a manner distinct from epitaxial strain, providing a novel means to engineer the electronic and ferroic properties of oxide heterostructures.Comment: 4 pages, 4 figures, submitted to PR

Decoupling carrier concentration and electron-phonon coupling in oxide heterostructures observed with resonant inelastic x-ray scattering

We report the observation of multiple phonon satellite features in ultra thin superlattices of form $n$SrIrO$_3$/$m$SrTiO$_3$ using resonant inelastic x-ray scattering. As the values of $n$ and $m$ vary the energy loss spectra show a systematic evolution in the relative intensity of the phonon satellites. Using a closed-form solution for the cross section, we extract the variation in the electron-phonon coupling strength as a function of $n$ and $m$. Combined with the negligible carrier doping into the SrTiO$_3$ layers, these results indicate that tuning of the electron-phonon coupling can be effectively decoupled from doping. This work showcases both a feasible method to extract the electron-phonon coupling in superlattices and unveils a potential route for tuning this coupling which is often associated with superconductivity in SrTiO$_3$-based systems.Comment: 4 pages, 5 figure

Charge transport and magnetization profile at the interface between a correlated metal and an antiferromagnetic insulator

A combination of spectroscopic probes was used to develop a detailed experimental description of the transport and magnetic properties of superlattices composed of the paramagnetic metal CaRuO$_3$ and the antiferromagnetic insulator CaMnO$_3$. The charge carrier density and Ru valence state in the superlattices are not significantly different from those of bulk CaRuO$_3$. The small charge transfer across the interface implied by these observations confirms predictions derived from density functional calculations. However, a ferromagnetic polarization due to canted Mn spins penetrates 3-4 unit cells into CaMnO$_3$, far exceeding the corresponding predictions. The discrepancy may indicate the formation of magnetic polarons at the interface.Comment: 4 pages, 3 figure

Enhanced interfacial ferromagnetism and exchange bias in (111)-oriented LaNiO3/CaMnO3 superlattices

Emergent properties of complex oxide interfaces are based on interface reconstruction that is driven by mismatch of electronic bands, valence states, interaction lengths, and even crystal symmetry of the interface. In particular, emergent ferromagnetism at the interface of two materials that do not exhibit ferro- or ferrimagnetism in the bulk has been stabilized as a result of competing exchange interactions. When LaNiO3 and CaMnO3, which are a paramagnetic metal and antiferromagnetic insulator in the bulk, respectively, are brought together, ferromagnetism emerges at the interface. Here we show that in (111)-oriented LaNiO3/CaMnO3 (LNO/CMO) superlattices, Ni2+-Mn4+ superexchange interactions due to polar mismatch at the LNO/CMO interfaces are responsible for the emergent ferromagnetism. Compared to (001)-oriented LNO/CMO superlattices, (111)-oriented LNO/CMO superlattices exhibit enhanced interfacial ferromagnetism with a TC&gt;200 K, greater than the bulk antiferromagnetic transition temperature of CaMnO3 and a saturated magnetic moment enhanced by up to a factor of 3. Furthermore, we observe exchange bias in (111)-oriented superlattices. The strong exchange interactions along the (111) interface, manifest in the enhanced Tc and exchange bias, make this class of CMO-based materials with (111)-oriented interfaces good candidates for low-dimensional spin-polarized materials in spintronic applications