Bottom-up fabrication of highly ordered metal nanostructures by hierarchical self-assembly

In a hierarchical nanopatterning routine relying exclusively on self-assembly processes we combine crystal surface reconstruction, microphase separation of copolymers, and selective metal diffusion to produce monodisperse metal nanostructures in highly regular arrays covering areas of square centimeters. In-situ GISAXS during Fe nanostructure formation evidences the outstanding structural order in the self-assembling system and hints at possibilities of sculpting nanostructures by external process parameters. Thus, we demonstrate that nanopatterning via self-assembly is a competitive alternative to lithography-based routines, achieving comparable pattern regularity, feature size, and patterned areas with considerably reduced effort. The option for in-situ investigations during pattern formation, the possibility of customizing the nanostructure morphology, the capacity to pattern arbitrarily large areas with ultra-high structure densities, and the potential of addressing the nanostructures individually enable numerous applications, e.g., in high-density magnetic data storage, in functional nanostructured materials, e.g., for photonics or catalysis, or in sensing based on surface plasmon resonances.Comment: 21 pages, 9 figures, 1 tabl

Nuclear resonant surface diffraction

Nuclear resonant x-ray diffraction in grazing incidence geometry is used to determine the lateral magnetic configuration in a one-dimensional lattice of ferromagnetic nanostripes. During magnetic reversal, strong nuclear superstructure diffraction peaks appear in addition to the electronic ones due to an antiferromagnetic order in the nanostripe lattice. We show that the analysis of the angular distribution of the resonantly diffracted x-rays together with the time-dependence of the coherently diffracted nuclear signal reveals surface spin structures with very high sensitivity. This novel scattering technique provides a unique access to laterally correlated spin configurations in magnetically ordered nanostructures and, in perspective, also to their dynamics

Spin precession mapping at ferromagnetic resonance via nuclear resonant scattering

We probe the spin dynamics in a thin magnetic film at ferromagnetic resonance by nuclear resonant scattering of synchrotron radiation at the 14.4 keV resonance of $^{57}$Fe. The precession of the magnetization leads to an apparent reduction of the magnetic hyperfine field acting at the $^{57}$Fe nuclei. The spin dynamics is described in a stochastic relaxation model adapted to the ferromagnetic resonance theory by Smit and Beljers to model the decay of the excited nuclear state. From the fits of the measured data the shape of the precession cone of the spins is determined. Our results open a new perspective to determine magnetization dynamics in layered structures with very high depth resolution by employing ultrathin isotopic probe layers

Effect of dopants on thermal stability and self-diffusion in iron nitride thin films

We studied the effect of dopants (Al, Ti, Zr) on the thermal stability of iron nitride thin films prepared using a dc magnetron sputtering technique. Structure and magnetic characterization of deposited samples reveal that the thermal stability together with soft magnetic properties of iron nitride thin films get significantly improved with doping. To understand the observed results, detailed Fe and N self-diffusion measurements were performed. It was observed that N self-diffusion gets suppressed with Al doping whereas Ti or Zr doping results in somewhat faster N diffusion. On the other hand Fe self-diffusion seems to get suppressed with any dopant of which heat of nitride formation is significantly smaller than that of iron nitride. Importantly, it was observed that N self-diffusion plays only a trivial role, as compared to Fe self-diffusion, in affecting the thermal stability of iron nitride thin films. Based on the obtained results effect of dopants on self-diffusion process is discussed.Comment: 10 pages, 9 fig

Origin of exchange bias in [Co/Pt]ML/Fe multilayer with orthogonal magnetic anisotropies

Magnetization reversal of soft ferromagnetic Fe layer, coupled to [Co/Pt]ML multilayer [ML] with perpendicular magnetic anisotropy (PMA), has been studied in-situ with an aim to understand the origin of exchange bias (EB) in orthogonal magnetic anisotropic systems. The interface remanant state of the ML is modified by magnetic field annealing, and the effect of the same on the soft Fe layer is monitored using the in-situ magneto-optical Kerr effect (MOKE). A considerable shift in the Fe layer hysteresis loop from the centre and an unusual increase in the coercivity, similar to exchange bias phenomena, is attributed to the exchange coupling at the [Co/Pt]ML and Fe interface. The effect of the coupling on spin orientation at the interface is further explored precisely by performing an isotope selective grazing incident nuclear resonance scattering (GINRS) technique. Here, the interface selectivity is achieved by introducing a 2 nm thick Fe57 marker between [Co/Pt]ML and Fe layers. Interface sensitivity is further enhanced by performing measurements under the x-ray standing wave conditions. The combined MOKE and GINRS analysis revealed the unidirectional pinning of the Fe layer due to the net in-plane magnetic spin at the interface caused by magnetic field annealing. Unidirectional exchange coupling or pinning at the interface, which may be due to the formation of asymmetrical closure domains, is found responsible for the origin of EB with an unusual increase in coercivity.Comment: 9 figures, 1 tabl

Quantum Imaging with Incoherently Scattered Light from a Free-Electron Laser

The advent of accelerator-driven free-electron lasers (FEL) has opened new avenues for high-resolution structure determination via diffraction methods that go far beyond conventional x-ray crystallography methods. These techniques rely on coherent scattering processes that require the maintenance of first-order coherence of the radiation field throughout the imaging procedure. Here we show that higher-order degrees of coherence, displayed in the intensity correlations of incoherently scattered x-rays from an FEL, can be used to image two-dimensional objects with a spatial resolution close to or even below the Abbe limit. This constitutes a new approach towards structure determination based on incoherent processes, including Compton scattering, fluorescence emission or wavefront distortions, generally considered detrimental for imaging applications. Our method is an extension of the landmark intensity correlation measurements of Hanbury Brown and Twiss to higher than second-order paving the way towards determination of structure and dynamics of matter in regimes where coherent imaging methods have intrinsic limitations