Dynamics of Metal Centers Monitored by Nuclear Inelastic Scattering

Nuclear inelastic scattering of synchrotron radiation has been used now since 10 years as a tool for vibrational spectroscopy. This method has turned out especially useful in case of large molecules that contain a M\"ossbauer active metal center. Recent applications to iron-sulfur proteins, to iron(II) spin crossover complexes and to tin-DNA complexes are discussed. Special emphasis is given to the combination of nuclear inelastic scattering and density functional calculations

Quantum Criticality via Magnetic Branes

Holographic methods are used to investigate the low temperature limit, including quantum critical behavior, of strongly coupled 4-dimensional gauge theories in the presence of an external magnetic field, and finite charge density. In addition to the metric, the dual gravity theory contains a Maxwell field with Chern-Simons coupling. In the absence of charge, the magnetic field induces an RG flow to an infrared AdS$_3 \times {\bf R}^2$ geometry, which is dual to a 2-dimensional CFT representing strongly interacting fermions in the lowest Landau level. Two asymptotic Virasoro algebras and one chiral Kac-Moody algebra arise as {\sl emergent symmetries} in the IR. Including a nonzero charge density reveals a quantum critical point when the magnetic field reaches a critical value whose scale is set by the charge density. The critical theory is probed by the study of long-distance correlation functions of the boundary stress tensor and current. All quantities of major physical interest in this system, such as critical exponents and scaling functions, can be computed analytically. We also study an asymptotically AdS$_6$ system whose magnetic field induced quantum critical point is governed by a IR Lifshitz geometry, holographically dual to a D=2+1 field theory. The behavior of these holographic theories shares important similarities with that of real world quantum critical systems obtained by tuning a magnetic field, and may be relevant to materials such as Strontium Ruthenates.Comment: To appear in Lect. Notes Phys. "Strongly interacting matter in magnetic fields" (Springer), edited by D. Kharzeev, K. Landsteiner, A. Schmitt, H.-U. Ye

Parasites of rhe oral cavity

This article provides an analysis and specific examples of oral myiasis diseases. The purpose of the analysis is to clearly show a fairly rare disease that many people forget about. We analyzed the causal relationship of the occurrence of parasites in the oral cavity and what it leads to.В данной статье приведен анализ и конкретные примеры заболеваний оральным миазом. Цель анализа заключается в наглядно показанной и достаточно редкой болезни, о которой многие забывают. Мы проанализировали причинно-следственную связь возникновения паразитов в ротовой полости и к чему это приводит

pi+ + d --> p + p reaction between 18 and 44 MeV

A study of the reaction pi+ + d --> p + p has been performed in the energy range of 18 - 44 MeV. Total cross sections and differential cross sections at six angles have been measured at 15 energies with an energy increment of 1 - 2 MeV. This is the most systematic data set in this energy range. No structure in the energy dependence of the cross section has been observed within the accuracy of this experiment.Comment: 20 pages, 7 Postscript figure

Cymantrene–Triazole "Click" Products: Structural Characterization and Electrochemical Properties

We report the first known examples of triazole-derivatized cymantrene complexes (η5-[4-substituted triazol-1-yl]cyclopentadienyl)tricarbonylmanganese(I), obtained via a “click” chemical synthesis, bearing a phenyl, 3-aminophenyl, or 4-aminophenyl moiety at the 4-position of the triazole ring. Structural characterization data using multinuclear NMR, UV–vis, ATR-IR, and mass spectrometric methods are provided, as well as crystallographic data for (η5-[4-phenyltriazol-1-yl]cyclopentadienyl)tricarbonylmanganese(I) and (η5-[4-(3-aminophenyl)triazol-1-yl]cyclopentadienyl)tricarbonylmanganese(I). Cyclic voltammetric characterization of the redox behavior of each of the three cymantrene–triazole complexes is presented together with digital simulations, in situ infrared spectroelectrochemistry, and DFT calculations to extract the associated kinetic and thermodynamic parameters. The trypanocidal activity of each cymantrene–triazole complex is also examined, and these complexes are found to be more active than cymantrene alone

Quantum oscillations and the Fermi surface in an underdoped high-Tc superconductor

Despite twenty years of research, the phase diagram of high transition- temperature superconductors remains enigmatic. A central issue is the origin of the differences in the physical properties of these copper oxides doped to opposite sides of the superconducting region. In the overdoped regime, the material behaves as a reasonably conventional metal, with a large Fermi surface. The underdoped regime, however, is highly anomalous and appears to have no coherent Fermi surface, but only disconnected "Fermi arcs". The fundamental question, then, is whether underdoped copper oxides have a Fermi surface, and if so, whether it is topologically different from that seen in the overdoped regime. Here we report the observation of quantum oscillations in the electrical resistance of the oxygen-ordered copper oxide YBa2Cu3O6.5, establishing the existence of a well-defined Fermi surface in the ground state of underdoped copper oxides, once superconductivity is suppressed by a magnetic field. The low oscillation frequency reveals a Fermi surface made of small pockets, in contrast to the large cylinder characteristic of the overdoped regime. Two possible interpretations are discussed: either a small pocket is part of the band structure specific to YBa2Cu3O6.5 or small pockets arise from a topological change at a critical point in the phase diagram. Our understanding of high-transition temperature (high-Tc) superconductors will depend critically on which of these two interpretations proves to be correct

A Solvable Regime of Disorder and Interactions in Ballistic Nanostructures, Part I: Consequences for Coulomb Blockade

We provide a framework for analyzing the problem of interacting electrons in a ballistic quantum dot with chaotic boundary conditions within an energy $E_T$ (the Thouless energy) of the Fermi energy. Within this window we show that the interactions can be characterized by Landau Fermi liquid parameters. When $g$, the dimensionless conductance of the dot, is large, we find that the disordered interacting problem can be solved in a saddle-point approximation which becomes exact as $g\to\infty$ (as in a large-N theory). The infinite $g$ theory shows a transition to a strong-coupling phase characterized by the same order parameter as in the Pomeranchuk transition in clean systems (a spontaneous interaction-induced Fermi surface distortion), but smeared and pinned by disorder. At finite $g$, the two phases and critical point evolve into three regimes in the $u_m-1/g$ plane -- weak- and strong-coupling regimes separated by crossover lines from a quantum-critical regime controlled by the quantum critical point. In the strong-coupling and quantum-critical regions, the quasiparticle acquires a width of the same order as the level spacing $\Delta$ within a few $\Delta$'s of the Fermi energy due to coupling to collective excitations. In the strong coupling regime if $m$ is odd, the dot will (if isolated) cross over from the orthogonal to unitary ensemble for an exponentially small external flux, or will (if strongly coupled to leads) break time-reversal symmetry spontaneously.Comment: 33 pages, 14 figures. Very minor changes. We have clarified that we are treating charge-channel instabilities in spinful systems, leaving spin-channel instabilities for future work. No substantive results are change