Synthesis of ultrathin platinum nanoplates for enhanced oxygen reduction activity.

Ultrathin Pt nanostructures exposing controlled crystal facets are highly desirable for their superior activity and cost-effectiveness in the electrocatalytic oxygen reduction reaction (ORR), and they are conventionally synthesized by epitaxial growth of Pt on a limited range of templates, such as Pd nanocrystals, resulting in a high cost and less structural diversity of the ultrathin Pt nanostructures. To solve this problem, we demonstrate that ultrathin Pt nanostructures can be synthesized by templating conveniently available Ag nanocrystals without involving galvanic replacement, which enables a much-reduced cost and controllable new morphologies, such as ultrathin Pt nanoplates that expose the {111} facets. The resulting ultrathin Pt nanoplates are ∼1-2 nm in thickness, which show an ∼22-fold increase in specific activity (5.3 mA cm-2), an ∼9.5-fold increase in mass activity (1.62 A mg-1) and significantly enhanced catalytic stability in the ORR, compared with the commercial Pt/C catalyst. We believe this strategy opens a door to a highly extendable family of ultrathin noble metal nanostructures, thus promising excellent activity and stability in a broad range of catalytic applications

Rethinking Urban Flood Risk Assessment By Adapting Health Domain Perspective

Inspired by ideas from health risk assessment, this paper presents a new perspective for flood risk assessment. The proposed perspective focuses on three pillars for examining flood risk: (1) inherent susceptibility, (2) mitigation strategies, and (3) external stressors. These pillars collectively encompass the physical and environmental characteristics of urban areas, the effectiveness of human-intervention measures, and the influence of uncontrollable external factors, offering a fresh point of view for decoding flood risks. For each pillar, we delineate its individual contributions to flood risk and illustrate their interactive and overall impact. The three-pillars model embodies a shift in focus from the quest to precisely model and quantify flood risk to evaluating pathways to high flood risk. The shift in perspective is intended to alleviate the quest for quantifying and predicting flood risk at fine resolutions as a panacea for enhanced flood risk management. The decomposition of flood risk pathways into the three intertwined pillars (i.e., inherent factors, mitigation factors, and external factors) enables evaluation of changes in factors within each pillar enhance and exacerbate flood risk, creating a platform from which to inform plans, decisions, and actions. Building on this foundation, we argue that a flood risk pathway analysis approach, which examines the individual and collective impacts of inherent factors, mitigation strategies, and external stressors, is essential for a nuanced evaluation of flood risk. Accordingly, the proposed perspective could complement the existing frameworks and approaches for flood risk assessment

Structures and cytotoxicities of three new sesquiterpenes from cultures of Armillaria sp.

[Image: see text] ELECTRONIC SUPPLEMENTARY MATERIAL: Supplementary material is available for this article at 10.1007/s13659-012-0077-1 and is accessible for authorized users