29 research outputs found

    Implication of the overlap representation for modelling generalized parton distributions

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    Based on a field theoretically inspired model of light-cone wave functions, we derive valence-like generalized parton distributions and their double distributions from the wave function overlap in the parton number conserved s-channel. The parton number changing contributions in the t-channel are restored from duality. In our construction constraints of positivity and polynomiality are simultaneously satisfied and it also implies a model dependent relation between generalized parton distributions and transverse momentum dependent parton distribution functions. The model predicts that the t-behavior of resulting hadronic amplitudes depends on the Bjorken variable x_Bj. We also propose an improved ansatz for double distributions that embeds this property.Comment: 15 pages, 8 eps figure

    Modelling the sputtering of Au surfaces using a multi time-scale technique

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    This article was published in the journal, Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences [© The Author(s). Published by the Royal Society] and the definitive version is available at: http://dx.doi.org/10.1098/rspa.2012.0480We present results from an atomistic computer simulation model of the sputtering of gold crystal surfaces under 500 eV ion bombardment by Au and Ar ions for doses up to 1014 ions cm−2. The multi time-scale technique uses molecular dynamics to calculate the fast ballistic collision processes in the early stages of the cascade, whereas an on-the fly kinetic Monte Carlo technique is used to model the relaxation and diffusion processes between successive ion impacts when the defect motion has begun to be dominated by rare events. The results indicate a large amount of crystalline recovery between impacts, some facetting of the crystal surfaces but no large sub-surface defect accumulation. Because of this recovery process, sputtering yields and energy distributions are in good agreement with those obtained assuming a perfect crystal surface and also with those experimentally measured

    In situ observation of self-assembled hydrocarbon Fischer–Tropsch products on a cobalt catalyst

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    Fischer-Tropsch synthesis is a heterogeneous catalytic reaction that creates approximately 2% of the world's fuel. It involves the synthesis of linear hydrocarbon molecules from a gaseous mixture of carbon monoxide and hydrogen at high pressures (from a few to tens of bars) and high temperatures (200-350 €...°C). To gain further insight into the fundamental mechanisms of this industrial process, we have used a purpose-built scanning tunnelling microscope to monitor a cobalt model catalyst under reaction conditions. We show that, after 30 €...minutes of reaction, the terraces of the cobalt catalyst are covered by parallel arrays of stripes. We propose that the stripes are formed by the self-assembly of linear hydrocarbon product molecules. Surprisingly, the width of the stripes corresponds to molecules that are 14 or 15 carbon atoms long. We introduce a simple model that explains the accumulation of such long molecules by describing their monomer-by-monomer synthesis and explicitly accounting for their thermal desorption
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