Amine-Functionalized Graphene/CdS Composite for Photocatalytic Reduction of CO₂

This study provides a significant enhancement in CO₂ photoconversion efficiency by the functionalization of a reduced graphene oxide/cadmium sulfide composite (rGO/CdS) with amine. The amine-functionalized graphene/CdS composite (AG/CdS) was obtained in two steps. First, graphene oxide (GO) was selectively deposited via electrostatic interaction with CdS nanoparticles modified with 3-aminopropyltriethoxysilane. Subsequently, ethylenediamine (NH₂C₂H₄NH₂) was grafted by an <i>N</i>,<i>N</i>′-dicyclohexylcarbodiimide coupling reaction between the amine group of ethylenediamine and the carboxylic group of GO. As a result, a few layers of amine-functionalized graphene wrapped CdS uniformly, forming a large interfacial area. Under visible light, the photocurrent through the AG/CdS significantly increased because of enhanced charge separation in CdS. The CO₂ adsorption capacity on AG/CdS was 4 times greater than that on rGO/CdS at 1 bar. These effects resulted in a methane formation rate of 2.84 μmol/(g h) under visible light and CO₂ at 1 bar, corresponding to 3.5 times that observed for rGO/CdS. Interestingly, a high methane formation rate (1.62 μmol/(g h)) was observed for AG/CdS under CO₂ at low pressure (0.1 bar), corresponding to a value 20 times greater than that observed for the rGO/CdS. Thus, the enhanced performance for photocatalytic reduction of CO₂ on the AG/CdS is due to the improved CO₂ adsorption related to the amine groups on amine-functionalized graphene, which sustains the strong absorption of visible light and superior charge-transfer properties in comparison with those of graphene

Rational Design of Aminopolymer for Selective Discrimination of Acidic Air Pollutants

Strong acidic gases such as CO₂, SO₂, and NO₂ are harsh air pollutants with major human health threatening factors, and as such, developing new tools to monitor and to quickly sense these gases is critically required. However, it is difficult to selectively detect the acidic air pollutants with single channel material due to the similar chemistry shared by acidic molecules. In this work, three acidic gases (i.e., CO₂, SO₂, and NO₂) are selectively discriminated using single channel material with precise moiety design. By changing the composition ratio of primary (1°), secondary (2°), and tertiary (3°) amines of polyethylenimine (PEI) on CNT channels, unprecedented high selectivity between CO₂ and SO₂ is achieved. Using in situ FT-IR characterizations, the distinct adsorption phenomenon of acidic gases on each amine moiety is precisely demonstrated. Our approach is the first attempt at controlling gas adsorption selectivity of solid-state sensor via modulating chemical moiety level within the single channel material. In addition, discrimination of CO₂, SO₂, and NO₂ with the single channel material solid-state sensor is first reported. We believe that this approach can greatly enhance air pollution tracking systems for strong acidic pollutants and thus aid future studies on selective solid-state gas sensors