A Model Ground State of Polyampholytes

The ground state of randomly charged polyampholytes is conjectured to have a structure similar to a necklace, made of weakly charged parts of the chain, compacting into globules, connected by highly charged stretched `strings'. We suggest a specific structure, within the necklace model, where all the neutral parts of the chain compact into globules: The longest neutral segment compacts into a globule; in the remaining part of the chain, the longest neutral segment (the 2nd longest neutral segment) compacts into a globule, then the 3rd, and so on. We investigate the size distributions of the longest neutral segments in random charge sequences, using analytical and Monte Carlo methods. We show that the length of the n-th longest neutral segment in a sequence of N monomers is proportional to N/(n^2), while the mean number of neutral segments increases as sqrt(N). The polyampholyte in the ground state within our model is found to have an average linear size proportional to sqrt(N), and an average surface area proportional to N^(2/3).Comment: 8 two-column pages. 5 eps figures. RevTex. Submitted to Phys. Rev.

Effects of Self-Avoidance on the Tubular Phase of Anisotropic Membranes

We study the tubular phase of self-avoiding anisotropic membranes. We discuss the renormalizability of the model Hamiltonian describing this phase and derive from a renormalization group equation some general scaling relations for the exponents of the model. We show how particular choices of renormalization factors reproduce the Gaussian result, the Flory theory and the Gaussian Variational treatment of the problem. We then study the perturbative renormalization to one loop in the self-avoiding parameter using dimensional regularization and an epsilon-expansion about the upper critical dimension, and determine the critical exponents to first order in epsilon.Comment: 19 pages, TeX, uses Harvmac. Revised Title and updated references: to appear in Phys. Rev.

Self-consistent variational theory for globules

A self-consistent variational theory for globules based on the uniform expansion method is presented. This method, first introduced by Edwards and Singh to estimate the size of a self-avoiding chain, is restricted to a good solvent regime, where two-body repulsion leads to chain swelling. We extend the variational method to a poor solvent regime where the balance between the two-body attractive and the three-body repulsive interactions leads to contraction of the chain to form a globule. By employing the Ginzburg criterion, we recover the correct scaling for the $\theta$-temperature. The introduction of the three-body interaction term in the variational scheme recovers the correct scaling for the two important length scales in the globule - its overall size $R$, and the thermal blob size $\xi_{T}$. Since these two length scales follow very different statistics - Gaussian on length scales $\xi_{T}$, and space filling on length scale $R$ - our approach extends the validity of the uniform expansion method to non-uniform contraction rendering it applicable to polymeric systems with attractive interactions. We present one such application by studying the Rayleigh instability of polyelectrolyte globules in poor solvents. At a critical fraction of charged monomers, $f_c$, along the chain backbone, we observe a clear indication of a first-order transition from a globular state at small $f$, to a stretched state at large $f$; in the intermediate regime the bistable equilibrium between these two states shows the existence of a pearl-necklace structure.Comment: 7 pages, 1 figur

Strongly regular graphs satisfying the 4-vertex condition

We survey the area of strongly regular graphs satisfying the 4-vertex condition and find several new families. We describe a switching operation on collinearity graphs of polar spaces that produces cospectral graphs. The obtained graphs satisfy the 4-vertex condition if the original graph belongs to a symplectic polar space.Comment: 19 page

Collineation group as a subgroup of the symmetric group

Let $\Psi$ be the projectivization (i.e., the set of one-dimensional vector subspaces) of a vector space of dimension $\ge 3$ over a field. Let $H$ be a closed (in the pointwise convergence topology) subgroup of the permutation group $\mathfrak{S}_{\Psi}$ of the set $\Psi$. Suppose that $H$ contains the projective group and an arbitrary self-bijection of $\Psi$ transforming a triple of collinear points to a non-collinear triple. It is well-known from \cite{KantorMcDonough} that if $\Psi$ is finite then $H$ contains the alternating subgroup $\mathfrak{A}_{\Psi}$ of $\mathfrak{S}_{\Psi}$. We show in Theorem \ref{density} below that $H=\mathfrak{S}_{\Psi}$, if $\Psi$ is infinite.Comment: 9 page