249 research outputs found
1-(4-Bromo-2-fluoroÂbenzÂyl)pyridinium bisÂ(2-thioxo-1,3-dithiole-4,5-dithiolÂato)nickelate(III)
The title compound, (C12H10BrFN)[Ni(C3S5)2], is an ion-pair complex consisting of N-(2-fluoro-4-bromoÂbenzÂyl)pyridinium cations and [Ni(dmit)2]− anions (dmit = 2-thioxo-1,3-dithiole-4,5-dithiolÂate). In the anion, the NiIII ion exhibits a square-planar coordination involving four S atoms from two dmit ligands. In the crystal structure, weak S⋯S [3.474 (3), 3.478 (3) and 3.547 (3) Å] and S⋯π [S⋯centroid distances = 3.360 (3), 3.378 (2), 3.537 (2) and 3.681 (3) Å] interÂactions and C—H⋯F hydrogen bonds lead to a three-dimensional supraÂmolecular network
TriaquaÂbis(1H-imidazole)bisÂ[μ2-2-(oxaloÂamino)benzoato(3−)]dicopper(II)calcium(II) heptaÂhydrate
In the title heterotrinuclear coordination compound, [CaCu2(C9H4NO5)2(C3H4N2)2(H2O)3]·7H2O, the Ca2+ cation is in a pentaÂgonal–bipyramidal geometry and bridges two (1H-imidazole)[2-(oxaloamino)benzoato(3−)]copper(II) units in its equatorial plane. Each CuII atom has a normal square-planar geometry. The molÂecule has approximate local (non-crystallographic) mirror symmetry and 23 classical hydrogen bonds are found in the crystal structure
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Minimizing the diffusivity difference between vacancies and interstitials in multi-principal element alloys.
Interstitial atoms usually diffuse much faster than vacancies, which is often the root cause for the ineffective recombination of point defects in metals under irradiation. Here, via ab initio modeling of single-defect diffusion behavior in the equiatomic NiCoCrFe(Pd) alloy, we demonstrate an alloy design strategy that can reduce the diffusivity difference between the two types of point defects. The two diffusivities become almost equal after substituting the NiCoCrFe base alloy with Pd. The underlying mechanism is that Pd, with a much larger atomic size (hence larger compressibility) than the rest of the constituents, not only heightens the activation energy barrier (Ea) for interstitial motion by narrowing the diffusion channels but simultaneously also reduces Ea for vacancies due to less energy penalty required for bond length change between the initial and the saddle states. Our findings have a broad implication that the dynamics of point defects can be manipulated by taking advantage of the atomic size disparity, to facilitate point-defect annihilation that suppresses void formation and swelling, thereby improving radiation tolerance
Evolution of Interlayer Coupling in Twisted MoS2 Bilayers
Van der Waals (vdW) coupling is emerging as a powerful method to engineer and
tailor physical properties of atomically thin two-dimensional (2D) materials.
In graphene/graphene and graphene/boron-nitride structures it leads to
interesting physical phenomena ranging from new van Hove singularities1-4 and
Fermi velocity renormalization5, 6 to unconventional quantum Hall effects7 and
Hofstadter's butterfly pattern8-12. 2D transition metal dichalcogenides
(TMDCs), another system of predominantly vdW-coupled atomically thin layers13,
14, can also exhibit interesting but different coupling phenomena because TMDCs
can be direct or indirect bandgap semiconductors15, 16. Here, we present the
first study on the evolution of interlayer coupling with twist angles in
as-grown MoS2 bilayers. We find that an indirect bandgap emerges in bilayers
with any stacking configuration, but the bandgap size varies appreciably with
the twist angle: it shows the largest redshift for AA- and AB-stacked bilayers,
and a significantly smaller but constant redshift for all other twist angles.
The vibration frequency of the out-of-plane phonon in MoS2 shows similar twist
angle dependence. Our observations, together with ab initio calculations,
reveal that this evolution of interlayer coupling originates from the repulsive
steric effects, which leads to different interlayer separations between the two
MoS2 layers in different stacking configurations
Growth and applications of two-dimensional single crystals
Two-dimensional (2D) materials have received extensive research attentions
over the past two decades due to their intriguing physical properties (such as
the ultrahigh mobility and strong light-matter interaction at atomic thickness)
and a broad range of potential applications (especially in the fields of
electronics and optoelectronics). The growth of single-crystal 2D materials is
the prerequisite to realize 2D-based high-performance applications. In this
review, we aim to provide an in-depth analysis of the state-of-the-art
technology for the growth and applications of 2D materials, with particular
emphasis on single crystals. We first summarize the major growth strategies for
monolayer 2D single crystals. Following that, we discuss the growth of
multilayer single crystals, including the control of thickness, stacking
sequence, and heterostructure composition. Then we highlight the exploration of
2D single crystals in electronic and optoelectronic devices. Finally, a
perspective is given to outline the research opportunities and the remaining
challenges in this field
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