Removal of metoprolol from aqueous solutions by the activated carbon prepared from pine cones

Background: Metoprolol (MTP) with its low biodegradability is one of the most dominant micropollutant in the effluent of wastewater treatment plants. The aim of this study was to investigate the removal of metoprolol from aqueous solutions by the activated carbon prepared from pine cones. Methods: The pine cones were activated using thermal activation method. Characteristics of the adsorbent were determined using Brunauer-Emmett-Teller (BET) and scanning electron microscopy (SEM). In this study, the influent of different parameters such as pH, contact time, initial concentrations of metoprolol, adsorbent dose, temperature, adsorption isotherms, and kinetics were investigated. Results: The maximum removal efficiency of MTP (89.2%) was obtained at pH=8.5, adsorbent dose=1.5 g, contact time=60 min, and initial concentration=50 mg/L. By increasing the adsorbent dose, the removal efficiency also increased, but the adsorption capacity decreased, however, by increasing the initial concentration, the removal efficiency decreased, but the adsorption capacity increased. The isotherm experimental data for metoprolol was best fitted using the Langmuir model, and kinetic data were better described by pseudo-second-order kinetic model. The thermodynamic study indicated that the adsorption of MTP by the adsorbent was feasible, spontaneous, and endothermic. Conclusion: MTP removal by the activated carbon prepared from pine cones showed that this natural adsorbent is appropriate for removal of metoprolol from aqueous solutions regarding cost, efficiency, and production method. Keywords: Metoprolol, Adsorption, Pine cones, Isotherm, Kinetics, Thermodynamic

Data of heavy metals in soil and groundwater at Kiwi gardens of Amlash in Guilan Province, Iran

Data on this paper describe the concentrations of arsenic, cadmium, copper, nickel, lead and zinc in the surface soils and groundwater's of Kiwi gardens and its relation to chemical fertilizers in Amlash city, Guilan Province, in Iran. The results of this study showed that the average concentration of heavy metals in groundwater and soils of the studied areas was less than the national standards of Iran for irrigation water, Dutch MPA for soils (except Cu and Ni) and Canadian MAC for inorganic fertilizers. Considering that after fertilizing to soils used in gardening, the concentration of heavy metals in groundwater and soil can be increased significantly, so that chemical fertilizers can be considered as an effective factor in increasing the amount of heavy metals in water and soil. The results of this research can be used by who concern about water and soil quality related to fertilizing and also can be used by Rural Water and Wastewater Company and Ministry of Jahad Agriculture of Iran. Keywords: Heavy metals, Chemical fertilizer, Soil & groundwater pollution, Amlas

Characterization, kinetic, thermodynamic and isotherm data for diclofenac removal from aqueous solution by activated carbon derived from pine tree

The usage of low cost material as adsorbent would be admirable from environmental point of view. Thus, herein, this data set present a simple method for providing an adsorbent from activated carbon derived from pine tree. The prepared adsorbent was applied to remove diclofenac from aqueous solution. The characterization data of the adsorbent was analyzed using FTIR method. The FTIR test results showed that adsorbent has a functional group that is useful in adsorption process. It was conducted in laboratory scale and the adsorption technique was batch technique. The information regarding isotherms of diclofenac adsorption were listed. The Langmuir isotherm was suitable for correlation of equilibrium data with correlation coefficient value of 0.999. Adsorption of diclofenac by adsorbent from activated carbon follows pseudo second order model with correlation coefficient value (R2) of 0.9997. The data implied that the maximum adsorption capacity of adsorbent to uptake diclofenac from aqueous solution was obtained 54.67 mg/g. The acquired data indicated that the adsorption of diclofenac by the adsorbent prepared from activated carbon derived from pine tree is a promising technique for treating diclofenac bearing wastewaters. Keywords: Adsorption, Diclofenac removal, Kinetic, Thermodynamic, Isotherm dat

Survey Removal Efficiency of Cadmium from Aqueous Solutions Using Commercial Aluminum nano oxide: Kinetic Study of the Equilibrium

Background: Human activities often diffuse heavy metal to the environment, which bring hazards up for human health when the concentration of these metals reaches high levels. The purpose of this study is evaluation effect of aluminum oxide Nano particles on cadmium removal from aquatic environment. Methods: This is a fundamental applied study which has been performed in order to investigation cadmium removal by using gamma aluminum nano oxide commercially prepared. In present study effects of pH, nano aluminum oxide concentration, initial concentration of cadmium, and contact time on kinetics and adsorption isotherm of cadmium by gamma Nano aluminum oxide were studied. Results: The results of experiments showed that cadmium ion had maximum adsorption over nano aluminum oxide on pH=3. Also by increasing adsorbent dose, adsorption efficiency was increased as by addition nano aluminum oxide from 0.5 g up to 4 g, the adsorption efficiency reached to 33%. By increasing cadmium initial concentration from 5 to 10 mg, removal efficiency was decreased from 29% to 25%. However the best time for adsorption was obtained at 60 minutes and the remaining time had no more effect on the removal efficiency. Data related to isotherm test for nano aluminum oxide has more conformity with Freundlich isotherm model (R2=0.9998). The results of cadmium adsorption kinetic showed that nano aluminum oxide has followed second order kinetic model (R2=0.9879). Conclusion: Nano Gamma-aluminum oxide adsorbent can introduce as an adsorbent for removal of cadmium from aquatic environment

