A study to investigate the chemical stability of gallium phosphate oxide/gallium arsenide phosphide

The elemental composition with depth into the oxide films was examined using secondary ion mass spectrometry. Results indicate that the layers are arsenic-deficient through the bulk of the oxide and arsenic-rich near both the oxide surface and the oxide-semiconductor interface region. Phosphorus is incorporated into the oxide in an approximately uniform manner. The MIS capacitor structures exhibited deep-depletion characteristics and hysteresis indicative of electron trapping at the oxide-semiconductor interface. Post-oxidation annealing of the films in argon or nitrogen generally results in slightly increased dielectric leakage currents and decreased C-V hysteresis effects, and is associated with arsenic loss at the oxide surface. The results of bias-temperature stress experiments indicate that the major instability effects are due to changes in the electron trapping behavior. No changes were observed in the elemental profiles following electrical stressing, indicating that the grown films are chemically stable under device operating conditions

Transcription by the numbers redux: experiments and calculations that surprise

The study of transcription has witnessed an explosion of quantitative effort both experimentally and theoretically. In this article we highlight some of the exciting recent experimental efforts in the study of transcription with an eye to the demands that such experiments put on theoretical models of transcription. From a modeling perspective, we focus on two broad classes of models: the so-called thermodynamic models that use statistical mechanics to reckon the level of gene expression as probabilities of promoter occupancy, and rate-equation treatments that focus on the temporal evolution of the activity of a given promoter and that make it possible to compute the distributions of messenger RNA and proteins. We consider several appealing case studies to illustrate how quantitative models have been used to dissect transcriptional regulation

Passive Margin evolution and control on natural gas leakage in the Orange Basin South Africa

Throughout exploration Block 2 of the Orange Basin offshore the South African continental margin, different natural gas leakage features and the relationship between natural gas leakage with structural and stratigraphic elements were studied. This study also quantifies liquid/gas hydrocarbon generation, migration and seepage dynamics through the post-rift history of the basin. The interpretation of seismic data reveals two mega-sequences: Cretaceous and Cenozoic that are subdivided by major stratigraphic unconformities into 5 and 2 sub-units, respectively. The basin is also divided into 2 structural domains: 1. an extensional domain characterized by basinward dipping listric normal faults rooted at the Cenomanian/Turonian level identified between 500 to 1500 m of present-day depth, 2. a compressional domain that accommodates the up-dip extension on the lower slope, and which is characterized by landward dipping thrust faults. One hundred and thirteen observed gas chimneys are identified and classified into .stratigraphically-controlled (sa-c) and structurally-controlled (s-c) chimneys. The ratio of s-c versus s-ac chimneys is estimated as 2:5, which suggest a strong stratigraphic control on natural gas leakage. The chimneys either terminate at the seafloor where active leaking gas is manifested by pockmarks, or are sealed within the Miocene (14 Ma) sequence as paleo-pockmarks. The s-c chimneys are located along the normal faults in the extensional domain, and terminate as seafloor mounds up to 1500 m in diameter and with heights between 10 to 50 m. The sa-c pockmarks range between 100 to 400 m in diameter, and are linked to stratigraphic onlaps and pinch-outs within the Aptian sequence. Several giant chimneys, with diameters of more than 7 km, are also identified. At least one of these displays apparent internal gravitational collap.se structures. Bright spots indicative of gas presence within these large chimneys were identified, but there is no evidence of acoustic turbidity or seismic pull-downs within these large structures. This suggests the giant chimneys are inactive paleo-gas-escape structures. Modelling suggests that gas from the lower Aptian and the Barremian source rocks migrates laterally-updip to the proximal parts of the basin where it accumulates beneath the Cenomanian/Turonian sequence that acts as a regional seal. Across the shelf-break and the upper slope, chimneys and pockmarks are fed from younger Cenomanian/Turonian source rocks. The migration model also indicates that fluids are about 24 times more likely to flow out of the study area than to be preserved within it. Since methane gas escaping across the sea floor into the exosphere (combined hydrosphere and atmosphere) may contribute to Earth s climate fluctuations, and because escaping gas must have been cut off when at least half of identified s-c chimneys were sealed within the Mioeene .sequenee, deerease of gas escape along the southern African continental margin may have to be factored into global Neogene cooling models

