Anion receptor chemistry: highlights from 2011 and 2012

This review covers advances in anion complexation in the years 2011 and 2012. The review covers both organic and inorganic systems and also highlights the applications to which anion receptors can be applied such as self-assembly and molecular architecture, sensing, catalysis and anion transport

Highly effective yet simple transmembrane anion transporters based upon ortho-phenylenediamine bis-ureas

Simple, highly fluorinated receptors are shown to function as highly effective transmembrane anion antiporters with the most active transporters rivalling the transport efficacy of natural anion transporter prodigiosin for bicarbonate

Uplink NOMA for UAV-Aided Maritime Internet-of-Things

Maritime activities are vital for economic growth, being further accelerated by various emerging maritime Internet of Things (IoT) use cases, including smart ports, autonomous navigation, and ocean monitoring systems. However, broadband, low-delay, and reliable wireless connectivity to the ever-increasing number of vessels, buoys, platforms and sensors in maritime communication networks (MCNs) has not yet been achieved. Towards this end, the integration of unmanned aerial vehicles (UAVs) in MCNs provides an aerial dimension to current deployments, relying on shore-based base stations (BSs) with limited coverage and satellite links with high latency. In this work, a maritime IoT topology is examined where direct uplink communication with a shore BS cannot be established due to excessive pathloss. In this context, we employ multiple UAVs for end-to-end connectivity, simultaneously receiving data from the maritime IoT nodes, following the non-orthogonal multiple access (NOMA) paradigm. In contrast to other UAV-aided NOMA schemes in maritime settings, dynamic decoding ordering at the UAVs is used to improve the performance of successive interference cancellation (SIC), considering the rate requirements and the channel state information (CSI) of each maritime node towards the UAVs. Moreover, the UAVs are equipped with buffers to store data and provide increased degrees of freedom in opportunistic UAV selection. Simulations reveal that the proposed opportunistic UAV-aided NOMA improves the average sum-rate of NOMA-based maritime IoT communication, leveraging the dynamic decoding ordering and caching capabilities of the UAVs

Diversity combining in hybrid RF/FSO systems with PSK modulation

We present a novel architecture for hybrid radio frequency (RF)/ free space optical (FSO) wireless systems without feedback or channel state information (CSI) at the transmitter. Under the assumption that 60 GHz RF and FSO systems support the same data rates, the proposed implementation transmits the same data over both links, using phase shift keying (PSK) as a common modulation scheme, and combines the signals from each individual link at the receiver on a symbol-by-symbol basis. Two popular diversity combining schemes are considered, namely, selection combining (SC) and maximal ratio combining (MRC), while tractable analytical approximations for the bit error rate (BER) are obtained. Investigations over various weather conditions and link distances revealed that the proposed implementation fully exploits the complementary nature of RF and FSO channels, even when one of the two available links fails. Furthermore, the comparison of the combining schemes demonstrates MRC as the optimum combining scheme, offering link distance gains compared to SC

New nanocomposites based on poly(benzoxazine-co-epoxy) matrix reinforced by novel graphene single and mixed blend fillers

We report new nanocomposites with poly(benzoxazine-co-epoxy) matrix reinforced with 1wt% graphene. Curabox 24-111, a benzoxazine resin was copolymerised with Epilok 60-566, a mixture of epoxy resins. Copolymerization was also carried out in the presence of different graphene powders namely Nanene-001 and Nanene-002, used as single fillers and as mixture (relative weight ratio 70:30 or 30:70). DSC results showed the addition of either single filler caused a delay in polymerisation and an increase in the exothermic peak temperature of the curing reaction with a related reduction in ΔHTotal. compared to the neat copolymer. Copolymerisation showed a 38% reduction and 24% increase in tensile modulus (E) compared to the neat polybenzoxazine and epoxy polymer, with a respective 18% and 30% reduction in tensile strength (TS). Nanocomposites with 0.7wt% Nanene-002 + 0.3wt% Nanene-001 showed the highest increase of 35% in TS, a 1.6% reduction in E and 36% increase in elongation at break (EB) compared to the neat copolymer matrix. Samples with 1wt% Nanene-001 showed the largest reduction of 21% in E, a 27% increase in TS and a 45% increase in EB. Additionally, TGA thermographs showed a 22℃ increase in the onset of degradation (300℃ to 322℃) improving the materials thermal stability