3,225 research outputs found
Quantum Hall effect and Landau level crossing of Dirac fermions in trilayer graphene
We investigate electronic transport in high mobility (\textgreater 100,000
cm/Vs) trilayer graphene devices on hexagonal boron nitride, which
enables the observation of Shubnikov-de Haas oscillations and an unconventional
quantum Hall effect. The massless and massive characters of the TLG subbands
lead to a set of Landau level crossings, whose magnetic field and filling
factor coordinates enable the direct determination of the
Slonczewski-Weiss-McClure (SWMcC) parameters used to describe the peculiar
electronic structure of trilayer graphene. Moreover, at high magnetic fields,
the degenerate crossing points split into manifolds indicating the existence of
broken-symmetry quantum Hall states.Comment: Supplementary Information at
http://jarilloherrero.mit.edu/wp-content/uploads/2011/04/Supplementary_Taychatanapat.pd
Atomically dispersed Pt-N-4 sites as efficient and selective electrocatalysts for the chlorine evolution reaction
Chlorine evolution reaction (CER) is a critical anode reaction in chlor-alkali electrolysis. Although precious metal-based mixed metal oxides (MMOs) have been widely used as CER catalysts, they suffer from the concomitant generation of oxygen during the CER. Herein, we demonstrate that atomically dispersed Pt-N-4 sites doped on a carbon nanotube (Pt-1/CNT) can catalyse the CER with excellent activity and selectivity. The Pt-1/CNT catalyst shows superior CER activity to a Pt nanoparticle-based catalyst and a commercial Ru/Ir-based MMO catalyst. Notably, Pt-1/CNT exhibits near 100% CER selectivity even in acidic media, with low Cl- concentrations (0.1M), as well as in neutral media, whereas the MMO catalyst shows substantially lower CER selectivity. In situ electrochemical X-ray absorption spectroscopy reveals the direct adsorption of Cl- on Pt-N-4 sites during the CER. Density functional theory calculations suggest the PtN4C12 site as the most plausible active site structure for the CER
The nature of localization in graphene under quantum Hall conditions
Particle localization is an essential ingredient in quantum Hall physics
[1,2]. In conventional high mobility two-dimensional electron systems Coulomb
interactions were shown to compete with disorder and to play a central role in
particle localization [3]. Here we address the nature of localization in
graphene where the carrier mobility, quantifying the disorder, is two to four
orders of magnitude smaller [4,5,6,7,8,9,10]. We image the electronic density
of states and the localized state spectrum of a graphene flake in the quantum
Hall regime with a scanning single electron transistor [11]. Our microscopic
approach provides direct insight into the nature of localization. Surprisingly,
despite strong disorder, our findings indicate that localization in graphene is
not dominated by single particle physics, but rather by a competition between
the underlying disorder potential and the repulsive Coulomb interaction
responsible for screening.Comment: 18 pages, including 5 figure
Broken symmetry states and divergent resistance in suspended bilayer graphene
Graphene [1] and its bilayer have generated tremendous excitement in the
physics community due to their unique electronic properties [2]. The intrinsic
physics of these materials, however, is partially masked by disorder, which can
arise from various sources such as ripples [3] or charged impurities [4].
Recent improvements in quality have been achieved by suspending graphene flakes
[5,6], yielding samples with very high mobilities and little charge
inhomogeneity. Here we report the fabrication of suspended bilayer graphene
devices with very little disorder. We observe fully developed quantized Hall
states at magnetic fields of 0.2 T, as well as broken symmetry states at
intermediate filling factors , , and . The
devices exhibit extremely high resistance in the state that grows
with magnetic field and scales as magnetic field divided by temperature. This
resistance is predominantly affected by the perpendicular component of the
applied field, indicating that the broken symmetry states arise from many-body
interactions.Comment: 23 pages, including 4 figures and supplementary information; accepted
to Nature Physic
STM Spectroscopy of ultra-flat graphene on hexagonal boron nitride
Graphene has demonstrated great promise for future electronics technology as
well as fundamental physics applications because of its linear energy-momentum
dispersion relations which cross at the Dirac point. However, accessing the
physics of the low density region at the Dirac point has been difficult because
of the presence of disorder which leaves the graphene with local microscopic
electron and hole puddles, resulting in a finite density of carriers even at
the charge neutrality point. Efforts have been made to reduce the disorder by
suspending graphene, leading to fabrication challenges and delicate devices
which make local spectroscopic measurements difficult. Recently, it has been
shown that placing graphene on hexagonal boron nitride (hBN) yields improved
device performance. In this letter, we use scanning tunneling microscopy to
show that graphene conforms to hBN, as evidenced by the presence of Moire
patterns in the topographic images. However, contrary to recent predictions,
this conformation does not lead to a sizable band gap due to the misalignment
of the lattices. Moreover, local spectroscopy measurements demonstrate that the
electron-hole charge fluctuations are reduced by two orders of magnitude as
compared to those on silicon oxide. This leads to charge fluctuations which are
as small as in suspended graphene, opening up Dirac point physics to more
diverse experiments than are possible on freestanding devices.Comment: Nature Materials advance online publication 13/02/201
Magnetic Catalysis and Quantum Hall Ferromagnetism in Weakly Coupled Graphene
We study the realization in a model of graphene of the phenomenon whereby the
tendency of gauge-field mediated interactions to break chiral symmetry
spontaneously is greatly enhanced in an external magnetic field. We prove that,
in the weak coupling limit, and where the electron-electron interaction
satisfies certain mild conditions, the ground state of charge neutral graphene
in an external magnetic field is a quantum Hall ferromagnet which spontaneously
breaks the emergent U(4) symmetry to U(2)XU(2).
