1 research outputs found
Evolution of Visible Photocatalytic Properties of Cu-Doped CeO<sub>2</sub> Nanoparticles: Role of Cu<sup>2+</sup>-Mediated Oxygen Vacancies and the Mixed-Valence States of Ce Ions
We
report the contribution of oxygen vacancies for enhancing the
optical and visible photocatalytic properties of Cu-doped CeO<sub>2</sub> nanoparticles (NPs) synthesized through a low-temperature
coprecipitation method. Doping Cu ions in the ceria lattice in different
mole percentages, 0, 3, 5, 7, 9, and 15 wt %, results in enhancement
of visible photocatalytic properties even under natural sunlight.
Transmission electron microscopy and X-ray diffraction studies showcase
the monodispersive nature of Cu-doped CeO<sub>2</sub> NPs in the size
range of 3–7 nm with face-centered cubic structure. The Cu-based
defect states induce a narrow band function in ceria nanostructures
and influence the red shift in absorption with the Cu concentrations.
Visible photocatalytic degradation of methylene blue was investigated
in the presence of pure CeO<sub>2</sub> NPs, CuO NPs, and Cu-doped
CeO<sub>2</sub> NPs. These studies revealed that the 7 wt % of Cu-doped
CeO<sub>2</sub> NPs exhibit the degradation rates of 1.41 × 10<sup>–2</sup> and 1.12 × 10<sup>–2</sup> min<sup>–1</sup> under exposure to natural sunlight and visible light (Xe light
source), respectively. This is nearly 23.5 and 1.61 times faster than
the undoped CeO<sub>2</sub> and CuO NPs, respectively. The inclusion
of more Cu<sup>2+</sup> ions in the CeO<sub>2</sub> structure leads
to the interaction and spatial distribution of oxygen vacancies with
a Ce<sup>4+</sup>/Ce<sup>3+</sup> ratio defect. This promotes the
narrowing of the band function to the visible photocatalytic characteristics.
Detailed investigations from X-ray absorption spectroscopy support
the fact that the oxygen vacancies may strongly affect the valences
of Ce ions in CeO<sub>2</sub>, which improves the carrier mobility
and visible response