18 research outputs found

    Preparation and Hydrosilylation Activity of a Molybdenum Carbonyl Complex That Features a Pentadentate Bis(imino)pyridine Ligand

    Full text link

    Enantiomerically pure cyclopentadienyl- and indenyl-functionalized N-heterocyclic carbene complexes of iridium and rhodium

    No full text
    Novel enantiomerically pure cyclopentadienyl- and indenyl-functionalized N-heterocyclic carbene ligands have been prepared by reaction of a chiral imidazole tosylate derivative with the corresponding cyclopentadienyl and indenyl lithium salts. Coordination of the Cp-functionalized NHC ligand to iridium and rhodium allowed the preparation of enantiomerically pure chelating cyclopentadienyl-functionalized Ir(III) and Rh(III) metal complexes. In contrast, the indenyl-functionalized NHC coordinates to iridium in a monodentate fashion, giving an Ir(I)-NHC complex containing a dangling indene group

    Mechanism of Al 3+

    No full text
    corecore