2,453 research outputs found
High brightness fully coherent X-ray amplifier seeded by a free-electron laser oscillator
X-ray free-electron laser oscillator (XFELO) is expected to be a cutting edge
tool for fully coherent X-ray laser generation, and undulator taper technique
is well-known for considerably increasing the efficiency of free-electron
lasers (FELs). In order to combine the advantages of these two schemes, FEL
amplifier seeded by XFELO is proposed by simply using a chirped electron beam.
With the right choice of the beam parameters, the bunch tail is within the gain
bandwidth of XFELO, and lase to saturation, which will be served as a seeding
for further amplification. Meanwhile, the bunch head which is outside the gain
bandwidth of XFELO, is preserved and used in the following FEL amplifier. It is
found that the natural "double-horn" beam current as well as residual energy
chirp from chicane compressor are quite suitable for the new scheme. Inheriting
the advantages from XFELO seeding and undulator tapering, it is feasible to
generate nearly terawatt level, fully coherent X-ray pulses with unprecedented
shot-to-shot stability, which might open up new scientific opportunities in
various research fields.Comment: 8 pages, 8 figure
Bilinear Graph Neural Network with Neighbor Interactions
Graph Neural Network (GNN) is a powerful model to learn representations and
make predictions on graph data. Existing efforts on GNN have largely defined
the graph convolution as a weighted sum of the features of the connected nodes
to form the representation of the target node. Nevertheless, the operation of
weighted sum assumes the neighbor nodes are independent of each other, and
ignores the possible interactions between them. When such interactions exist,
such as the co-occurrence of two neighbor nodes is a strong signal of the
target node's characteristics, existing GNN models may fail to capture the
signal. In this work, we argue the importance of modeling the interactions
between neighbor nodes in GNN. We propose a new graph convolution operator,
which augments the weighted sum with pairwise interactions of the
representations of neighbor nodes. We term this framework as Bilinear Graph
Neural Network (BGNN), which improves GNN representation ability with bilinear
interactions between neighbor nodes. In particular, we specify two BGNN models
named BGCN and BGAT, based on the well-known GCN and GAT, respectively.
Empirical results on three public benchmarks of semi-supervised node
classification verify the effectiveness of BGNN -- BGCN (BGAT) outperforms GCN
(GAT) by 1.6% (1.5%) in classification accuracy.Codes are available at:
https://github.com/zhuhm1996/bgnn.Comment: Accepted by IJCAI 2020. SOLE copyright holder is IJCAI (International
Joint Conferences on Artificial Intelligence), all rights reserve
Defect-Driven Efficient Selective CO2 Hydrogenation with Mo-Based Clusters
Synthetic fuels produced from CO2 show promise in combating climate change. The reverse water gas shift (RWGS) reaction is the key to opening the CO2 molecule, and CO serves as a versatile intermediate for creating various hydrocarbons. Mo-based catalysts are of great interest for RWGS reactions featured for their stability and strong metal–oxygen interactions. Our study identified Mo defects as the intrinsic origin of the high activity of cluster Mo2C for CO2-selective hydrogenation. Specifically, we found that defected Mo2C clusters supported on nitrogen-doped graphene exhibited exceptional catalytic performance, attaining a reaction rate of 6.3 gCO/gcat/h at 400 °C with over 99% CO selectivity and good stability. Such a catalyst outperformed other Mo-based catalysts and noble metal-based catalysts in terms of facile dissociation of CO2, highly selective hydrogenation, and nonbarrier liberation of CO. Our study revealed that as a potential descriptor, the atomic magnetism linearly correlates to the liberation capacity of CO, and Mo defects facilitated product desorption by reducing the magnetization of the adsorption site. On the other hand, the defects were effective in neutralizing the negative charges of surface hydrogen, which is crucial for selective hydrogenation. Finally, we have successfully demonstrated that the combination of a carbon support and the carbonization process synergistically serves as a feasible strategy for creating rich Mo defects, and biochar can be a low-cost alternative option for large-scale applications
Threshold Effects in the Decay of Heavy b' and t' Quarks
A sequential fourth generation is still viable, but the t' and b' quarks are
constrained to be not too far apart in mass. The t'{\to}bW and b'{\to}tW decay
channels are still being pursued at the Tevatron, which would soon be surpassed
by the LHC. We use a convolution method with up to five-body final state to
study t' and b' decays. We show how the two decay branches for m_{b'} below the
tW threshold, b'{\to}tW^* and t^*W, merge with b'{\to}tW above the threshold.
We then consider the heavy-to-heavy transitions b'{\to}t^{\prime(*)}W^{(*)} (or
t'{\to}b^{\prime(*)}W^{(*)}), as they are not suppressed by quark mixing. We
find that, because of the threshold sensitivity of the branching fraction of
t'{\to}b'W^* (or b'{\to}t'W^*), it is possible to measure the strength of the
CKM mixing element V_{t'b} (or V_{tb'}), especially when it is rather small. We
urge the experiments to pursue and separate the t'{\to}b'W^* (or b'{\to}t'W^*)
decay in their search program
Electron Delocalization in Gate-Tunable Gapless Silicene
The application of a perpendicular electric field can drive silicene into a
gapless state, characterized by two nearly fully spin-polarized Dirac cones
owing to both relatively large spin-orbital interactions and inversion symmetry
breaking. Here we argue that since inter-valley scattering from non-magnetic
impurities is highly suppressed by time reversal symmetry, the physics should
be effectively single-Dirac-cone like. Through numerical calculations, we
demonstrate that there is no significant backscattering from a single impurity
that is non-magnetic and unit-cell uniform, indicating a stable delocalized
state. This conjecture is then further confirmed from a scaling of conductance
for disordered systems using the same type of impurities.Comment: 6 pages, 3 figures, published versio
Divergent and Stereoselective Synthesis of β-Silyl-α-Amino Acids through Palladium-Catalyzed Intermolecular Silylation of Unactivated Primary and Secondary C−H Bonds
A general and practical Pd^(II)-catalyzed intermolecular silylation of primary and secondary C−H bonds of α-amino acids and simple aliphatic acids is reported. This method provides divergent and stereoselective access to a variety of optical pure β-silyl-α-amino acids, which are useful for genetic technologies and proteomics. It can also be readily performed on a gram scale and the auxiliary can be easily removed with retention of configuration. The synthetic importance of this method is further demonstrated by the late-stage functionalization of biological small molecules, such as (−)-santonin and β-cholic acid. Moreover, several key palladacycles were successfully isolated and characterized to elucidate the mechanism of this β−C(sp^3)-H silylation process
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