Corrosion properties of tempered medium carbon steel in 1.0 M HCl and homemade vinegar

ABSTRACT. The consumable palm wine has never been used in heat treatment process of steels. This research therefore focuses on the utilization of the consumable palm wine and other palm tree products as quenchants. The mechanical and physical properties of the samples were also evaluated to determine which of the quenchants that influences the hardness and corrosion rate values of medium carbon steel the most. The corrosion test was performed in 1.0 M of HCl solution and homemade vinegar using potentiodynamic polarization method. The results revealed a hardness value of 431, 351, 359 and 265 HB for the samples quenched in palm wine, palm kernel oil, palm oil and as-received, respectively. The corrosion rates of palm oil tempered samples showed more susceptibity to corrosion in HCl solution with a value of 2.261e+003 mil/year. Vinegar offers the highest corrosion rate with a value of 4.017e+002 mil/year for palm wine tempered. The corrosion rate of the as-received samples pulled the lowest values while on the treated samples, palm kernel oil showed the least corrosion rate values.   KEY WORDS: Consumable palm wine, Palm oil, Hardness, Corrosion rate, Austenitization, Quenching   Bull. Chem. Soc. Ethiop. 2022, 36(4), 893-901.                                                               DOI: https://dx.doi.org/10.4314/bcse.v36i4.14                                                     &nbsp

Modified activation process for supercapacitor electrode materials from African maize cob

In this work, African maize cobs (AMC) were used as a rich biomass precursor to synthesize carbon material through a chemical activation process for application in electrochemical energy storage devices. The carbonization and activation were carried out with concentrated Sulphuric acid at three different temperatures of 600, 700 and 800 °C, respectively. The activated carbon exhibited excellent microporous and mesoporous structure with a specific surface area that ranges between 30 and 254 m2·g−1 as measured by BET analysis. The morphology and structure of the produced materials are analyzed through Field Emission Scanning Electron Microscopy (FESEM), Fourier Transform Infrared Spectroscopy (FTIR), X-Ray Diffraction (XRD), Boehm titration, X-ray Photoelectron Spectroscopy (XPS) and Raman Spectroscopy. X-ray photoelectron spectroscopy indicates that a considerable amount of oxygen is present in the materials. The functional groups in the activated carbon enhanced the electrochemical performance and improved the material’s double-layer capacitance. The carbonized composite activated at 700 °C exhibited excellent capacitance of 456 F g−1 at a specific current of 0.25 A g−1 in 6 M KOH electrolyte and showed excellent stability after 10,000 cycles. Besides being a low cost, the produced materials offer good stability and electrochemical properties, making them suitable for supercapacitor applications

Mechanical and Thermomechanical Properties of Clay-Cowpea (Vigna Unguiculata Walp.) Husks Polyester Bio-Composite for Building Applications

This study investigates the feasibility of creating a clay polymer-based composite using cowpea husk (CPH) as filler for production of roof tiles. Polymeric composites were fabricated by mixing unsaturated polyester (UPT) resin with cowpea husk at different filler weights and curing. A hybrid composite was produced with the addition of 3 wt.% clay and all samples produced were subjected to flexural, hardness and dynamic mechanical analysis (DMA) tests. The effect of clay addition on the mechanical and thermo-mechanical behaviour of formulated composites was investigated. The morphological analysis of the mono and hybrid system shows a rough and coarse inhomogeneous surface with voids created due to the addition of CPH filler for the mono reinforced and clay uniformly filling the voids that were created by the CPH in the hybrid composite. It is observed that hardness, tensile modulus and flexural modulus of hybrid composites increase with an increase in the CPH contents, while the strength and flexural strength all decrease with filler content. The optimal composition was obtained using Grey relational analysis (GRA) at 18% CPH for both mono and hybrid composite. The results imply that the composite combination can be used in making rooftiles and/or also in applications where low strength is required

Mechanical and Thermomechanical Properties of Clay-Cowpea (Vigna Unguiculata Walp.) Husks Polyester Bio-Composite for Building Applications

This study investigates the feasibility of creating a clay polymer-based composite using cowpea husk (CPH) as filler for production of roof tiles. Polymeric composites were fabricated by mixing unsaturated polyester (UPT) resin with cowpea husk at different filler weights and curing. A hybrid composite was produced with the addition of 3 wt.% clay and all samples produced were subjected to flexural, hardness and dynamic mechanical analysis (DMA) tests. The effect of clay addition on the mechanical and thermo-mechanical behaviour of formulated composites was investigated. The morphological analysis of the mono and hybrid system shows a rough and coarse inhomogeneous surface with voids created due to the addition of CPH filler for the mono reinforced and clay uniformly filling the voids that were created by the CPH in the hybrid composite. It is observed that hardness, tensile modulus and flexural modulus of hybrid composites increase with an increase in the CPH contents, while the strength and flexural strength all decrease with filler content. The optimal composition was obtained using Grey relational analysis (GRA) at 18% CPH for both mono and hybrid composite. The results imply that the composite combination can be used in making rooftiles and/or also in applications where low strength is required