Multidimensional Structure for Definingthe Effect of Organizational Culture and Supply Chain Culture on Knowledge Sharing in Supply Chain of Automotive Industry: With Emphasis on Improving Supply Chain Performance

: One of the key aspects of knowledge management is organizational culture. Finding an appropriate culture and key indicators for culture in implementation and execution of knowledge management are one the most important matter in knowledge management implementation in any organization. So, the main purpose of this article was presenting a multidimensional structure for organizational culture and supply chain culture with the aim of effective knowledge sharing in supply chain of automotive industry of Iran. First, according to the literature review, key indicators for any dimension of multidimensional structure of the research were defined. Then, key indicators were revised, adjusted and modified by three industry experts and three college professors, so 4 questions and 5 hypotheses were offered. Next, that multidimensional structure has been assessed as a survey and cause-effect study in supply chains of Iran Khodro Company and Saipa Company.115 industry professionals have participated in this study. In the research, after testing co-linearity between variables, relations between different dimensions of the multidimensional structure have been assessed with the help of path analysis. Research findings showed that the multidimensional structure introduced in the study had an appropriate fitness in automotive industry. The results of path analysis also showed that the culture of the supply chain has had the greatest impact of Business culture. On the other hand, business culture had a strong but indirect effect on supply chain performance. And finally, the greatest effect of knowledge sharing and transferring was on non-financial performance of supply chain

How to Create Business Value through Information Technology (A Case Study on Automotive Production)

This study aimed at designing information technology business value model in order to explain the value of information technology in business and evaluate information technology contribution in organization function. For the purpose of a comprehensive analysis of the subject using qualitative data, the research method was set to be mixed method focusing on qualitative sequential design. The first stage of the research strategy was an exploratory single case study and for the second phase, the researchers used focus groups design. Saipa Corporation, one of the most famous firms in Iranian automotive industry, was selected as the case. The varied qualitative date were gathered through interview, document review and observation methods and were analyzed afterwards. Ultimately, the findings of the study highlighted the items and dimensions of information technology business value. This model is composed of the relationship between different dimensions of the theoretical models regarding and the share of information technology in building a business. In order to ensure research generalizability, the results of the research were compared with those in the literature review and the theoretic adequacy of the proposed framework was confirmed

Data on pollutants content in the influent and effluent from wastewater treatment plant of Rasht in Guilan Province, Iran

Data on this paper show the concentrations of COD, BOD5, TSS, K+, Ca2+, Na+, Cl−, NO3−, PO42+, Mn2+, Fe2+, Mg2+, Zn2+, Ni, Pb, Cu and Cd in the influent and effluent of wastewater, and also the nematode eggs, total and fecal coliform in effluents from wastewater treatment plant of Rasht, Guilan Province, in Iran. Measurements of pollutants in influent and effluent was measured according to standard methods (W.E. Federation and Association, A. P. H., 2005) [1]. Statistical analysis of the data was carried out using Special Package for Social Sciences (SPSS 16). Keywords: Wastewater, Influent, Effluent, Treatment, Rash

Phytoremediation of heavy metals (Ni, Cd, Pb) by Azolla filiculoides from aqueous solution: A dataset

In this article, the data of heavy metals phytoremediation efficiency were provided. The Azolla was collected from the lake around the Rasht city and washed in tap water, then weighed (0.2, 0.4 and 0.8 g), and kept for 15 days in the 100 ml disposable container in the presence 5, 10 and 25 mg/L of lead, nickel and cadmium ions. The samples were stored in polyethylene containers for analysis of the metal concentration with ICP-OES. According to the results, removal efficiency was increased from 40% to 70% at 10 days along with the increasing of the biomass from 2.0 to 8.0 g. The removal efficiency of Ni (II), Cd (II), and Pb (II) were increased by increasing the contact time up to 10 days. The removal efficiency decreased by increasing of the metals concentration from 5 to 25 mg/L. The highest removal efficiency was observed at heavy metals concentrations of 5 mg/L and contact time of 10 days. Results showed that Azolla had a high potential for the removal of heavy metals from water resources and it can be used in phytoremediation of heavy metals in environmental refinement projects. Keywords: Phytoremediation, Azolla filiculoides, Aqueous solution, Heavy metal