We argue that, due to a residual CP symmetry, the quantum Hall ferromagnet
order parameter is given exactly by the leading order in perturbation theory.
On the other hand, the chiral condensate which is the order parameter for
chiral symmetry breaking generically obtains contributions at all orders. We
compute the leading correction to the chiral condensate. We argue that the
ensuing fermion spectrum resembles that of massive fermions with a vanishing
U(4)-valued chemical potential. We discuss the realization of parity and charge
conjugation symmetries and argue that, in the context of our model, the charge
neutral quantum Hall state in graphene is a bulk insulator, with vanishing
longitudinal conductivity due to a charge gap and Hall conductivity vanishing
due to a residual discrete particle-hole symmetry.Comment: 35 page
Application of Graphene within Optoelectronic Devices and Transistors
Scientists are always yearning for new and exciting ways to unlock graphene's
true potential. However, recent reports suggest this two-dimensional material
may harbor some unique properties, making it a viable candidate for use in
optoelectronic and semiconducting devices. Whereas on one hand, graphene is
highly transparent due to its atomic thickness, the material does exhibit a
strong interaction with photons. This has clear advantages over existing
materials used in photonic devices such as Indium-based compounds. Moreover,
the material can be used to 'trap' light and alter the incident wavelength,
forming the basis of the plasmonic devices. We also highlight upon graphene's
nonlinear optical response to an applied electric field, and the phenomenon of
saturable absorption. Within the context of logical devices, graphene has no
discernible band-gap. Therefore, generating one will be of utmost importance.
Amongst many others, some existing methods to open this band-gap include
chemical doping, deformation of the honeycomb structure, or the use of carbon
nanotubes (CNTs). We shall also discuss various designs of transistors,
including those which incorporate CNTs, and others which exploit the idea of
quantum tunneling. A key advantage of the CNT transistor is that ballistic
transport occurs throughout the CNT channel, with short channel effects being
minimized. We shall also discuss recent developments of the graphene tunneling
transistor, with emphasis being placed upon its operational mechanism. Finally,
we provide perspective for incorporating graphene within high frequency
devices, which do not require a pre-defined band-gap.Comment: Due to be published in "Current Topics in Applied Spectroscopy and
the Science of Nanomaterials" - Springer (Fall 2014). (17 pages, 19 figures
Quantum phase transition to unconventional multi-orbital superfluidity in optical lattices
Orbital physics plays a significant role for a vast number of important
phenomena in complex condensed matter systems such as high-T
superconductivity and unconventional magnetism. In contrast, phenomena in
superfluids -- especially in ultracold quantum gases -- are commonly well
described by the lowest orbital and a real order parameter. Here, we report on
the observation of a novel multi-orbital superfluid phase with a {\it complex}
order parameter in binary spin mixtures. In this unconventional superfluid, the
local phase angle of the complex order parameter is continuously twisted
between neighboring lattice sites. The nature of this twisted superfluid
quantum phase is an interaction-induced admixture of the p-orbital favored by
the graphene-like band structure of the hexagonal optical lattice used in the
experiment. We observe a second-order quantum phase transition between the
normal superfluid (NSF) and the twisted superfluid phase (TSF) which is
accompanied by a symmetry breaking in momentum space. The experimental results
are consistent with calculated phase diagrams and reveal fundamentally new
aspects of orbital superfluidity in quantum gas mixtures. Our studies might
bridge the gap between conventional superfluidity and complex phenomena of
orbital physics.Comment: 5 pages, 4 figure
Observation of the Fractional Quantum Hall Effect in Graphene
When electrons are confined in two dimensions and subjected to strong
magnetic fields, the Coulomb interactions between them become dominant and can
lead to novel states of matter such as fractional quantum Hall liquids. In
these liquids electrons linked to magnetic flux quanta form complex composite
quasipartices, which are manifested in the quantization of the Hall
conductivity as rational fractions of the conductance quantum. The recent
experimental discovery of an anomalous integer quantum Hall effect in graphene
has opened up a new avenue in the study of correlated 2D electronic systems, in
which the interacting electron wavefunctions are those of massless chiral
fermions. However, due to the prevailing disorder, graphene has thus far
exhibited only weak signatures of correlated electron phenomena, despite
concerted experimental efforts and intense theoretical interest. Here, we
report the observation of the fractional quantum Hall effect in ultraclean
suspended graphene, supporting the existence of strongly correlated electron
states in the presence of a magnetic field. In addition, at low carrier density
graphene becomes an insulator with an energy gap tunable by magnetic field.
These newly discovered quantum states offer the opportunity to study a new
state of matter of strongly correlated Dirac fermions in the presence of large
magnetic fields
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