The Mythology of Game Theory

Non-cooperative game theory is at its heart a theory of cognition, specifically a theory of how decisions are made. Game theory\u27s leverage is that we can design different payoffs, settings, player arrays, action possibilities, and information structures, and that these differences lead to different strategies, outcomes, and equilibria. It is well-known that, in experimental settings, people do not adopt the predicted strategies, outcomes, and equilibria. The standard response to this mismatch of prediction and observation is to add various psychological axioms to the game-theoretic framework. Regardless of the differing specific proposals and results, game theory uniformly makes certain cognitive assumptions that seem rarely to be acknowledged, much less interrogated. Indeed, it is not widely understood that game theory is essentially a cognitive theory. Here, we interrogate those cognitive assumptions. We do more than reject specific predictions from specific games. More broadly, we reject the underlying cognitive model implicitly assumed by game theory

Behavioral Management of Auditory Hallucinations: Implementation and Evaluation of a 10-Week Course

A 10-session behavioral course for self-management of auditory hallucinations in patients with schizophrenia has demonstrated positive outcomes. This article evaluates both the course’s implementation and benefits to patients attending the course. Teleconferencing, electronic media, and 26 monthly conference calls were used to educate six advanced practice nurses (APNs) at six sites about the course implementation. Thirty-two patients within the U.S. Department of Veterans Affairs participated in the course. All of the APNs reported course helpfulness, improved communication with patients about voices, and improved harm assessment. Of the patients, 96% found the course helpful: 67% no longer heard voices to harm self or others, and 60% had improved auditory hallucination intensity scores. The project demonstrated successful implementation and practice integration with APNs’ activities corresponding to Rogers’ stages of innovation adoption. Facilitators and barriers to implementation are also described

Guidelines for Proof Test Analysis

These guidelines integrate state-of-the-art elastic-plastic fracture mechanics (EPFM) and proof test implementation issues into a comprehensive proof test analysis procedure in the form of a road map which identifies the types of data, fracture mechanics based parameters, and calculations needed to perform flaw screening and minimum proof load analyses of fracture critical components. Worked examples are presented to illustrate the application of the road map to proof test analysis. The state-of-the art fracture technology employed in these guidelines is based on the EPFM parameter, J, and a pictorial representation of a J fracture analysis, called the failure assessment diagram (FAD) approach. The recommended fracture technology is validated using finite element J results, and laboratory and hardware fracture test results on the nickel-based superalloy Inconel 718, the aluminum alloy 2024-T3511, and ferritic pressure vessel steels. In all cases the laboratory specimens and hardware failed by ductile mechanisms. Advanced proof test analyses involving probability analysis and multiple-cycle proof testing (MCPT) are addressed. Finally, recommendations are provided on how to account for the effects of the proof test overload on subsequent service fatigue and fracture behaviors

NASA Contractor Report: Guidelines for Proof Test Analysis

These Guidelines integrate state-of-the-art Elastic-Plastic Fracture Mechanics (EPFM) and proof test implementation issues into a comprehensive proof test analysis procedure in the form of a Road Map which identifies the types of data, fracture mechanics based parameters, and calculations needed to perform flaw screening and minimum proof load analyses of fracture critical components. Worked examples are presented to illustrate the application of the Road Map to proof test analysis. The state-of-the-art fracture technology employed in these Guidelines is based on the EPFM parameter, J, and a pictorial representation of a J fracture analysis, called the Failure Assessment Diagram (FAD) approach. The recommended fracture technology is validated using finite element J results, and laboratory and hardware fracture test results on the nickel-based superalloy IN-718, the aluminum alloy 2024-T351 1, and ferritic pressure vessel steels. In all cases the laboratory specimens and hardware failed by ductile mechanisms. Advanced proof test analyses involving probability analysis and Multiple Cycle Proof Testing (MCPT) are addressed. Finally, recommendations are provided on to how to account for the effects of the proof test overload on subsequent service fatigue and fracture behaviors

Catastrophic Impact of Silicon on Silicon: Unraveling the Genesis Impact Using Sample 61881

The Genesis mission collected solar wind and brought it back to Earth in order to provide precise knowledge of solar isotopic and elemental compositions. The ions in the solar wind were stopped in the collectors at depths on the order of 10 to a few hundred nanometers. This shallow implantation layer is critical for scientific analysis of the composition of the solar wind and must be preserved throughout sample handling, cleaning, processing, distribution, preparation and analysis. The current work is motivated by the need to understand the interaction of the Genesis payload with contamination during the crash in the Utah desert. Silicon contamination has been found to be notoriously difficult to remove from silicon samples despite multiple cleanings with multiple techniques. However, the question has been posed, "Does the silicon really need to be removed for large area analyses?." If the recalcitrant silicon contamination is all pure silicon from fractured collectors, only a very tiny fraction of that bulk material will contain solar wind, which could skew the analyses. This could be complicated if the silicon trapped other materials and/or gases as it impacted the surface