1,995 research outputs found
A Model Ground State of Polyampholytes
The ground state of randomly charged polyampholytes is conjectured to have a
structure similar to a necklace, made of weakly charged parts of the chain,
compacting into globules, connected by highly charged stretched `strings'. We
suggest a specific structure, within the necklace model, where all the neutral
parts of the chain compact into globules: The longest neutral segment compacts
into a globule; in the remaining part of the chain, the longest neutral segment
(the 2nd longest neutral segment) compacts into a globule, then the 3rd, and so
on. We investigate the size distributions of the longest neutral segments in
random charge sequences, using analytical and Monte Carlo methods. We show that
the length of the n-th longest neutral segment in a sequence of N monomers is
proportional to N/(n^2), while the mean number of neutral segments increases as
sqrt(N). The polyampholyte in the ground state within our model is found to
have an average linear size proportional to sqrt(N), and an average surface
area proportional to N^(2/3).Comment: 8 two-column pages. 5 eps figures. RevTex. Submitted to Phys. Rev.
Ground States of Two-Dimensional Polyampholytes
We perform an exact enumeration study of polymers formed from a (quenched)
random sequence of charged monomers , restricted to a 2-dimensional
square lattice. Monomers interact via a logarithmic (Coulomb) interaction. We
study the ground state properties of the polymers as a function of their excess
charge for all possible charge sequences up to a polymer length N=18. We
find that the ground state of the neutral ensemble is compact and its energy
extensive and self-averaging. The addition of small excess charge causes an
expansion of the ground state with the monomer density depending only on .
In an annealed ensemble the ground state is fully stretched for any excess
charge .Comment: 6 pages, 6 eps figures, RevTex, Submitted to Phys. Rev.
Self-consistent variational theory for globules
A self-consistent variational theory for globules based on the uniform
expansion method is presented. This method, first introduced by Edwards and
Singh to estimate the size of a self-avoiding chain, is restricted to a good
solvent regime, where two-body repulsion leads to chain swelling. We extend the
variational method to a poor solvent regime where the balance between the
two-body attractive and the three-body repulsive interactions leads to
contraction of the chain to form a globule. By employing the Ginzburg
criterion, we recover the correct scaling for the -temperature. The
introduction of the three-body interaction term in the variational scheme
recovers the correct scaling for the two important length scales in the globule
- its overall size , and the thermal blob size . Since these two
length scales follow very different statistics - Gaussian on length scales
, and space filling on length scale - our approach extends the
validity of the uniform expansion method to non-uniform contraction rendering
it applicable to polymeric systems with attractive interactions. We present one
such application by studying the Rayleigh instability of polyelectrolyte
globules in poor solvents. At a critical fraction of charged monomers, ,
along the chain backbone, we observe a clear indication of a first-order
transition from a globular state at small , to a stretched state at large
; in the intermediate regime the bistable equilibrium between these two
states shows the existence of a pearl-necklace structure.Comment: 7 pages, 1 figur
Statistical properties of charged interfaces
We consider the equilibrium statistical properties of interfaces submitted to
competing interactions; a long-range repulsive Coulomb interaction inherent to
the charged interface and a short-range, anisotropic, attractive one due to
either elasticity or confinement. We focus on one-dimensional interfaces such
as strings. Model systems considered for applications are mainly aggregates of
solitons in polyacetylene and other charge density wave systems, domain lines
in uniaxial ferroelectrics and the stripe phase of oxides. At zero temperature,
we find a shape instability which lead, via phase transitions, to tilted
phases. Depending on the regime, elastic or confinement, the order of the
zero-temperature transition changes. Thermal fluctuations lead to a pure
Coulomb roughening of the string, in addition to the usual one, and to the
presence of angular kinks. We suggest that such instabilities might explain the
tilting of stripes in cuprate oxides. The 3D problem of the charged wall is
also analyzed. The latter experiences instabilities towards various tilted
phases separated by a tricritical point in the elastic regime. In the
confinement regime, the increase of dimensionality favors either the melting of
the wall into a Wigner crystal of its constituent charges or a strongly
inclined wall which might have been observed in nickelate oxides.Comment: 17 pages, 11 figure
Damping of sound waves in superfluid nucleon-hyperon matter of neutron stars
We consider sound waves in superfluid nucleon-hyperon matter of massive
neutron-star cores. We calculate and analyze the speeds of sound modes and
their damping times due to the shear viscosity and non-equilibrium weak
processes of particle transformations. For that, we employ the dissipative
relativistic hydrodynamics of a superfluid nucleon-hyperon mixture, formulated
recently [M.E. Gusakov and E.M. Kantor, Phys. Rev. D78, 083006 (2008)]. We
demonstrate that the damping times of sound modes calculated using this
hydrodynamics and the ordinary (nonsuperfluid) one, can differ from each other
by several orders of magnitude.Comment: 15 pages, 5 figures, Phys. Rev. D accepte
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