18 research outputs found
Preparation and Hydrosilylation Activity of a Molybdenum Carbonyl Complex That Features a Pentadentate Bis(imino)pyridine Ligand
Full text linkEnantiomerically pure cyclopentadienyl- and indenyl-functionalized N-heterocyclic carbene complexes of iridium and rhodium
No full textNovel enantiomerically pure cyclopentadienyl- and indenyl-functionalized N-heterocyclic carbene ligands have been prepared by reaction of a chiral imidazole tosylate derivative with the corresponding cyclopentadienyl and indenyl lithium salts. Coordination of the Cp-functionalized NHC ligand to iridium and rhodium allowed the preparation of enantiomerically pure chelating cyclopentadienyl-functionalized Ir(III) and Rh(III) metal complexes. In contrast, the indenyl-functionalized NHC coordinates to iridium in a monodentate fashion, giving an Ir(I)-NHC complex containing a dangling indene group
Enantiomerically Pure Cyclopentadienyl- and Indenyl-Functionalized N-Heterocyclic Carbene Complexes of Iridium and Rhodium
No full textCyclopentadienyl Molybdenum(II) N,C-Chelating Benzothiazole-Carbene Complexes: Synthesis, Structure, and Application in Cyclooctene Epoxidation Catalysis
No full textCyclopentadienyl molybdenum(II/VI) N-heterocyclic carbene complexes: Synthesis, structure, and reactivity under oxidative conditions
No full text10.1021/om900980aOrganometallics2981924-1933ORGN
Iron(II) Complexes Bearing Chelating Cyclopentadienyl-N-Heterocyclic Carbene Ligands as Catalysts for Hydrosilylation and Hydrogen Transfer Reactions
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